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The Bethe–Salpeter equation (named after
Hans Bethe Hans Albrecht Bethe (; July 2, 1906 – March 6, 2005) was a German-American theoretical physicist who made major contributions to nuclear physics, astrophysics, quantum electrodynamics, and solid-state physics, and who won the 1967 Nobel ...
and
Edwin Salpeter Edwin Ernest Salpeter (3 December 1924 – 26 November 2008,) was an Austrian–Australian–American astrophysicist. Life Born in Vienna to a Jewish family, Salpeter emigrated from Austria to Australia while in his teens to escape the Nazis. He ...
) describes the
bound state Bound or bounds may refer to: Mathematics * Bound variable * Upper and lower bounds, observed limits of mathematical functions Physics * Bound state, a particle that has a tendency to remain localized in one or more regions of space Geography * ...
s of a two-body (particles) quantum field theoretical system in a relativistically covariant formalism. The equation was actually first published in 1950 at the end of a paper by
Yoichiro Nambu was a Japanese-American physicist and professor at the University of Chicago. Known for his contributions to the field of theoretical physics, he was awarded half of the Nobel Prize in Physics in 2008 for the discovery in 1960 of the mechanism ...
, but without derivation. Due to its generality and its application in many branches of theoretical physics, the Bethe–Salpeter equation appears in many different forms. One form, that is quite often used in
high energy physics Particle physics or high energy physics is the study of Elementary particle, fundamental particles and fundamental interaction, forces that constitute matter and radiation. The fundamental particles in the universe are classified in the Standa ...
is : \Gamma(P,p) =\int\!\frac \; K(P,p,k)\, S(k-\tfrac) \,\Gamma(P,k)\, S(k+\tfrac) where ''Γ'' is the Bethe–Salpeter amplitude, ''K'' the interaction and ''S'' the propagators of the two participating particles. In quantum theory, bound states are objects with lifetimes that are much longer than the time-scale of the interaction ruling their structure (otherwise they are called
resonances Resonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied periodic force (or a Fourier component of it) is equal or close to a natural frequency of the system on which it acts. When an oscillat ...
). Thus the constituents interact essentially infinitely many times. By summing up, infinitely many times, all possible interactions that can occur between the two constituents, the Bethe–Salpeter equation is a tool to calculate properties of bound states. Its solution, the Bethe–Salpeter amplitude, is a description of the bound state under consideration. As it can be derived via identifying bound-states with poles in the
S-matrix In physics, the ''S''-matrix or scattering matrix relates the initial state and the final state of a physical system undergoing a scattering process. It is used in quantum mechanics, scattering theory and quantum field theory (QFT). More forma ...
, it can be connected to the quantum theoretical description of scattering processes and
Green's functions In mathematics, a Green's function is the impulse response of an inhomogeneous linear differential operator defined on a domain with specified initial conditions or boundary conditions. This means that if \operatorname is the linear differential ...
. The Bethe–Salpeter equation is a general quantum field theoretical tool, thus applications for it can be found in any quantum field theory. Some examples are
positronium Positronium (Ps) is a system consisting of an electron and its anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two particles annih ...
(bound state of an
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no ...
positron pair), excitons (bound states of an electron–hole pairs), and
meson In particle physics, a meson ( or ) is a type of hadronic subatomic particle composed of an equal number of quarks and antiquarks, usually one of each, bound together by the strong interaction. Because mesons are composed of quark subparticles, ...
s (as quark-antiquark bound states). Even for simple systems such as the positronium, the equation cannot be solved exactly, although in principle it can be formulated exactly. A classification of the states can be achieved without the need for an exact solution. If one of the particles is significantly more
mass Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different eleme ...
ive than the other, the problem is considerably simplified as one solves the
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin- massive particles, called "Dirac par ...
for the lighter particle under the external
potential Potential generally refers to a currently unrealized ability. The term is used in a wide variety of fields, from physics to the social sciences to indicate things that are in a state where they are able to change in ways ranging from the simple r ...
of the heavier particle.


Derivation

The starting point for the derivation of the Bethe–Salpeter equation is the two-particle (or four point)
Dyson equation In quantum field theory, the energy that a particle has as a result of changes that it causes in its environment defines self-energy \Sigma, and represents the contribution to the particle's energy, or Effective mass (solid-state physics), effecti ...
: G = S_1\,S_2 + S_1\,S_2\, K_\, G in momentum space, where "G" is the two-particle Green function \langle\Omega, \phi_1 \,\phi_2\, \phi_3\, \phi_4 , \Omega\rangle , "S" are the free propagators and "K" is an interaction kernel, which contains all possible interactions between the two particles. The crucial step is now, to assume that bound states appear as poles in the Green function. One assumes, that two particles come together and form a bound state with mass "M", this bound state propagates freely, and then the bound state splits in its two constituents again. Therefore, one introduces the Bethe–Salpeter wave function \Psi = \langle\Omega, \phi_1 \,\phi_2, \psi\rangle , which is a transition amplitude of two constituents \phi_i into a bound state \psi, and then makes an ansatz for the Green function in the vicinity of the pole as : G \approx \frac, where ''P'' is the total momentum of the system. One sees, that if for this momentum the equation P^2 = M^2 holds, which is exactly the Einstein energy-momentum relation (with the
Four-momentum In special relativity, four-momentum (also called momentum-energy or momenergy ) is the generalization of the classical three-dimensional momentum to four-dimensional spacetime. Momentum is a vector in three dimensions; similarly four-momentum is ...
P_\mu = \left(E/c,\vec p \right) and P^2 = P_\mu\,P^\mu ), the four-point Green function contains a pole. If one plugs that ansatz into the Dyson equation above, and sets the total momentum "P" such that the energy-momentum relation holds, on both sides of the term a pole appears. : \frac = S_1\,S_2 +S_1\,S_2\, K_\frac Comparing the residues yields : \Psi=S_1\,S_2\, K_\Psi, \, This is already the Bethe–Salpeter equation, written in terms of the Bethe–Salpeter wave functions. To obtain the above form one introduces the Bethe–Salpeter amplitudes "Γ" : \Psi = S_1\,S_2\,\Gamma and gets finally : \Gamma= K_\,S_1\,S_2\,\Gamma which is written down above, with the explicit momentum dependence.


Rainbow-ladder approximation

In principle the interaction kernel K contains all possible two-particle-irreducible interactions that can occur between the two constituents. Thus, in practical calculations one has to model it and only choose a subset of the interactions. As in quantum field theories, interaction is described via the exchange of particles (e.g.
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
s in
quantum electrodynamics In particle physics, quantum electrodynamics (QED) is the relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and spec ...
, or gluons in quantum chromodynamics), the most simple interaction is the exchange of only one of these force-particles. As the Bethe–Salpeter equation sums up the interaction infinitely many times, the resulting
Feynman graph In theoretical physics, a Feynman diagram is a pictorial representation of the mathematical expressions describing the behavior and interaction of subatomic particles. The scheme is named after American physicist Richard Feynman, who introduce ...
has the form of a ladder (or rainbow). While in
quantum electrodynamics In particle physics, quantum electrodynamics (QED) is the relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and spec ...
the ladder approximation caused problems with crossing symmetry and gauge invariance and thus crossed ladder terms had to be included, in quantum chromodynamics this approximation is used phenomenologically quite a lot to calculate
hadron In particle physics, a hadron (; grc, ἁδρός, hadrós; "stout, thick") is a composite subatomic particle made of two or more quarks held together by the strong interaction. They are analogous to molecules that are held together by the e ...
masses, since it respects
chiral symmetry breaking In particle physics, chiral symmetry breaking is the spontaneous symmetry breaking of a chiral symmetry – usually by a gauge theory such as quantum chromodynamics, the quantum field theory of the strong interaction. Yoichiro Nambu was awar ...
and therefore is an important part of the generation of these masses.


Normalization

As for any homogeneous equation, the solution of the Bethe–Salpeter equation is determined only up to a numerical factor. This factor has to be specified by a certain normalization condition. For the Bethe–Salpeter amplitudes this is usually done by demanding probability conservation (similar to the normalization of the quantum mechanical
wave function A wave function in quantum physics is a mathematical description of the quantum state of an isolated quantum system. The wave function is a complex-valued probability amplitude, and the probabilities for the possible results of measurements ...
), which corresponds to the equation :2 P_\mu = \bar\Gamma \left( \frac \left( S_1 \otimes S_2 \right) - S_1\,S_2\, \left(\frac\,K\right)\, S_1\,S_2\right) \Gamma Normalizations to the charge and energy-momentum tensor of the bound state lead to the same equation. In ladder approximation the Interaction kernel does not depend on the total momentum of the Bethe–Salpeter amplitude, thus, for this case, the second term of the normalization condition vanishes.


See also

*
ABINIT ABINIT is an open-source suite of programs for materials science, distributed under the GNU General Public License. ABINIT implements density functional theory, using a plane wave basis set and pseudopotentials, to compute the electronic density ...
* Araki–Sucher correction *
Breit equation The Breit equation is a relativistic wave equation derived by Gregory Breit in 1929 based on the Dirac equation, which formally describes two or more massive spin-1/2 particles (electrons, for example) interacting electromagnetically to the first ...
* Lippmann–Schwinger equation *
Schwinger–Dyson equation The Schwinger–Dyson equations (SDEs) or Dyson–Schwinger equations, named after Julian Schwinger and Freeman Dyson, are general relations between correlation functions in quantum field theories (QFTs). They are also referred to as the Euler ...
*
Two-body Dirac equations In quantum field theory, and in the significant subfields of quantum electrodynamics (QED) and quantum chromodynamics (QCD), the two-body Dirac equations (TBDE) of constraint dynamics provide a three-dimensional yet manifestly covariant reformulat ...
* YAMBO code


References


Bibliography

Many modern quantum field theory textbooks and a few articles provide pedagogical accounts for the Bethe–Salpeter equation's context and uses. See: * * Still a good introduction is given by the review article of Nakanishi * For historical aspects, see *


External links


BerkeleyGW
– plane-wave pseudopotential method
ExC
- plane wave
Fiesta
- Gaussian all-electron method {{DEFAULTSORT:Bethe-Salpeter Equation Quantum field theory Equations of physics Quantum mechanics