The Bethe–Salpeter equation (named after
Hans Bethe and
Edwin Salpeter) describes the
bound states of a two-body (particles)
quantum field theoretical system in a relativistically covariant formalism. The equation was actually first published in 1950 at the end of a paper by
Yoichiro Nambu, but without derivation.
Due to its generality and its application in many branches of theoretical physics, the Bethe–Salpeter equation appears in many different forms. One form, that is quite often used in
high energy physics is
:
where ''Γ'' is the Bethe–Salpeter amplitude, ''K'' the interaction and ''S'' the
propagator
In quantum mechanics and quantum field theory, the propagator is a function that specifies the probability amplitude for a particle to travel from one place to another in a given period of time, or to travel with a certain energy and momentum. In ...
s of the two participating particles.
In quantum theory, bound states are objects with
lifetimes
''LifeTimes'' is an album by Diana Hubbard, released in 1979 by Waterhouse Records 8. In addition to Diana Hubbard, the album includes musical contributions from Chick Corea, Stanley Clarke, John Goodsall, Michael Boddicker, and Patrick Moraz ...
that are much longer than the time-scale of the interaction ruling their structure (otherwise they are called
resonances). Thus the constituents interact essentially infinitely many times. By summing up, infinitely many times, all possible interactions that can occur between the two constituents, the Bethe–Salpeter equation is a tool to calculate properties of bound states. Its solution, the Bethe–Salpeter amplitude, is a description of the bound state under consideration.
As it can be derived via identifying bound-states with poles in the
S-matrix, it can be connected to the quantum theoretical description of scattering processes and
Green's functions.
The Bethe–Salpeter equation is a general quantum field theoretical tool, thus applications for it can be found in any quantum field theory. Some examples are
positronium (bound state of an
electron–
positron
The positron or antielectron is the antiparticle or the antimatter counterpart of the electron. It has an electric charge of +1 '' e'', a spin of 1/2 (the same as the electron), and the same mass as an electron. When a positron collides ...
pair),
exciton
An exciton is a bound state of an electron and an electron hole which are attracted to each other by the electrostatic Coulomb force. It is an electrically neutral quasiparticle that exists in insulators, semiconductors and some liquids. The ...
s (bound states of an
electron–hole pairs), and
mesons (as
quark
A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All commonly o ...
-antiquark bound states).
Even for simple systems such as the positronium, the equation cannot be solved exactly, although in principle it can be formulated exactly. A classification of the states can be achieved without the need for an exact solution. If one of the particles is significantly more
massive than the other, the problem is considerably simplified as one solves the
Dirac equation for the lighter particle under the external
potential of the heavier particle.
Derivation
The starting point for the derivation of the Bethe–Salpeter equation is the two-particle (or four point)
Dyson equation
:
in momentum space, where "G" is the two-particle
Green function , "S" are the free
propagator
In quantum mechanics and quantum field theory, the propagator is a function that specifies the probability amplitude for a particle to travel from one place to another in a given period of time, or to travel with a certain energy and momentum. In ...
s and "K" is an interaction kernel, which contains all possible interactions between the two particles. The crucial step is now, to assume that bound states appear as poles in the Green function. One assumes, that two particles come together and form a bound state with mass "M", this bound state propagates freely, and then the bound state splits in its two constituents again. Therefore, one introduces the Bethe–Salpeter wave function
, which is a transition amplitude of two constituents
into a bound state
, and then makes an ansatz for the Green function in the vicinity of the pole as
:
where ''P'' is the total momentum of the system. One sees, that if for this momentum the equation
holds, which is exactly the
Einstein energy-momentum relation (with the
Four-momentum and
), the four-point Green function contains a pole. If one plugs that ansatz into the Dyson equation above, and sets the total momentum "P" such that the energy-momentum relation holds, on both sides of the term a pole appears.
:
Comparing the residues yields
:
This is already the Bethe–Salpeter equation, written in terms of the Bethe–Salpeter wave functions. To obtain the above form one introduces the Bethe–Salpeter amplitudes "Γ"
:
and gets finally
:
which is written down above, with the explicit momentum dependence.
Rainbow-ladder approximation
In principle the interaction kernel K contains all possible two-particle-irreducible interactions that can occur between the two constituents. Thus, in practical calculations one has to model it and only choose a subset of the interactions. As in
quantum field theories, interaction is described via the exchange of particles (e.g.
photons in
quantum electrodynamics, or
gluon
A gluon ( ) is an elementary particle that acts as the exchange particle (or gauge boson) for the strong force between quarks. It is analogous to the exchange of photons in the electromagnetic force between two charged particles. Gluons bind q ...
s in
quantum chromodynamics
In theoretical physics, quantum chromodynamics (QCD) is the theory of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a type ...
), the most simple interaction is the exchange of only one of these force-particles.
As the Bethe–Salpeter equation sums up the interaction infinitely many times, the resulting
Feynman graph has the form of a ladder (or rainbow).
While in
quantum electrodynamics the ladder approximation caused problems with crossing symmetry and gauge invariance and thus crossed ladder terms had to be included, in
quantum chromodynamics
In theoretical physics, quantum chromodynamics (QCD) is the theory of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a type ...
this approximation is used phenomenologically quite a lot to calculate
hadron masses,
since it respects
chiral symmetry breaking and therefore is an important part of the generation of these masses.
Normalization
As for any homogeneous equation, the solution of the Bethe–Salpeter equation is determined only up to a numerical factor. This factor has to be specified by a certain normalization condition. For the Bethe–Salpeter amplitudes this is usually done by demanding probability conservation (similar to the normalization of the quantum mechanical
wave function), which corresponds to the equation
:
Normalizations to the charge and energy-momentum tensor of the bound state lead to the same equation. In ladder approximation the Interaction kernel does not depend on the total momentum of the Bethe–Salpeter amplitude, thus, for this case, the second term of the normalization condition vanishes.
See also
*
ABINIT
*
Araki–Sucher correction
*
Breit equation
*
Lippmann–Schwinger equation
*
Schwinger–Dyson equation
*
Two-body Dirac equations
*
YAMBO code
References
Bibliography
Many modern quantum field theory textbooks and a few articles provide pedagogical accounts for the Bethe–Salpeter equation's context and uses. See:
*
*
Still a good introduction is given by the review article of Nakanishi
*
For historical aspects, see
*
External links
BerkeleyGW– plane-wave pseudopotential method
ExC- plane wave
Fiesta- Gaussian all-electron method
{{DEFAULTSORT:Bethe-Salpeter Equation
Quantum field theory
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Quantum mechanics