In
organic chemistry, benzoyl (, ) is the
functional group with the formula C
6H
5CO-. It can be viewed as
benzaldehyde
Benzaldehyde (C6H5CHO) is an organic compound consisting of a benzene ring with a formyl substituent. It is the simplest aromatic aldehyde and one of the most industrially useful.
It is a colorless liquid with a characteristic almond-like odor. ...
missing one hydrogen.
The term "benzoyl" should not be confused with
benzyl, which has the formula C
6H
5CH
2. The benzoyl group is given the symbol "Bz". Benzyl is commonly abbreviated "Bn".
Sources
Benzoyl chloride
Benzoyl chloride, also known as benzenecarbonyl chloride, is an organochlorine compound with the formula . It is a colourless, fuming liquid with an irritating odour, and consists of a benzene ring () with an acyl chloride () substituent. It i ...
is a favored source of benzoyl groups, being used to prepare benzoyl ketones, benzamides (benzoyl amides), and benzoate esters. The source of many naturally occurring benzoyl compounds is the thioester
benzoyl-CoA. Irradiation of
benzil generates benzoyl radicals, which have the formula PhCO.
Benzoyl compounds
Many ketones contain the benzoyl group. They have the formula C
6H
5CO–R, an important example being
benzophenone.
Benzoyl
esters and
amides are common in organic chemistry. The esters are used as a
protecting group
A protecting group or protective group is introduced into a molecule by chemical modification of a functional group to obtain chemoselectivity in a subsequent chemical reaction. It plays an important role in multistep organic synthesis.
In many ...
s in
organic synthesis
Organic synthesis is a special branch of chemical synthesis and is concerned with the intentional construction of organic compounds. Organic molecules are often more complex than inorganic compounds, and their synthesis has developed into one o ...
,
which can be easily removed by
hydrolysis in dilute
basic
BASIC (Beginners' All-purpose Symbolic Instruction Code) is a family of general-purpose, high-level programming languages designed for ease of use. The original version was created by John G. Kemeny and Thomas E. Kurtz at Dartmouth College ...
solution.
Benzoyl-β-D-glucoside is a natural substance that can be found in ''
Pteris ensiformis''.
References
{{Functional group, state=expanded
Acyl groups
Phenyl compounds