![MgAl2O4](https://upload.wikimedia.org/wikipedia/commons/8/85/MgAl2O4.png)
Spinel () is the
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
/
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
member of the larger
spinel group The spinels are any of a class of minerals of general formulation which crystallise in the cubic (isometric) crystal system, with the X anions (typically chalcogens, like oxygen and sulfur) arranged in a cubic close-packed lattice and the cations ...
of minerals. It has the formula in the
cubic crystal system
In crystallography, the cubic (or isometric) crystal system is a crystal system where the Crystal_structure#Unit_cell, unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There ...
. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals.
[
]
Properties
Spinel crystallizes in the isometric system; common crystal forms are octahedra
In geometry, an octahedron (plural: octahedra, octahedrons) is a polyhedron with eight faces. The term is most commonly used to refer to the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at ea ...
, usually twinned. It has no true cleavage, but shows an octahedral parting
Parting may refer to:
* ''Parting'' (film), a 2016 Afghan-Iranian film
* Parting.com, a funeral home directory
*Parting tradition
* Cleavage (crystal)#Parting
*Side-parting, a common male hairstyle: see Regular haircut
* PartinG (gamer), a South K ...
and a conchoidal fracture
Conchoidal fracture describes the way that brittle materials break or fracture when they do not follow any natural planes of separation. Mindat.org defines conchoidal fracture as follows: "a fracture with smooth, curved surfaces, typically slig ...
. Its hardness
In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
is 8, its specific gravity
Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...
is 3.5–4.1, and it is transparent to opaque with a vitreous to dull luster. It may be colorless, but is usually various shades of red, lavender
''Lavandula'' (common name lavender) is a genus of 47 known species of flowering plants in the mint family, Lamiaceae. It is native to the Old World and is found in Cape Verde and the Canary Islands, and from Europe across to northern and easte ...
, blue, green, brown, black, or yellow. Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby
The Black Prince's Ruby is a large, irregular cabochon red spinel weighing set in the cross pattée above the Cullinan II diamond at the front of the Imperial State Crown of the United Kingdom. The spinel is one of the oldest parts of the Crown ...
and the "Timur ruby
The Timur Ruby (also ''Khiraj-i-alam'', "Tribute to the World") is an unfaceted, polished red spinel set in a necklace. It is named after the ruler Timur,Morgan, Diane (2008). ''Fire and Blood: Rubies in Myth, Magic, and History.'' Greenwood Publ ...
" in the British Crown Jewels, and the "Côte de Bretagne", formerly from the French Crown jewels. The Samarian Spinel is the largest known spinel in the world, weighing .
The transparent red spinels were called spinel-rubies or balas rubies. In the past, before the arrival of modern science, spinels and rubies were equally known as rubies. After the 18th century, the word ruby was only used for the red gem variety of the mineral corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pres ...
, and the word spinel came to be used. "Balas" is derived from Balascia, the ancient name for Badakhshan
Badakhshan is a historical region comprising parts of modern-day north-eastern Afghanistan, eastern Tajikistan, and Taxkorgan Tajik Autonomous County in China. Badakhshan Province is one of the 34 provinces of Afghanistan. Much of historic Ba ...
, a region in central Asia
Asia (, ) is one of the world's most notable geographical regions, which is either considered a continent in its own right or a subcontinent of Eurasia, which shares the continental landmass of Afro-Eurasia with Africa. Asia covers an area ...
situated in the upper valley of the Panj River
The Panj (russian: Пяндж; fa, رودخانه پنج) (; tg, Панҷ, پنج), traditionally known as the Ochus River and also known as ''Pyandzh'' (derived from its Russian name "Пяндж"), is a tributary of the Amu Darya. The river ...
, one of the principal tributaries of the Oxus River
The Amu Darya, tk, Amyderýa/ uz, Amudaryo// tg, Амударё, Amudaryo ps, , tr, Ceyhun / Amu Derya grc, Ὦξος, Ôxos (also called the Amu, Amo River and historically known by its Latin name or Greek ) is a major river in Central Asi ...
. However, "Balascia" itself may be derived from Sanskrit
Sanskrit (; attributively , ; nominally , , ) is a classical language belonging to the Indo-Aryan branch of the Indo-European languages. It arose in South Asia after its predecessor languages had diffused there from the northwest in the late ...
''bālasūryaka'', which translates as "crimson-coloured morning sun". Mines in the Gorno Badakhshan
Gorno-Badakhshan, officially the Badakhshan Mountainous Autonomous Region,, abbr. / is an autonomous region in eastern Tajikistan, in the Pamir Mountains. It makes up nearly forty-five percent of the country's land area, but only two percen ...
region of Tajikistan
Tajikistan (, ; tg, Тоҷикистон, Tojikiston; russian: Таджикистан, Tadzhikistan), officially the Republic of Tajikistan ( tg, Ҷумҳурии Тоҷикистон, Jumhurii Tojikiston), is a landlocked country in Centr ...
constituted for centuries the main source for red and pink spinels.
Occurrence
Geologic occurrence
Spinel is found as a metamorphic mineral in metamorphosed limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
s and silica-poor mudstone
Mudstone, a type of mudrock, is a fine-grained sedimentary rock whose original constituents were clays or muds. Mudstone is distinguished from '' shale'' by its lack of fissility (parallel layering).Blatt, H., and R.J. Tracy, 1996, ''Petrology. ...
s. It also occurs as a primary mineral in rare mafic igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
s; in these igneous rocks, the magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
s are relatively deficient in alkali
In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a ...
s relative to aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
, and aluminium oxide may form as the mineral corundum or may combine with magnesia to form spinel. This is why spinel and ruby
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sa ...
are often found together. The spinel petrogenesis in mafic magmatic rocks is strongly debated, but certainly results from mafic magma interaction with more evolved magma or rock (e.g. gabbro, troctolite).
Spinel, , is common in peridotite
Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high prop ...
in the uppermost Earth's mantle
Earth's mantle is a layer of silicate rock between the crust and the outer core. It has a mass of 4.01 × 1024 kg and thus makes up 67% of the mass of Earth. It has a thickness of making up about 84% of Earth's volume. It is predominantly sol ...
, between approximately 20 km to approximately 120 km, possibly to lower depths depending on the chromium content. At significantly shallower depths, above the Moho, calcic plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...
is the more stable aluminous mineral in peridotite while garnet
Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different s ...
is the stable phase deeper in the mantle below the spinel stability region.
Spinel, , is a common mineral in the Ca-Al-rich inclusions (CAIs) in some chondritic meteorite
A chondrite is a stony (non-Metallicity, metallic) meteorite that has not been modified, by either melting or planetary differentiation, differentiation of the parent body. They are formed when various types of dust and small grains in the ea ...
s.
Geographical occurrence
Spinel has long been found in the gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
-bearing gravel of Sri Lanka
Sri Lanka (, ; si, ශ්රී ලංකා, Śrī Laṅkā, translit-std=ISO (); ta, இலங்கை, Ilaṅkai, translit-std=ISO ()), formerly known as Ceylon and officially the Democratic Socialist Republic of Sri Lanka, is an ...
and in limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
s of the Badakshan Province in modern-day Afghanistan
Afghanistan, officially the Islamic Emirate of Afghanistan,; prs, امارت اسلامی افغانستان is a landlocked country located at the crossroads of Central Asia and South Asia. Referred to as the Heart of Asia, it is bordere ...
and Tajikistan
Tajikistan (, ; tg, Тоҷикистон, Tojikiston; russian: Таджикистан, Tadzhikistan), officially the Republic of Tajikistan ( tg, Ҷумҳурии Тоҷикистон, Jumhurii Tojikiston), is a landlocked country in Centr ...
; and of Mogok
Mogok (, ; Shan: , ) is a town in the Thabeikkyin District of Mandalay Region of Myanmar, located north of Mandalay and north-east of Shwebo.
History
Mogok is believed to have been founded in 1217 by three lost Shan hunters who discovered r ...
in Myanmar
Myanmar, ; UK pronunciations: US pronunciations incl. . Note: Wikipedia's IPA conventions require indicating /r/ even in British English although only some British English speakers pronounce r at the end of syllables. As John C. Wells, Joh ...
. Over the last decades gem quality spinels are found in the marbles of Lục Yên District (Vietnam
Vietnam or Viet Nam ( vi, Việt Nam, ), officially the Socialist Republic of Vietnam,., group="n" is a country in Southeast Asia, at the eastern edge of mainland Southeast Asia, with an area of and population of 96 million, making i ...
), Mahenge
Mahenge is a town in the Mahenge Mountains of Tanzania. It is the headquarters of Ulanga District in Morogoro Region.
There is a hospital, a market, and primary schools. A Catholic Capuchin mission was established around 1897, and there is n ...
and Matombo (Tanzania
Tanzania (; ), officially the United Republic of Tanzania ( sw, Jamhuri ya Muungano wa Tanzania), is a country in East Africa within the African Great Lakes region. It borders Uganda to the north; Kenya to the northeast; Comoro Islands and ...
), Tsavo (Kenya
)
, national_anthem = "Ee Mungu Nguvu Yetu"()
, image_map =
, map_caption =
, image_map2 =
, capital = Nairobi
, coordinates =
, largest_city = Nairobi
, ...
) and in the gravels of Tunduru (Tanzania
Tanzania (; ), officially the United Republic of Tanzania ( sw, Jamhuri ya Muungano wa Tanzania), is a country in East Africa within the African Great Lakes region. It borders Uganda to the north; Kenya to the northeast; Comoro Islands and ...
) and Ilakaka (Madagascar
Madagascar (; mg, Madagasikara, ), officially the Republic of Madagascar ( mg, Repoblikan'i Madagasikara, links=no, ; french: République de Madagascar), is an island country in the Indian Ocean, approximately off the coast of East Africa ...
).
Since 2000, in several locations around the world, spinels have been discovered with unusual vivid pink or blue colors. Such "glowing" spinels are known from Mogok (Myanmar), Mahenge plateau (Tanzania), Lục Yên District (Vietnam) and some more localities. In 2018 bright blue spinels have been reported also in the southern part of Baffin Island
Baffin Island (formerly Baffin Land), in the Canadian territory of Nunavut, is the largest island in Canada and the fifth-largest island in the world. Its area is , slightly larger than Spain; its population was 13,039 as of the 2021 Canadia ...
(Canada). The pure blue coloration of spinel is caused by small additions of cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pr ...
.
Synthetic spinel
Synthetic spinel can be produced by similar means to synthetic corundum, including the Verneuil method
The Verneuil method (or Verneuil process or Verneuil technique), also called flame fusion, was the first commercially successful method of manufacturing synthetic gemstones, developed in the late 1883 by the French chemist Auguste Verneuil. It ...
and the flux method
The flux method of crystal growth is a method where the components of the desired substance are dissolved in a solvent (flux). The method is particularly suitable for crystals needing to be free from thermal strain. It takes place in a crucible ma ...
pioneered by Edmond Frémy
Edmond Frémy (; 28 February 1814 – 3 February 1894) was a French chemist. He is perhaps best known today for Frémy's salt, a strong oxidizing agent which he discovered in 1845. Fremy's salt is a long-lived free radical that finds use as a s ...
. It is widely used as an inexpensive cut gem in birthstone
A birthstone is a gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rock ...
jewelry
Jewellery ( UK) or jewelry (U.S.) consists of decorative items worn for personal adornment, such as brooches, rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the clothes. From a western ...
for the month of August
August is the eighth month of the year in the Julian and Gregorian calendars, and the fifth of seven months to have a length of 31 days. Its zodiac sign is Leo and was originally named ''Sextilis'' in Latin because it was the 6th month in ...
. Light blue synthetic spinel is a good imitation of aquamarine beryl, and green synthetic spinel is used as an emerald or tourmaline simulant. By 2015, transparent spinel was being made in sheets and other shapes through sintering
Clinker nodules produced by sintering
Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction.
Sintering happens as part of a manufacturing ...
. Synthetic spinel, which looks like glass but has notably higher strength against pressure, can also have applications in military and commercial use.
See also
*
* Aluminium oxynitride
Aluminium oxynitride (marketed under the name ALON by Surmet Corporation) is a transparent ceramic composed of aluminium, oxygen and nitrogen. ALON is optically transparent (≥ 80%) in the near-ultraviolet, visible, and midwave-infrared re ...
* Ceylonite
* The Three Brothers, a lost 14th-century crown jewel with three red spinels in a triangular arrangement
References
Bibliography
* Deer, Howie and Zussman (1966). '' An Introduction to the Rock-Forming Minerals'', Longman, pp. 424–433, .
* Shumann, Walter (2006). ''Gemstones of the World'' 3rd edition, Sterling, pp. 116–117.
External links
Spinel structure
at the University of Wisconsin - Green Bay
Spinel structure
at the Institut for materials science of the University of Kiel
Kiel University, officially the Christian-Albrecht University of Kiel, (german: Christian-Albrechts-Universität zu Kiel, abbreviated CAU, known informally as Christiana Albertina) is a university in the city of Kiel, Germany. It was founded in ...
Value of Spinel
{{Jewelry
Aluminium minerals
Cubic minerals
Minerals in space group 227
Magnesium minerals
Luminescent minerals
Transparent materials