The alkaline magma series is a chemically distinct range of

magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...

compositions that describes the evolution of an

alkaline In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a base (chemistry), basic, ionic compound, ionic salt (chemistry), salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as ...

mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include ...

magma into a more evolved, silica-rich end member.

Geochemical characterization

Rocks in the alkaline magma series are distinguished from rocks in the subalkaline

tholeiitic The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma ...

and

calc-alkaline The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic m ...

magma series by their high content of

alkali metal oxide The alkali metals react with oxygen to form several different compounds: suboxides, oxides, peroxides, sesquioxides, superoxides, and ozonides. They all react violently with water. Alkali metal suboxides * Hexarubidium monoxide (Rb6O) h * Non ...

s (K₂O plus Na₂O) relative to

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...

(SiO₂). They are distinct from the rare peralkaline magmas, which have excess alkali oxides relative to alumina (Na₂O + K₂O > Al₂O₃). Alkaline magmas tend to show high

titanium oxide Titanium oxide may refer to: * Titanium dioxide (titanium(IV) oxide), TiO2 * Titanium(II) oxide (titanium monoxide), TiO, a non-stoichiometric oxide * Titanium(III) oxide (dititanium trioxide), Ti2O3 * Ti3O * Ti2O * δ-TiOx (x= 0.68–0.75) * T ...

(TiO₂) content, typically in excess of 3% by weight. Other

incompatible element In petrology and geochemistry, an incompatible element is one that is unsuitable in size and/or charge to the cation sites of the minerals of which it is included. It is defined by the partition coefficient between rock-forming minerals and melt b ...

s, such as

phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...

and light rare earth elements, are also elevated. This is attributed to a very low degree of

partial melting Partial melting occurs when only a portion of a solid is melted. For mixed substances, such as a rock containing several different minerals or a mineral that displays solid solution, this melt can be different from the bulk composition of the soli ...

of the source rock, with only 5% or less of the source rock going into the magma melt.

Petrography

All alkaline series magmas are thought to have evolved from a primitive mafic alkaline magma, either an alkalic picrite basalt or an ankaramite. This evolves to an

alkali olivine basalt Alkali basalt or alkali olivine basalt is a dark-colored, porphyritic volcanic rock usually found in oceanic and continental areas associated with volcanic activity, such as oceanic islands, continental rifts and volcanic fields. Alkali basalt ...

or basanite. Thereafter the series branches to the ''sodic'' series, the ''potassic series'', or the ''nephelinic, leucitic, and analcitic series''. The sodic series evolves through

hawaiite Hawaiite is an olivine basalt with a composition between alkali basalt and mugearite. It was first used as a name for some lavas found on the island of Hawaii. It occurs during the later stages of volcanic activity on oceanic islands such as Haw ...

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatite ...

hawaiite through

mugearite Mugearite () is a type of oligoclase-bearing basalt, comprising olivine, apatite, and opaque oxides. The main feldspar in mugearite is oligoclase. Mugearite is a sodium-rich member of the alkaline magma series. In the TAS classification of volc ...

or nepheline mugearite and

benmoreite Benmoreite is a silica-undersaturated volcanic rock of intermediate composition. It is a sodium-rich variety of trachyandesite and belongs to the alkalic suite of igneous rocks. Nepheline benmoreite An origin by fractionation from basanite t ...

or nepheline benmoreite to

trachyte Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and al ...

phonolite Phonolite is an uncommon extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous ...

. The potassic series evolves through

trachybasalt Trachybasalt is a volcanic rock with a composition between trachyte and basalt. It resembles basalt but has a high content of alkali metal oxides. Minerals in trachybasalt include alkali feldspar, calcic plagioclase, olivine, clinopyroxene and li ...

leucite Leucite is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra but, as first observed by Sir David Brewster in ...

trachybasalt through

tristanite Latite is an igneous, volcanic rock, with aphanitic- aphyric to aphyric- porphyritic texture. Its mineral assemblage is usually alkali feldspar and plagioclase in approximately equal amounts. Quartz is less than five percent and is absent in a ...

or leucite tristanite to potassic trachyte or leucite phonolite. The nephelinic, leucitic and analcitic series evolves from

nephelinite Nephelinite is a fine-grained or aphanitic igneous rock made up almost entirely of nepheline and clinopyroxene (variety augite). If olivine is present, the rock may be classified as an olivine nephelinite. Nephelinite is dark in color and may res ...

melilite Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is ( Ca, Na)2( Al, Mg, ...

through

analcite Analcime (; ) or analcite is a white, gray, or colorless tectosilicate mineral. Analcime consists of hydrated sodium aluminium silicate in cubic crystalline form. Its chemical formula is Na Al Si2 O6· H2O. Minor amounts of potassium and calci ...

leucitite Leucitite or leucite rock is an igneous rock containing leucite. It is scarce, many countries such as England being entirely without them. However, they are of wide distribution, occurring in every quarter of the globe. Taken collectively, they exhi ...

or wyomingite. The latter two may also be produced by evolution of leucite trachybasalt. The less evolved alkali rocks tend to contain

phenocryst 300px, feldspathic phenocrysts. This granite, from the Switzerland">Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter ...

s of olivine, and almost all have augite phenocrysts with elevated

titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...

, aluminum, and sodium compared with the calcic augite phenocrysts of tholeiites. Peralkaline

rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...

s (comendite or pantellerite) may be generated by fractionation of alkali basalt magma.

Geologic context

Alkaline magmas are characteristic of

continental rifting In geology, a rift is a linear zone where the lithosphere is being pulled apart and is an example of extensional tectonics. Typical rift features are a central linear downfaulted depression, called a graben, or more commonly a half-grabe ...

, areas overlying deeply

subducted Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the ...

plates, or at intraplate

hotspots Hotspot, Hot Spot or Hot spot may refer to: Places * Hot Spot, Kentucky, a community in the United States Arts, entertainment, and media Fictional entities * Hot Spot (comics), a name for the DC Comics character Isaiah Crockett * Hot Spot (Tra ...

. They are more likely to be generated at greater depths in the mantle than subalkaline magmas. Alkaline rocks are rare in the

Archean The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic. The Earth Earth ...

, but become common in the

Proterozoic The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided ...

. Alkaline rocks with an age close to 570 million years are common around the perimeters of many

continental shield A shield is a large area of exposed Precambrian crystalline igneous and high-grade metamorphic rocks that form tectonically stable areas. These rocks are older than 570 million years and sometimes date back to around 2 to 3.5 billion years. T ...

s and are evidence of worldwide rifting at that time.

References

{{Authority control Igneous petrology

Geochemical characterization

Petrography

Geologic context

See also

References