![Star-Saphire](https://upload.wikimedia.org/wikipedia/commons/e/ee/Star-Saphire.jpg)
An asterism () is a star-shaped concentration of
reflected or
refracted
In physics, refraction is the redirection of a wave as it passes from one medium to another. The redirection can be caused by the wave's change in speed or by a change in the medium. Refraction of light is the most commonly observed phenomeno ...
light from a
gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
. Asterisms can appear when a suitable stone is cut ''en
cabochon
A cabochon (; ) is a gemstone that has been shaped and polished, as opposed to faceted. The resulting form is usually a convex (rounded) obverse with a flat reverse. Cabochon was the default method of preparing gemstones before gemstone cuttin ...
'' i.e. shaped and polished (not
faceted).
A gemstone that exhibits this effect is referred to as a star stone or asteria. The best known is
star sapphire, but many other minerals can also be asteria, usually due to impurities in the crystal structure.
Archetype
The archetypal asteria is the
star sapphire, generally
corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pres ...
with near uniform impurities which is bluish-grey and milky or opalescent, which when lit has a star of six rays. In the red instance stellate reflection is rarer; the star-
ruby
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sa ...
occasionally found with the star-sapphire in
Sri Lanka
Sri Lanka (, ; si, ශ්රී ලංකා, Śrī Laṅkā, translit-std=ISO (); ta, இலங்கை, Ilaṅkai, translit-std=ISO ()), formerly known as Ceylon and officially the Democratic Socialist Republic of Sri Lanka, is an ...
is among the most valued of "fancy stones". Other examples are star-
topaz
Topaz is a silicate mineral of aluminium and fluorine with the chemical formula Al Si O( F, OH). It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can mak ...
and certain prized
chatoyant
In gemology, chatoyancy ( ), or chatoyance or cat's eye effect, is an optical reflectance effect seen in certain gemstones, woods, and carbon fibre. Coined from the French "œil de chat", meaning "cat's eye", chatoyancy arises either from the ...
(, )
chrysoberyl
The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula Be Al2 O4. The name chrysoberyl is derived from the Greek words χρυσός ''chrysos'' and βήρυλλος ''beryllos'', meaning "a gold-white spar". Despite ...
stones, particularly of the
cymophane
The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula Be Al2 O4. The name chrysoberyl is derived from the Greek words χρυσός ''chrysos'' and βήρυλλος ''beryllos'', meaning "a gold-white spar". Despite ...
(yellow) variety.
Description
Asterism is generated by reflections of light from twin-
lamellae
Lamella (plural lamellae) means a small plate or flake in Latin, and in English may refer to:
Biology
* Lamella (mycology), a papery rib beneath a mushroom cap
* Lamella (botany)
* Lamella (surface anatomy), a plate-like structure in an animal
* ...
or from extremely fine needle-shaped
acicular inclusions within the stone's crystal structure.
A common cause is oriented sub-microscopic crystals of
rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer Polymorphism (materials science), polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.
Rutile has one of the highest ...
within the gem mineral.
It occurs in
rubies
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sap ...
,
sapphire
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphir ...
s,
garnet
Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different s ...
,
diopside
Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
and
spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals.
Properties
S ...
when a
cabochon
A cabochon (; ) is a gemstone that has been shaped and polished, as opposed to faceted. The resulting form is usually a convex (rounded) obverse with a flat reverse. Cabochon was the default method of preparing gemstones before gemstone cuttin ...
is cut from a suitable stone.
Star sapphires
Star Sapphire is the name of several fictional characters in DC Comics; many of them are villainous, and all connected in origin. Within DC continuity, an immortal race of warrior women (the Zamarons) were depicted as having the ancient traditio ...
and rubies display the property from
titanium dioxide
Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insolubl ...
impurities (
rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer Polymorphism (materials science), polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.
Rutile has one of the highest ...
) present in them.
The star-effect or "asterism" is caused by the difference in refractive index between the host material and that of the dense inclusions of tiny fibers of rutile (also known as "silk"). Rutile causes the relative bright relief of a star in a host material such as corundum, which has a refractive index between 1.760 and 1.778, much lower than that of rutile. The stars are caused by the light reflecting from needle-like inclusions of rutile aligned perpendicularly to the rays of the star. The star-effect may be also caused by the inclusions of
hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
. In black star sapphire hematite needles formed parallel to the faces of the second order prism produce asterism. Some star sapphires from Thailand contain both hematite and rutile needles forming a 12-ray star.
Star-stones were formerly regarded with much superstition.
Pliny the Elder
Gaius Plinius Secundus (AD 23/2479), called Pliny the Elder (), was a Roman author, naturalist and natural philosopher, and naval and army commander of the early Roman Empire, and a friend of the emperor Vespasian. He wrote the encyclopedic '' ...
's example is consistent with a
moonstone; he described it as a colourless stone from
India
India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
within which was the appearance of a star shining with the light of the moon.
However, since rutile is present in most common star gemstones, these are almost never completely transparent.
A distinction can be made between two types of asterism:
* Epiasterism, such as that seen in sapphire and most other gems, is the result of a reflection of light on parallel arranged inclusions inside the gemstone.
* Diasterism, such as that seen in
rose quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
, is the result of light transmitted through the stone. In order to see this effect, the stone must be illuminated from behind. Rose quartz also exhibits epiasterism.
See also
*
Isomorphism (crystallography)
In chemistry isomorphism has meanings both at the level of crystallography and at a molecular level. In crystallography, compounds are isomorphous if their symmetry is the same and their unit cell parameters are similar
Molecules are isomorpho ...
References
* D. S. Phillips, T. E. Mitchell and A. H. Heuer,"Precipitation in Star Sapphire I: Identification of the Precipitates, Phil. Mag. A, 1980, v. 42, N0. 3, pp 385–404
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Gemology
Optical phenomena