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Arthur Michael (August 7, 1853 – February 8, 1942) was an American organic chemist who is best known for the
Michael reaction In organic chemistry, the Michael reaction or Michael addition is a reaction between a Michael donor (an enolate or other nucleophile) and a Michael acceptor (usually an α,β-unsaturated carbonyl) to produce a Michael adduct by creating a carbon ...
.


Life

Arthur Michael was born into a wealthy family in
Buffalo, New York Buffalo is the second-largest city in the U.S. state of New York (behind only New York City) and the seat of Erie County. It is at the eastern end of Lake Erie, at the head of the Niagara River, and is across the Canadian border from South ...
in 1853, the son of John and Clara Michael, well-off real-estate investor. He was educated in that same city, learning chemistry both from a local teacher and in his own homebuilt laboratory. An illness thwarted Michael's plans to attend
Harvard Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
, and instead in 1871 he traveled to Europe with his parents and decided to study in Germany. He studied in Hofmann's chemical laboratory in Berlin at the
University of Berlin Humboldt-Universität zu Berlin (german: Humboldt-Universität zu Berlin, abbreviated HU Berlin) is a German public research university in the central borough of Mitte in Berlin. It was established by Frederick William III on the initiative o ...
, he studied with
Robert Bunsen Robert Wilhelm Eberhard Bunsen (; 30 March 1811 – 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. The Bu ...
at
Heidelberg University } Heidelberg University, officially the Ruprecht Karl University of Heidelberg, (german: Ruprecht-Karls-Universität Heidelberg; la, Universitas Ruperto Carola Heidelbergensis) is a public research university in Heidelberg, Baden-Württemberg, ...
and after 2 years again in Berlin with Hofmann. He then studied for another year with Wurtz at the
École de Médecine École may refer to: * an elementary school in the French educational stages normally followed by secondary education establishments (collège and lycée) * École (river), a tributary of the Seine flowing in région Île-de-France * École, Sav ...
in Paris and with
Dmitri Mendeleev Dmitri Ivanovich Mendeleev (sometimes transliterated as Mendeleyev or Mendeleef) ( ; russian: links=no, Дмитрий Иванович Менделеев, tr. , ; 8 February Old_Style_and_New_Style_dates">O.S._27_January.html" ;"title="O ...
in St. Petersburg. Returning to the United States in 1880, Michael became Professor of Chemistry at
Tufts College Tufts University is a private research university on the border of Medford and Somerville, Massachusetts. It was founded in 1852 as Tufts College by Christian universalists who sought to provide a nonsectarian institution of higher learning. ...
where he taught from 1882-1889. He received an A. M. degree from Tufts in 1882, and a Ph. D. in 1890. At Tufts College, Michael met and married, in 1888, one of his own science students, Helen Cecilia De Silver Abbott. Following several years in England, during which the couple worked in a self-constructed laboratory on the
Isle of Wight The Isle of Wight ( ) is a county in the English Channel, off the coast of Hampshire, from which it is separated by the Solent. It is the largest and second-most populous island of England. Referred to as 'The Island' by residents, the Isle of ...
, they returned to the United States in 1894 where Arthur Michael again taught at Tufts, leaving in 1907 as an emeritus professor. Michael's retirement from academia lasted but five years. In 1912 he became a Professor of Chemistry at Harvard University, and there he stayed until a second retirement, in 1936. Throughout his career, Michael worked with some of the foremost chemists of his day, obtained chemistry professorships, and achieved fame among his peers. Arthur Michael died in Orlando, Florida on February 8, 1942. His wife died in 1904. They had no children.


Work

Arthur Michael is remembered today primarily for the
Michael reaction In organic chemistry, the Michael reaction or Michael addition is a reaction between a Michael donor (an enolate or other nucleophile) and a Michael acceptor (usually an α,β-unsaturated carbonyl) to produce a Michael adduct by creating a carbon ...
, also called the Michael addition. As originally defined by Michael, the reaction involves the combination of an
enolate In organic chemistry, enolates are organic anions derived from the deprotonation of carbonyl () compounds. Rarely isolated, they are widely used as reagents in the synthesis of organic compounds. Bonding and structure Enolate anions are electr ...
ion of a ketone or aldehyde to an α,β-unsaturated carbonyl compound at the β carbon. Michael was also well known in his day for incorporating thermodynamic concepts into organic chemistry, particularly for his use of entropy arguments. Perhaps his most enduring contribution to science was his central role in introducing the European model of graduate education into the United States.


Activities and honors

* National Academy of Sciences (1889) Arthur Michael is credited with the 1897
first ascent In mountaineering, a first ascent (abbreviated to FA in guide books) is the first successful, documented attainment of the top of a mountain or the first to follow a particular climbing route. First mountain ascents are notable because they en ...
s of Mount Lefroy and Mount Victoria in the Canadian Rockies along with
J. Norman Collie Professor John Norman Collie FRSE FRS (10 September 1859 – 1 November 1942), commonly referred to as J. Norman Collie, was an English scientist, mountaineer and explorer. Life and work He was born in Alderley Edge, Cheshire, the second of ...
, also a fellow Professor of Organic Chemistry.
Michael Peak Michael Peak is a mountain summit located in Yoho National Park, in the Canadian Rockies of British Columbia, Canada. Its nearest higher peak is The President, to the west-northwest. Both are part of the President Range which is a subset of th ...
was named by his friend
Edward Whymper Edward Whymper FRSE (27 April 184016 September 1911) was an English mountaineer, explorer, illustrator, and author best known for the first ascent of the Matterhorn in 1865. Four members of his climbing party were killed during the descent. W ...
in 1901 in his honor.Michael Peak
PeakFinder
https://www.thieme.de/statics/dokumente/thieme/final/en/dokumente/tw_chemistry/CFZ-Synform-Arthur-Michael-The-Michael-Addition-Reaction-NRBio.pdf


References


External links



{{DEFAULTSORT:Michael, Arthur 1853 births 1942 deaths American chemists Organic chemists Members of the United States National Academy of Sciences