Andrianovite is a very rare mineral of the

eudialyte group Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula (1)N(2)N(3)N(4)N(5)sub>3 (1a)M(1b)sub>3M(2)3M(4)Z3 i24O72'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3 ...

, with formula Na₁₂(K,Sr,Ce)₆Ca₆(Mn,Fe)₃Zr₃NbSi(Si₃O₉)₂(Si₉O₂₇)₂O(O,H₂O,OH)₅.Khomyakov, A.P., Nechelyustov, G.N., Rastsvetaeva, R.K., and Rozenberg, R.A., 2009. Andrianovite, Na₁₂(K,Sr,Ce)₃Ca₆Mn₃Zr₃Nb(Si₂₅O₇₃)(O,H₂O,OH)₅, a new potassium-rich mineral species of the eudialyte group from the Khibiny alkaline Pluton, Kola Peninsula, Russia. Geology of Ore deposits 50(8), 705–712 The original formula was extended to show the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of eudialyte group.Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794 Andrianovite is unique among the eudialyte group in being potassium-rich (other eudialyte-group species with essential K are

davinciite Davinciite is a very rare mineral of the eudialyte group, with the simplified formula Na12K3Ca6Fe32+Zr3(Si26O73OH)Cl2. The formula given does not show the presence of cyclic silicate groups. The mineral was named after Leonardo da Vinci to refer t ...

and

rastsvetaevite Rastsveatevite is a rare mineral of the eudialyte group with the chemical formula . Its structure is modular. It is only the third member of the group after andrianovite and davinciite with essential (site-dominating) potassium. Potassium and so ...

). It is regarded as potassium analogue of kentbrooksite, but it also differs from it in being oxygen-dominant rather than fluorine-dominant. Also, the coordination number of Na in this representative is enlarged from 7 to 9. The name of the mineral honors Russian mathematician and crystallographer Valerii Ivanovich Andrianov.

Occurrence and association

Andrianovite was discovered in pegmatites of Koashva open pit,

Khibiny massif The Khibiny Mountains (russian: Хиби́ны ; sjd, Umptek) is one of the two main mountain ranges of the Kola Peninsula, Russia, within the Arctic Circle, located between Imandra and Umbozero lakes. The range is also known as Khibiny Massif, K ...

, Kola Peninsula. Russia. It coexists with aegirine,

lamprophyllite Lamprophyllite (named for its lustrous cleavage) is a rare, but widespread mineral Ti-silicate mineral usually found in intrusive agpasitic igneous rocks. Yellow, reddish brown, Vitreous, Pearly. Lamprophyllite formula is (Sr,Ba,K,Na)2Na(Na,Fe, ...

, lomonosovite, microcline, mosandrite, natrolite,

sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an wikt:ornamental, ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite i ...

(silicates) and

villiaumite Villiaumite is a rare halide mineral composed of sodium fluoride, Na F. It is very soluble in water and some specimens fluoresce under long and short wave ultraviolet light. It has a Mohs hardness of 2.5 and is usually red, pink, or orange in col ...

Notes on chemistry

The formula of andrianovite is devoid of some substituting elements and group, the most important being carbonate and chlorine. Minor substituting elements are lanthanum, neodymium, yttrium, titanium,

barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...

, hafnium and aluminium.

References

Cyclosilicates Sodium minerals Potassium minerals Calcium minerals Manganese minerals Zirconium minerals Trigonal minerals Minerals in space group 160 {{silicate-mineral-stub