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An alternative fuel vehicle is a
motor vehicle A motor vehicle, also known as motorized vehicle or automotive vehicle, is a self-propelled land vehicle, commonly wheeled, that does not operate on rails (such as trains or trams) and is used for the transportation of people or cargo. The ...
that runs on alternative fuel rather than traditional
petroleum fuel Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude ...
s (
petrol Gasoline (; ) or petrol (; ) (see ) is a transparent, petroleum-derived flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines (also known as petrol engines). It consists mostly of organic c ...
or
petrodiesel Diesel fuel , also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air an ...
). The term also refers to any technology (e.g. electric car,
hybrid electric vehicle A hybrid electric vehicle (HEV) is a type of hybrid vehicle that combines a conventional internal combustion engine (ICE) system with an electric propulsion system (hybrid vehicle drivetrain). The presence of the electric powertrain is intended ...
s, solar-powered vehicles) powering an engine that does not solely involve
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude ...
. Because of a combination of factors, such as environmental concerns, high oil-prices and the potential for peak oil, development of cleaner alternative fuels and advanced power systems for vehicles has become a high priority for many governments and vehicle manufacturers around the world. Vehicle engines powered by gasolene/petrol first emerged in the 1860s and 1870s; they took until the 1930s to completely dominate the original "alternative" engines driven by steam (18th century), by gases (early 19th century), or by electricity ( 1830s).
Hybrid electric vehicle A hybrid electric vehicle (HEV) is a type of hybrid vehicle that combines a conventional internal combustion engine (ICE) system with an electric propulsion system (hybrid vehicle drivetrain). The presence of the electric powertrain is intended ...
s such as the
Toyota Prius The is a car built by Toyota which has a hybrid drivetrain, combining an internal combustion engine with an electric motor. Initially offered as a four-door sedan, it has been produced only as a five-door liftback since 2003. In 2007, t ...
are not actually alternative fuel vehicles, but through advanced technologies in the electric battery and motor/generator, they make a more efficient use of petroleum fuel. Other research-and-development efforts in alternative forms of power focus on developing
all-electric An electric vehicle (EV) is a vehicle that uses one or more electric motors for propulsion. It can be powered by a collector system, with electricity from extravehicular sources, or it can be powered autonomously by a battery (sometimes cha ...
and fuel cell vehicles, and even on the stored energy of compressed air. An environmental analysis of the impacts of various vehicle-fuels extends beyond just operating efficiency and emissions, especially if a technology comes into wide use. A life-cycle assessment of a vehicle involves production and post-use considerations. A cradle-to-cradle design is more important than a focus on a single factor such as the type of fuel.


Global outlook

, there were more than 1.4 billion
motor vehicle A motor vehicle, also known as motorized vehicle or automotive vehicle, is a self-propelled land vehicle, commonly wheeled, that does not operate on rails (such as trains or trams) and is used for the transportation of people or cargo. The ...
s on the world's roads, ''See Tables 3.2 and 3.3'' compared with just more than 116 million alternative fuel and advanced technology vehicles that had been sold or converted worldwide at the end of 2016 and consisting of: * About 55 million flex fuel automobiles, motorcycles and light duty trucks manufactured and sold worldwide by mid 2015, led by Brazil with 29.5 million by mid 2015, followed by the United States with 17.4 million by the end of 2014, Canada with about 1.6 million by 2014, and Sweden with 243,100 through December 2014. The Brazilian flex fuel fleet includes over 4 million flexible-fuel motorcycles produced since 2009 through March 2015. * 22.7 million
natural gas vehicle A natural gas vehicle (NGV) is an alternative fuel vehicle that uses compressed natural gas (CNG) or liquefied natural gas (LNG). Natural gas vehicles should not be confused with autogas vehicles powered by liquefied petroleum gas (LPG), mai ...
s , led by China (4.4 million)
Iran Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkm ...
with 4.00 million, followed by
Pakistan Pakistan ( ur, ), officially the Islamic Republic of Pakistan ( ur, , label=none), is a country in South Asia. It is the world's List of countries and dependencies by population, fifth-most populous country, with a population of almost 24 ...
(3.70 million),
Argentina Argentina (), officially the Argentine Republic ( es, link=no, República Argentina), is a country in the southern half of South America. Argentina covers an area of , making it the second-largest country in South America after Brazil, t ...
(2.48 million),
India India, officially the Republic of India ( Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the ...
(1.80 million) and
Brazil Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...
(1.78 million). * 24.9 million LPG powered vehicles by December 2013, led by
Turkey Turkey ( tr, Türkiye ), officially the Republic of Türkiye ( tr, Türkiye Cumhuriyeti, links=no ), is a list of transcontinental countries, transcontinental country located mainly on the Anatolia, Anatolian Peninsula in Western Asia, with ...
with 3.93 million,
South Korea South Korea, officially the Republic of Korea (ROK), is a country in East Asia, constituting the southern part of the Korea, Korean Peninsula and sharing a Korean Demilitarized Zone, land border with North Korea. Its western border is formed ...
(2.4 million), and Poland (2.75 million). * More than 12 million
hybrid electric vehicle A hybrid electric vehicle (HEV) is a type of hybrid vehicle that combines a conventional internal combustion engine (ICE) system with an electric propulsion system (hybrid vehicle drivetrain). The presence of the electric powertrain is intended ...
s have been sold worldwide. , Japan ranked as the market leader with more than 5 million hybrids sold, followed by the United States with cumulative sales of over 4 million units since 1999, and Europe with about 1.5 million hybrids delivered since 2000. , global sales are by Toyota Motor Company with more than 10 million Lexus and Toyota hybrids sold, followed by Honda Motor Co., Ltd. with cumulative global sales of more than 1.35 million hybrids . , global hybrid sales are led by the Prius family, with cumulative sales of 6.1 million units. The
Toyota Prius The is a car built by Toyota which has a hybrid drivetrain, combining an internal combustion engine with an electric motor. Initially offered as a four-door sedan, it has been produced only as a five-door liftback since 2003. In 2007, t ...
liftback is the world's top selling hybrid electric car with cumulative sales of 3.985 million units through January 2017. *5.7 million neat-ethanol only light-vehicles built in Brazil since 1979, pp. 62–63. with 2.4 to 3.0 million vehicles still in use by 2003. and 1.22 million units as of December 2011. * More than 10 million highway-legal plug-in electric passenger cars and light utility vehicles had been sold worldwide at the end of 2020. , the
Tesla Model 3 The Tesla Model 3 is a compact executive sedan that is battery powered and produced by Tesla. Limited production of the Model 3 began in mid-2017, with the first production vehicle rolling off the assembly line on July 7, 2017. The offici ...
listed as the world's top selling highway-capable plug-in electric car in history, with global sales since inception of more than 800,000 units, "Global sales totaled 3,124,793 plug-in passenger cars in 2020, with a BEV to PHEV ratio of 69:31, and a global market share of 4%. The world's top selling plug-in car was the Tesla Model 3 with 365,240 units delivered, and Tesla was the top selling manufacturer of plug-in passenger cars in 2019 with 499,535 units, followed by VW with 220,220." followed by the
Nissan Leaf The , stylized as LEAF, is a compact five-door hatchback battery electric vehicle (BEV) manufactured by Nissan. It was introduced in Japan and the United States in December 2010, and its second generation was introduced in October 2017. The L ...
with 500,000 units. The Mitsubishi Outlander P-HEV is the world's all-time best selling plug-in hybrid with global sales of 270,000 units through December 2020. :, China had the world's largest stock of highway legal plug-in electric passenger cars with 4.5 million units, representing 42% of the world's stock of plug-in cars. ''See Statistical annex, pp. 247–252 (See Tables A.1 and A.12).'' ''NEV sales in China totaled 1.637 million in 2020, consisting of 1.246 million passenger cars and 121,000 commercial vehicles.'' Europe ranked next with over 3.2 million plug-in passenger cars at the end of 2020, accounting for about 30% of the global stock. Filters: Elecricity/EU + UK + EFTA + Turkey/2020 (YTD) - See grahp "AF Fleet M1 Electricity (2020) Total number AF passenger cars in the fleet": BEV=1,722,003 and 1,394,915 PHEVs (Total=3,116,918 plug-in passenger cars on the road) Filters: Elecricity/EU + UK + EFTA + Turkey/2020 (YTD) - See grahp "AF Fleet Electricity (2020)": BEV=146,611 (total number AF light commercial vehicles) and "AF New Registrations Electricity (2020)": BEV=37,535 (newly registered AF light commercial vehicles) The U.S. cumulative sales totaled about 1.8 million plug-in cars through December 2020. ''National sales 2020: 322,442, cumulative sales 1,786,258. California sales 2020: 145,099, cumulative sales 803,816.'' * There were 31,225 passenger fuel cell electric vehicles (FCEV) powered with
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
on the world's roads. ''Go to th
Global EV Data Explorer
tool and choose "EV Stock", "Cars" and "World" for global stock, and "Country" for the country stock.''
South Korea is the country market with the largest stock of passenger FCEVs with 10,041 units, followed by the United States (9,135), China (5,546) and Japan (4,100).


Single fuel source


Engine air compressor

The air engine is an emission-free piston engine that uses compressed air as a source of energy. The first compressed air car was invented by a French engineer named
Guy Nègre Motor Development International SA (MDI) is a Luxembourg-French based company designing products in both mobility and energy storage using a compressed air engine. Development history Established by Guy Nègre, the Luxembourg company MDI, with i ...
. The expansion of compressed air may be used to drive the pistons in a modified piston engine. Efficiency of operation is gained through the use of environmental heat at normal temperature to warm the otherwise cold expanded air from the storage tank. This non-adiabatic expansion has the potential to greatly increase the efficiency of the machine. The only exhaust is cold air (−15 °C), which could also be used to air condition the car. The source for air is a pressurized carbon-fiber tank. Air is delivered to the engine via a rather conventional injection system. Unique crank design within the engine increases the time during which the air charge is warmed from ambient sources and a two-stage process allows improved heat transfer rates.


Electric, fed by external source

Electric power fed from an external source to the vehicle is standard in
railway electrification A railway electrification system supplies electric power to railway trains and trams without an on-board prime mover or local fuel supply. Electric railways use either electric locomotives (hauling passengers or freight in separate cars), ...
. At such systems usually the tracks form one pole, while the other is usually a single overhead wire or a rail insulated against ground. On roads this system does not work as described, as normal road surfaces are very poor electric conductors; and so electric vehicles fed with external power on roads require at least two overhead wires. The most common type of road vehicles fed with electricity from external source are
trolleybus A trolleybus (also known as trolley bus, trolley coach, trackless trolley, trackless tramin the 1910s and 1920sJoyce, J.; King, J. S.; and Newman, A. G. (1986). ''British Trolleybus Systems'', pp. 9, 12. London: Ian Allan Publishing. .or trol ...
ses, but there are also some trucks powered with this technology. The advantage is that the vehicle can be operated without breaks for refueling or charging. Disadvantages include: a large infrastructure of electric wires; difficulty in driving as one has to prevent a dewirement of the vehicle; vehicles cannot overtake each other; a danger of electrocution; and an aesthetic problem. Wireless transmission (see Wireless power transfer) is possible, in principal; but the infrastructure (especially wiring) necessary for inductive or capacitive coupling would be extensive and expensive. In principle it is also possible to transmit energy by microwaves or by lasers to the vehicle, but this may be inefficient and dangerous for the power required. Beside this, in the case of lasers one requires a guidance system to track the vehicle to be powered, as laser beams have a small diameter.


Battery-electric

Battery electric vehicle A battery electric vehicle (BEV), pure electric vehicle, only-electric vehicle, fully electric vehicle or all-electric vehicle is a type of electric vehicle (EV) that exclusively uses chemical energy stored in rechargeable battery packs, wi ...
s (BEVs), also known as all-electric vehicles (AEVs), are electric vehicles whose main energy storage is in the chemical energy of batteries. BEVs are the most common form of what is defined by the
California Air Resources Board The California Air Resources Board (CARB or ARB) is the "clean air agency" of the government of California. Established in 1967 when then-governor Ronald Reagan signed the Mulford-Carrell Act, combining the Bureau of Air Sanitation and the Mot ...
(CARB) as
zero emission vehicle A zero-emission vehicle, or ZEV, is a vehicle that does not emit exhaust gas or other pollutants from the onboard source of power. The California definition also adds that this includes under any and all possible operational modes and conditions ...
(ZEV) because they produce no tailpipe emissions at the point of operation. The electrical energy carried on board a BEV to power the motors is obtained from a variety of battery chemistries arranged into battery packs. For additional range genset trailers or pusher trailers are sometimes used, forming a type of hybrid vehicle. Batteries used in electric vehicles include "flooded" lead-acid, absorbed glass mat, NiCd, nickel metal hydride, Li-ion, Li-poly and zinc-air batteries. Attempts at building viable, modern battery-powered electric vehicles began in the 1950s with the introduction of the first modern (
transistor upright=1.4, gate (G), body (B), source (S) and drain (D) terminals. The gate is separated from the body by an insulating layer (pink). A transistor is a semiconductor device used to Electronic amplifier, amplify or electronic switch, switch ...
controlled) electric car – the Henney Kilowatt, even though the concept was out in the market since 1890. Despite the poor sales of the early battery-powered vehicles, development of various battery-powered vehicles continued through the mid-1990s, with such models as the General Motors EV1 and the Toyota RAV4 EV. Battery powered cars had primarily used lead-acid batteries and NiMH batteries. Lead-acid batteries' recharge capacity is considerably reduced if they're discharged beyond 75% on a regular basis, making them a less-than-ideal solution. NiMH batteries are a better choice, but are considerably more expensive than lead-acid.
Lithium-ion battery A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also s ...
powered vehicles such as the Venturi Fetish and the Tesla Roadster have recently demonstrated excellent performance and range, and nevertheless is used in most mass production models launched since December 2010. Expanding on traditional Lithium-ion batteries predominately used in today's battery electric vehicles, is an emerging science that is paving the way to utilize a carbon fiber structure (a vehicle body or chassis in this case) as a
structural battery Structural batteries are multifunctional materials or structures, capable of acting as an electrochemical energy storage system (i.e. batteries) while possessing mechanical integrity. They help save weight and are useful in transport applicati ...
. Experiments being conducted at th
Chalmers University of Technology
in Sweden are showing that when coupled with Lithium-ion insertion mechanisms, an enhanced carbon fiber structure can have electromechanical properties. This means that the carbon fiber structure itself can act as its own battery/power source for propulsion. This would negate the need for traditional heavy battery banks, reducing weight and therefore increasing fuel efficiency. , several neighborhood electric vehicles, city electric cars and series production highway-capable electric cars and utility vans have been made available for retails sales, including Tesla Roadster, GEM cars, Buddy, Mitsubishi i MiEV and its rebadged versions Peugeot iOn and Citroën C-Zero, Chery QQ3 EV,
JAC J3 EV JAC Motors (; officially Anhui Jianghuai Automobile Co., Ltd.) is a Chinese automobile and commercial vehicle manufacturer.
,
Nissan Leaf The , stylized as LEAF, is a compact five-door hatchback battery electric vehicle (BEV) manufactured by Nissan. It was introduced in Japan and the United States in December 2010, and its second generation was introduced in October 2017. The L ...
, Smart ED, Mia electric, BYD e6,
Renault Kangoo Z.E. The Renault Kangoo is a family of multi purpose vehicles manufactured and marketed by Renault since 1997, in commercial as well as passenger variants, across three generations. For the European market, the Kangoo is manufactured at the MCA plan ...
, Bolloré Bluecar, Renault Fluence Z.E., Ford Focus Electric,
BMW ActiveE The BMW ActiveE was a demonstration electric car based on the BMW 1 Series small family cars. It was the second vehicle after the Mini E to be developed under BMW Group’s Project i. The electric drive system was the latest addition to BMW’ ...
, Renault Twizy,
Tesla Model S The Tesla Model S is a battery-powered liftback car serving as the flagship model of Tesla, Inc. The Model S features a dual-motor, all-wheel drive layout, although earlier versions of the Model S featured a rear-motor and rear-wheel drive ...
,
Honda Fit EV The second generation Honda Fit is a subcompact car or supermini manufactured by Honda from 2007 to 2014. It debuted on 17 October 2007 at the 40th Tokyo Motor Show. __TOC__ Overview The vehicle offered a longer wheelbase than its predec ...
, RAV4 EV second generation, Renault Zoe, Mitsubishi Minicab MiEV, Roewe E50, Chevrolet Spark EV, Fiat 500e, BMW i3, Volkswagen e-Up!,
Nissan e-NV200 The Nissan NV200 is a light commercial and leisure activity, 4/5-door van designed and produced by the Japanese automaker Nissan since 2009. Overview The vehicle was previewed as the NV200 Concept at the 2007 Tokyo Motor Show, followed by ...
, Volkswagen e-Golf, Mercedes-Benz B-Class Electric Drive, Kia Soul EV, BYD e5, and Tesla Model X. The world's all-time top selling highway legal electric car is the
Nissan Leaf The , stylized as LEAF, is a compact five-door hatchback battery electric vehicle (BEV) manufactured by Nissan. It was introduced in Japan and the United States in December 2010, and its second generation was introduced in October 2017. The L ...
, released in December 2010, with global sales of more than 250,000 units through December 2016. '', the Nissan Leaf is the world's best-selling plug-in car in history with more than 250,000 units delivered, followed by the Tesla Model S with over 158,000 sales (which may soon replace the Nissan Leaf in most EV sales), the Volt/Ampera family of vehicles with 134,500 vehicles sold, and the Mitsubishi Outlander PHEV with about 116,500 units sold through November 2016. These are the only plug-in electric cars so far with over 100,000 global sales.'' The
Tesla Model S The Tesla Model S is a battery-powered liftback car serving as the flagship model of Tesla, Inc. The Model S features a dual-motor, all-wheel drive layout, although earlier versions of the Model S featured a rear-motor and rear-wheel drive ...
, released in June 2012, ranks second with global sales of over 158,000 cars delivered . The
Renault Kangoo Z.E. The Renault Kangoo is a family of multi purpose vehicles manufactured and marketed by Renault since 1997, in commercial as well as passenger variants, across three generations. For the European market, the Kangoo is manufactured at the MCA plan ...
utility van is the leader of the light-duty all-electric segment with global sales of 25,205 units through December 2016. '' Includes passenger and light utility variants. Click on "(décembre 2016)" to download the file "XLSX - 239 Ko" for CYTD sales in 2016, and open the tab "Sales by Model". Click on "+ Voir plus" (See more) to download the files "Ventes mensuelles du groupe (décembre 2011) (xls, 183 Ko)" "Ventes mensuelles (décembre 2012) (xls, 289 Ko)" - Ventes mensuelles (décembre 2013) (xlsx, 227 Ko)" - "XLSX - 220 Ko Ventes mensuelles (décembre 2014)" - "Ventes mensuelles (décembre 2015)" to download the file "XLSX - 227 Ko" for 2011, 2012, 2013, 2014 and 2015 sales. Sales figures for 2013 were revised in the 2014 report''


Electric, stored-otherway

Electricity can be also stored in supercapacitors and supraconductors. However supraconductor storage is unsuitable for vehicle propulsion as it requires extreme deep temperature and produces strong magnetic fields. Supercapacitors, however, can be used in vehicles and are used in some trams on sections without overhead wire. They can be load in during regular stops, at which passengers enter and leave the train, but can only travel a few kilometres with the stored energy. However, this is no problem in this case as the next stop is usually in reachable distance.


Solar

A solar car is an electric vehicle powered by solar energy obtained from solar panels on the car. Solar panels cannot currently be used to directly supply a car with a suitable amount of power at this time, but they can be used to extend the range of electric vehicles. They are raced in competitions such as the World Solar Challenge and the North American Solar Challenge. These events are often sponsored by Government agencies such as the United States Department of Energy keen to promote the development of
alternative energy Renewable energy is energy that is collected from renewable resources that are naturally replenished on a human timescale. It includes sources such as sunlight, wind, the movement of water, and geothermal heat. Although most renewable energy ...
technology such as solar cells and electric vehicles. Such challenges are often entered by universities to develop their students' engineering and technological skills as well as motor vehicle manufacturers such as GM and Honda. The North American Solar Challenge is a solar car race across North America. Originally called Sunrayce, organized and sponsored by General Motors in 1990, it was renamed American Solar Challenge in 2001, sponsored by the United States Department of Energy and the National Renewable Energy Laboratory. Teams from universities in the United States and Canada compete in a long distance test of endurance as well as efficiency, driving thousands of miles on regular highways. Nuna is the name of a series of manned solar powered vehicles that won the World solar challenge in Australia three times in a row, in 2001 (Nuna 1 or just Nuna), 2003 (Nuna 2) and 2005 (Nuna 3). The Nunas are built by students of the Delft University of Technology. The World solar challenge is a solar powered car race over through central Australia from Darwin to Adelaide. The race attracts teams from around the world, most of which are fielded by universities or corporations although some are fielded by high schools. Trev (two-seater renewable energy vehicle) was designed by the staff and students at the University of South Australia. Trev was first displayed at the 2005 World Solar Challenge as the concept of a low-mass, efficient commuter car. With 3 wheels and a mass of about 300 kg, the prototype car had maximum speed of 120 km/h and acceleration of 0–100 km/h in about 10 seconds. The running cost of Trev is projected to be less than 1/10 of the running cost of a small petrol car.


Dimethyl ether fuel

Dimethyl ether Dimethyl ether (DME; also known as methoxymethane) is the organic compound with the formula CH3OCH3, (sometimes ambiguously simplified to C2H6O as it is an isomer of ethanol). The simplest ether, it is a colorless gas that is a useful precurs ...
(DME) is a promising fuel in diesel engines,
petrol engine A petrol engine (gasoline engine in American English) is an internal combustion engine designed to run on petrol (gasoline). Petrol engines can often be adapted to also run on fuels such as liquefied petroleum gas and ethanol blends (such as '' ...
s (30% DME / 70% LPG), and
gas turbines A gas turbine, also called a combustion turbine, is a type of continuous flow internal combustion engine. The main parts common to all gas turbine engines form the power-producing part (known as the gas generator or core) and are, in the directio ...
owing to its high cetane number, which is 55, compared to diesel's, which is 40–53. Only moderate modifications are needed to convert a diesel engine to burn DME. The simplicity of this short carbon chain compound leads during combustion to very low emissions of particulate matter, NOx, CO. For these reasons as well as being sulfur-free, DME meets even the most stringent emission regulations in Europe (EURO5), U.S. (U.S. 2010), and Japan (2009 Japan).
Mobil Mobil is a petroleum brand owned and operated by American oil and gas corporation ExxonMobil. The brand was formerly owned and operated by an oil and gas corporation of the same name, which itself merged with Exxon to form ExxonMobil in 1999. ...
is using DME in their
methanol to gasoline Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a ...
process. DME is being developed as a synthetic
second generation biofuel Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel. First-gener ...
(BioDME), which can be manufactured from lignocellulosic biomass. Currently the EU is considering BioDME in its potential biofuel mix in 2030; the
Volvo The Volvo Group ( sv, Volvokoncernen; legally Aktiebolaget Volvo, shortened to AB Volvo, stylized as VOLVO) is a Swedish multinational manufacturing corporation headquartered in Gothenburg. While its core activity is the production, distributio ...
Group is the coordinator for the
European Community The European Economic Community (EEC) was a regional organization created by the Treaty of Rome of 1957,Today the largely rewritten treaty continues in force as the ''Treaty on the functioning of the European Union'', as renamed by the Lisb ...
Seventh Framework Programme project BioDME where Chemrec's BioDME pilot plant based on
black liquor In industrial chemistry, black liquor is the by-product from the kraft process when digesting pulpwood into paper pulp removing lignin, hemicelluloses and other extractives from the wood to free the cellulose fibers. The equivalent material i ...
gasification Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by react ...
is nearing completion in Piteå, Sweden.


Ammonia fuelled vehicles

Ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogeno ...
is produced by combining gaseous hydrogen with nitrogen from the air. Large-scale ammonia production uses natural gas for the source of hydrogen. Ammonia was used during World War II to power buses in Belgium, and in engine and solar energy applications prior to 1900. Liquid ammonia also fuelled the
Reaction Motors XLR99 The Reaction Motors LR99 engine was the first large, throttleable, restartable liquid-propellant rocket engine. Development began in the 1950s by the Reaction Motors Division of Thiokol Chemical Company to power the North American X-15 hypersonic ...
rocket engine, that powered the X-15 hypersonic research aircraft. Although not as powerful as other fuels, it left no soot in the reusable rocket engine and its density approximately matches the density of the oxidizer, liquid oxygen, which simplified the aircraft's design.
Ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogeno ...
has been proposed as a practical alternative to fossil fuel for
internal combustion engines An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal comb ...
. The calorific value of ammonia is 22.5 MJ/kg (9690 BTU/lb), which is about half that of diesel. In a normal engine, in which the water vapour is not condensed, the calorific value of ammonia will be about 21% less than this figure. It can be used in existing engines with only minor modifications to
carburettor A carburetor (also spelled carburettor) is a device used by an internal combustion engine to control and mix air and fuel entering the engine. The primary method of adding fuel to the intake air is through the venturi tube in the main meteri ...
s/
injector An injector is a system of ducting and nozzles used to direct the flow of a high-pressure fluid in such a way that a lower pressure fluid is entrained in the jet and carried through a duct to a region of higher pressure. It is a fluid-dynamic ...
s. If produced from coal, the CO2 can be readily sequestered (the combustion products are nitrogen and water). Ammonia engines or ammonia motors, using ammonia as a working fluid, have been proposed and occasionally used. The principle is similar to that used in a fireless locomotive, but with ammonia as the working fluid, instead of steam or compressed air. Ammonia engines were used experimentally in the 19th century by Goldsworthy Gurney in the UK and in
streetcars in New Orleans Streetcars in New Orleans have been an integral part of the city's public transportation network since the first half of the 19th century. The longest of New Orleans' streetcar lines, the St. Charles Avenue line, is the oldest continuously ope ...
. In 1981 a Canadian company converted a 1981 Chevrolet Impala to operate using ammonia as fuel. Ammonia and is being used with success by developers in Canada, since it can run in spark ignited or diesel engines with minor modifications, also the only green fuel to power jet engines, and despite its toxicity is reckoned to be no more dangerous than petrol or LPG. It can be made from renewable electricity, and having half the density of petrol or diesel can be readily carried in sufficient quantities in vehicles. On complete combustion it has no emissions other than nitrogen and water vapour. The combustion chemical formula is 4 NH3 + 3 O2 → 2 N2 + 6 H2O, 75% water is the result.


Biofuels


Bioalcohol and ethanol

The first commercial vehicle that used
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a h ...
as a fuel was the
Ford Model T The Ford Model T is an automobile that was produced by Ford Motor Company from October 1, 1908, to May 26, 1927. It is generally regarded as the first affordable automobile, which made car travel available to middle-class Americans. The relat ...
, produced from 1908 through 1927. It was fitted with a
carburetor A carburetor (also spelled carburettor) is a device used by an internal combustion engine to control and mix air and fuel entering the engine. The primary method of adding fuel to the intake air is through the venturi tube in the main meter ...
with adjustable jetting, allowing use of gasoline or ethanol, or a combination of both. Other car manufactures also provided engines for ethanol fuel use. In the United States, alcohol fuel was produced in corn-alcohol stills until
Prohibition Prohibition is the act or practice of forbidding something by law; more particularly the term refers to the banning of the manufacture, storage (whether in barrels or in bottles), transportation, sale, possession, and consumption of alcoholic ...
criminalized the production of alcohol in 1919. The use of alcohol as a fuel for
internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal co ...
s, either alone or in combination with other fuels, lapsed until the oil price shocks of the 1970s. Furthermore, additional attention was gained because of its possible environmental and long-term economical advantages over fossil fuel. Both
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a h ...
and methanol have been used as an automotive fuel. While both can be obtained from petroleum or natural gas, ethanol has attracted more attention because it is considered a
renewable resource A renewable resource, also known as a flow resource, is a natural resource which will replenish to replace the portion depleted by usage and consumption, either through natural reproduction or other recurring processes in a finite amount of ti ...
, easily obtained from sugar or
starch Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human diets ...
in crops and other agricultural produce such as
grain A grain is a small, hard, dry fruit ( caryopsis) – with or without an attached hull layer – harvested for human or animal consumption. A grain crop is a grain-producing plant. The two main types of commercial grain crops are cereals and legu ...
, sugarcane, sugar beets or even
lactose Lactose is a disaccharide sugar synthesized by galactose and glucose subunits and has the molecular formula C12H22O11. Lactose makes up around 2–8% of milk (by mass). The name comes from ' (gen. '), the Latin word for milk, plus the suffix ...
. Since ethanol occurs in nature whenever yeast happens to find a sugar solution such as overripe fruit, most organisms have evolved some tolerance to
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a h ...
, whereas methanol is toxic. Other experiments involve
butanol Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C4 H9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; all are a ...
, which can also be produced by fermentation of plants. Support for ethanol comes from the fact that it is a biomass fuel, which addresses
climate change In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to ...
and
greenhouse gas emissions Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and ...
, though these benefits are now highly debated, Oxfam Briefing Paper 114. Originally published online in Science Express on 7 February 2008. See Letters to ''Science'' by Wang and Haq. There are critics to these findings for assuming a worst-case scenario. Originally published online in Science Express on 7 February 2008. There are rebuttals to these findings for assuming a worst-case scenario including the heated 2008 food vs fuel debate. Most modern cars are designed to run on gasoline are capable of running with a blend from 10% up to 15% ethanol mixed into gasoline ( E10-E15). With a small amount of redesign, gasoline-powered vehicles can run on ethanol concentrations as high as 85% ( E85), the maximum set in the United States and Europe due to cold weather during the winter, or up to 100% (
E100 E100 or E-100 may refer to: Electronics * Casio Cassiopeia E-100, a pocket of knife PC * iriver E100, a portable media player Vehicles Automobiles * Baojun E100, a Chinese electric microcar * JMEV E100, a Chinese electric city car * Toyota C ...
) in Brazil, with a warmer climate. Ethanol has close to 34% less energy per volume than gasoline,http://www.eere.energy.go
Energy.gov site
http://www.eia.doe.go
Alternative Fuel Efficiencies in Miles per Gallon
consequently fuel economy ratings with ethanol blends are significantly lower than with pure gasoline, but this lower energy content does not translate directly into a 34% reduction in mileage, because there are many other variables that affect the performance of a particular fuel in a particular engine, and also because ethanol has a higher octane rating which is beneficial to high compression ratio engines. For this reason, for pure or high ethanol blends to be attractive for users, its price must be lower than gasoline to offset the lower fuel economy. As a rule of thumb, Brazilian consumers are frequently advised by the local media to use more alcohol than gasoline in their mix only when ethanol prices are 30% lower or more than gasoline, as ethanol price fluctuates heavily depending on the results and seasonal harvests of sugar cane and by region. In the US, and based on EPA tests for all 2006 E85 models, the average fuel economy for E85 vehicles was found 25.56% lower than unleaded gasoline. The EPA-rated mileage of current American flex-fuel vehicles could be considered when making price comparisons, though E85 has octane rating of about 104 and could be used as a substitute for premium gasoline. Regional retail E85 prices vary widely across the US, with more favorable prices in the Midwest region, where most corn is grown and ethanol produced. In August 2008 the US average spread between the price of E85 and gasoline was 16.9%, while in
Indiana Indiana () is a U.S. state in the Midwestern United States. It is the 38th-largest by area and the 17th-most populous of the 50 States. Its capital and largest city is Indianapolis. Indiana was admitted to the United States as the 19th ...
was 35%, 30% in
Minnesota Minnesota () is a state in the upper midwestern region of the United States. It is the 12th largest U.S. state in area and the List of U.S. states and territories by population, 22nd most populous, with over 5.75 million residents. Minne ...
and
Wisconsin Wisconsin () is a state in the upper Midwestern United States. Wisconsin is the 25th-largest state by total area and the 20th-most populous. It is bordered by Minnesota to the west, Iowa to the southwest, Illinois to the south, Lake M ...
, 19% in
Maryland Maryland ( ) is a U.S. state, state in the Mid-Atlantic (United States), Mid-Atlantic region of the United States. It shares borders with Virginia, West Virginia, and the District of Columbia to its south and west; Pennsylvania to its north; ...
, 12 to 15% in California, and just 3% in
Utah Utah ( , ) is a state in the Mountain West subregion of the Western United States. Utah is a landlocked U.S. state bordered to its east by Colorado, to its northeast by Wyoming, to its north by Idaho, to its south by Arizona, and to its ...
. Depending on the vehicle capabilities, the break even price of E85 usually has to be between 25 and 30% lower than gasoline. Reacting to the high price of oil and its growing dependence on imports, in 1975
Brazil Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...
launched the Pro-alcool program, a huge government-subsidized effort to manufacture ethanol fuel (from its sugar cane crop) and ethanol-powered automobiles. These ethanol-only vehicles were very popular in the 1980s, but became economically impractical when oil prices fell – and sugar prices rose – late in that decade. In May 2003
Volkswagen Volkswagen (),English: , . abbreviated as VW (), is a German motor vehicle manufacturer headquartered in Wolfsburg, Lower Saxony, Germany. Founded in 1937 by the German Labour Front under the Nazi Party and revived into a global brand post ...
built for the first time a commercial ethanol flexible fuel car, the Gol 1.6 Total Flex. These vehicles were a commercial success and by early 2009 other nine Brazilian manufacturers are producing flexible fuel vehicles: Chevrolet,
Fiat Fiat Automobiles S.p.A. (, , ; originally FIAT, it, Fabbrica Italiana Automobili di Torino, lit=Italian Automobiles Factory of Turin) is an Italian automobile manufacturer, formerly part of Fiat Chrysler Automobiles, and since 2021 a subsidiary ...
, Ford, Peugeot,
Renault Groupe Renault ( , , , also known as the Renault Group in English; legally Renault S.A.) is a French multinational automobile manufacturer established in 1899. The company produces a range of cars and vans, and in the past has manufacture ...
,
Honda is a Japanese public multinational conglomerate manufacturer of automobiles, motorcycles, and power equipment, headquartered in Minato, Tokyo, Japan. Honda has been the world's largest motorcycle manufacturer since 1959, reaching a producti ...
,
Mitsubishi The is a group of autonomous Japanese multinational companies in a variety of industries. Founded by Yatarō Iwasaki in 1870, the Mitsubishi Group historically descended from the Mitsubishi zaibatsu, a unified company which existed from 187 ...
,
Toyota is a Japanese multinational automotive manufacturer headquartered in Toyota City, Aichi, Japan. It was founded by Kiichiro Toyoda and incorporated on . Toyota is one of the largest automobile manufacturers in the world, producing about 10 ...
, Citroën, and Nissan. The adoption of the flex technology was so rapid, that flexible fuel cars reached 87.6% of new car sales in July 2008. As of August 2008, the fleet of "flex" automobiles and light commercial vehicles had reached 6 million new vehicles sold, representing almost 19% of all registered light vehicles. As of March 31, 2008, DENATRAN reports a total fleet of 50 million, including motorcycles, trucks and special equipment, and 32 million automobiles and light commercial vehicles. The rapid success of "flex" vehicles, as they are popularly known, was made possible by the existence of 33,000 filling stations with at least one ethanol pump available by 2006, a heritage of the ''Pro-alcool'' program. ''See Chapter 6. Homegrown Energy.'' In the United States, initial support to develop alternative fuels by the government was also a response to the 1973 oil crisis, and later on, as a goal to improve air quality. Also, liquid fuels were preferred over gaseous fuels not only because they have a better volumetric energy density but also because they were the most compatible fuels with existing distribution systems and engines, thus avoiding a big departure from the existing technologies and taking advantage of the vehicle and the refueling infrastructure. California led the search of sustainable alternatives with interest in methanol. In 1996, a new FFV Ford Taurus was developed, with models fully capable of running either methanol or ethanol blended with gasoline. This ethanol version of the Taurus was the first commercial production of an E85 FFV. The momentum of the FFV production programs at the American car companies continued, although by the end of the 1990s, the emphasis was on the FFV E85 version, as it is today. Ethanol was preferred over methanol because there is a large support in the farming community and thanks to government's incentive programs and corn-based ethanol subsidies. Sweden also tested both the M85 and the E85 flexifuel vehicles, but due to agriculture policy, in the end emphasis was given to the ethanol flexifuel vehicles.


Biodiesel

The main benefit of Diesel combustion engines is that they have a 44% fuel burn efficiency; compared with just 25–30% in the best gasoline engines. In addition diesel fuel has slightly higher energy density by volume than gasoline. This makes Diesel engines capable of achieving much better fuel economy than gasoline vehicles.
Biodiesel Biodiesel is a form of diesel fuel derived from plants or animals and consisting of long-chain fatty acid esters. It is typically made by chemically reacting lipids such as animal fat ( tallow), soybean oil, or some other vegetable oil ...
(fatty acid methyl ester), is commercially available in most oilseed-producing states in the United States. As of 2005, it is somewhat more expensive than fossil diesel, though it is still commonly produced in relatively small quantities (in comparison to petroleum products and ethanol). Many farmers who raise oilseeds use a biodiesel blend in tractors and equipment as a matter of policy, to foster production of biodiesel and raise public awareness. It is sometimes easier to find biodiesel in rural areas than in cities. Biodiesel has lower energy density than fossil diesel fuel, so biodiesel vehicles are not quite able to keep up with the fuel economy of a fossil fuelled diesel vehicle, if the diesel injection system is not reset for the new fuel. If the injection timing is changed to take account of the higher cetane value of biodiesel, the difference in economy is negligible. Because biodiesel contains more oxygen than diesel or vegetable oil fuel, it produces the lowest emissions from diesel engines, and is lower in most emissions than gasoline engines. Biodiesel has a higher lubricity than mineral diesel and is an additive in European pump diesel for lubricity and emissions reduction. Some Diesel-powered cars can run with minor modifications on 100% pure
vegetable oil Vegetable oils, or vegetable fats, are oils extracted from seeds or from other parts of fruits. Like animal fats, vegetable fats are ''mixtures'' of triglycerides. Soybean oil, grape seed oil, and cocoa butter are examples of seed oils, ...
s. Vegetable oils tend to thicken (or solidify if it is waste cooking oil), in cold weather conditions so vehicle modifications (a two tank system with diesel start/stop tank), are essential in order to heat the fuel prior to use under most circumstances. Heating to the temperature of engine coolant reduces fuel viscosity, to the range cited by injection system manufacturers, for systems prior to 'common rail' or 'unit injection ( VW PD)' systems. Waste vegetable oil, especially if it has been used for a long time, may become hydrogenated and have increased acidity. This can cause the thickening of fuel, gumming in the engine and acid damage of the fuel system. Biodiesel does not have this problem, because it is chemically processed to be PH neutral and lower viscosity. Modern low emission diesels (most often Euro -3 and -4 compliant), typical of the current production in the European industry, would require extensive modification of injector system, pumps and seals etc. due to the higher operating pressures, that are designed thinner (heated) mineral diesel than ever before, for atomisation, if they were to use pure vegetable oil as fuel. Vegetable oil fuel is not suitable for these vehicles as they are currently produced. This reduces the market as increasing numbers of new vehicles are not able to use it. However, the German Elsbett company has successfully produced single tank vegetable oil fuel systems for several decades, and has worked with Volkswagen on their TDI engines. This shows that it is technologically possible to use vegetable oil as a fuel in high efficiency / low emission diesel engines. Greasestock is an event held yearly in Yorktown Heights, New York, and is one of the largest showcases of vehicles using waste oil as a biofuel in the United States.


Biogas

Compressed biogas may be used for internal combustion engines after purification of the raw gas. The removal of H2O, H2S and particles can be seen as standard producing a gas which has the same quality as compressed natural gas. The use of biogas is particularly interesting for climates where the waste heat of a biogas powered power plant cannot be used during the summer.


Charcoal

In the 1930s Tang Zhongming made an invention using abundant charcoal resources for Chinese auto market. The charcoal-fuelled car was later used intensively in China, serving the army and conveyancer after the breakout of World War II.


Compressed natural gas

High-pressure
compressed natural gas Compressed natural gas (CNG) is a fuel gas mainly composed of methane (CH4), compressed to less than 1% of the volume it occupies at standard atmospheric pressure. It is stored and distributed in hard containers at a pressure of , usually in ...
(CNG), mainly composed of methane, that is used to fuel normal combustion engines instead of gasoline. Combustion of methane produces the least amount of CO2 of all fossil fuels. Gasoline cars can be retrofitted to CNG and become bifuel
Natural gas vehicle A natural gas vehicle (NGV) is an alternative fuel vehicle that uses compressed natural gas (CNG) or liquefied natural gas (LNG). Natural gas vehicles should not be confused with autogas vehicles powered by liquefied petroleum gas (LPG), mai ...
s (NGVs) as the gasoline tank is kept. The driver can switch between CNG and gasoline during operation.
Natural gas vehicle A natural gas vehicle (NGV) is an alternative fuel vehicle that uses compressed natural gas (CNG) or liquefied natural gas (LNG). Natural gas vehicles should not be confused with autogas vehicles powered by liquefied petroleum gas (LPG), mai ...
s (NGVs) are popular in regions or countries where natural gas is abundant. Widespread use began in the
Po River Valley Po or PO may refer to: Arts and entertainment Fictional characters * Po (Kung Fu Panda), the protagonist of the ''Kung Fu Panda'' franchise * Po, one of the titular ''Teletubbies#Characters, Teletubbies'' * Po, a character in the novel ''Graceling ...
of
Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical ...
, and later became very popular in
New Zealand New Zealand ( mi, Aotearoa ) is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and over 700 List of islands of New Zealand, smaller islands. It is the ...
by the eighties, though its use has declined. , there were 17.8 million
natural gas vehicle A natural gas vehicle (NGV) is an alternative fuel vehicle that uses compressed natural gas (CNG) or liquefied natural gas (LNG). Natural gas vehicles should not be confused with autogas vehicles powered by liquefied petroleum gas (LPG), mai ...
s worldwide, led by Iran with 3.30 million, followed by Pakistan (2.79 million), Argentina (2.29 million), Brazil (1.75 million), China (1.58 million) and India (1.5 million). As of 2010, the Asia-Pacific region led the global market with a share of 54%. ''Click on Ranked by number.'' In Europe they are popular in Italy (730,000), Ukraine (200,000), Armenia (101,352), Russia (100,000) and Germany (91,500), and they are becoming more so as various manufacturers produce factory made cars, buses, vans and heavy vehicles. In the United States CNG powered buses are the favorite choice of several
public transit Public transport (also known as public transportation, public transit, mass transit, or simply transit) is a system of transport for passengers by group travel systems available for use by the general public unlike private transport, typic ...
agencies, with an estimated CNG bus fleet of some 130,000. Other countries where CNG-powered buses are popular include India, Australia, Argentina, and Germany. CNG vehicles are common in South America, where these vehicles are mainly used as
taxicab A taxi, also known as a taxicab or simply a cab, is a type of vehicle for hire with a driver, used by a single passenger or small group of passengers, often for a non-shared ride. A taxicab conveys passengers between locations of their choi ...
s in main cities of Argentina and Brazil. Normally, standard gasoline vehicles are retrofitted in specialized shops, which involve installing the gas cylinder in the trunk and the CNG injection system and electronics. The Brazilian GNV fleet is concentrated in the cities of
Rio de Janeiro Rio de Janeiro ( , , ; literally 'River of January'), or simply Rio, is the capital of the Rio de Janeiro (state), state of the same name, Brazil's List of Brazilian states by population, third-most populous state, and the List of largest citi ...
and
São Paulo São Paulo (, ; Portuguese for 'Saint Paul') is the most populous city in Brazil, and is the capital of the state of São Paulo, the most populous and wealthiest Brazilian state, located in the country's Southeast Region. Listed by the Ga ...
. Pike Research reports that almost 90% of NGVs in Latin America have bi-fuel engines, allowing these vehicles to run on either gasoline or CNG. In 2006 the Brazilian subsidiary of
FIAT Fiat Automobiles S.p.A. (, , ; originally FIAT, it, Fabbrica Italiana Automobili di Torino, lit=Italian Automobiles Factory of Turin) is an Italian automobile manufacturer, formerly part of Fiat Chrysler Automobiles, and since 2021 a subsidiary ...
introduced the Fiat Siena Tetra fuel, a four-fuel car developed under Magneti Marelli of
Fiat Fiat Automobiles S.p.A. (, , ; originally FIAT, it, Fabbrica Italiana Automobili di Torino, lit=Italian Automobiles Factory of Turin) is an Italian automobile manufacturer, formerly part of Fiat Chrysler Automobiles, and since 2021 a subsidiary ...
Brazil. This automobile can run on 100% ethanol (
E100 E100 or E-100 may refer to: Electronics * Casio Cassiopeia E-100, a pocket of knife PC * iriver E100, a portable media player Vehicles Automobiles * Baojun E100, a Chinese electric microcar * JMEV E100, a Chinese electric city car * Toyota C ...
), E25 (Brazil's normal ethanol gasoline blend), pure gasoline (not available in Brazil), and natural gas, and switches from the gasoline-ethanol blend to CNG automatically, depending on the power required by road conditions. Other existing option is to retrofit an ethanol flexible-fuel vehicle to add a natural gas tank and the corresponding injection system. Some
taxicab A taxi, also known as a taxicab or simply a cab, is a type of vehicle for hire with a driver, used by a single passenger or small group of passengers, often for a non-shared ride. A taxicab conveys passengers between locations of their choi ...
s in
São Paulo São Paulo (, ; Portuguese for 'Saint Paul') is the most populous city in Brazil, and is the capital of the state of São Paulo, the most populous and wealthiest Brazilian state, located in the country's Southeast Region. Listed by the Ga ...
and
Rio de Janeiro Rio de Janeiro ( , , ; literally 'River of January'), or simply Rio, is the capital of the Rio de Janeiro (state), state of the same name, Brazil's List of Brazilian states by population, third-most populous state, and the List of largest citi ...
, Brazil, run on this option, allowing the user to choose among three fuels (E25, E100 and CNG) according to current market prices at the pump. Vehicles with this adaptation are known in Brazil as "tri-fuel" cars. HCNG or hydrogen enriched compressed natural gas for automobile use is premixed at the hydrogen station.


Liquefied natural gas

Liquefied natural gas Liquefied natural gas (LNG) is natural gas (predominantly methane, CH4, with some mixture of ethane, C2H6) that has been cooled down to liquid form for ease and safety of non-pressurized storage or transport. It takes up about 1/600th the v ...
(LNG) is natural gas that has been cooled to a point at which it becomes a cryogenic liquid. In this liquid state, natural gas is more than 2 times as dense as highly compressed CNG. LNG fuel systems function on any vehicle capable of burning natural gas. Unlike CNG, which is stored at high pressure (typically 3000 or 3600 psi) and then regulated to a lower pressure that the engine can accept, LNG is stored at low pressure (50 to 150 psi) and simply vaporized by a heat exchanger before entering the fuel metering devices to the engine. Because of its high energy density compared to CNG, it is very suitable for those interested in long ranges while running on natural gas. In the United States, the LNG supply chain is the main thing that has held back this fuel source from growing rapidly. The LNG supply chain is very analogous to that of diesel or gasoline. First, pipeline natural gas is liquefied in large quantities, which is analogous to refining gasoline or diesel. Then, the LNG is transported via semi trailer to fuel stations where it is stored in bulk tanks until it is dispensed into a vehicle. CNG, on the other hand, requires expensive compression at each station to fill the high-pressure cylinder cascades.


Autogas

LPG or liquefied petroleum gas (LPG) is a low pressure liquefied gas mixture composed mainly of propane and butane which burns in conventional gasoline combustion engines with less CO2 than gasoline. Gasoline cars can be retrofitted to LPG aka Autogas and become bifuel vehicles as the gasoline tank is not removed, allowing drivers to switch between LPG and gasoline during operation. Estimated 10 million vehicles running worldwide. There are 17.473 million LPG powered vehicles worldwide as of December 2010, and the leading countries are Turkey (2.394 million vehicles), Poland (2.325 million), and South Korea (2.3 million). See table: Largest autogas markets, 2010 In the U.S., 190,000 on-road vehicles use propane, and 450,000 forklifts use it for power. Whereas it is banned in Pakistan (DEC 2013) as it is considered a risk to public safety by OGRA. Hyundai Motor Company began sales of the
Elantra LPI Hybrid The Hyundai Elantra, also known as the Hyundai Avante ( ko, 현대 아반떼), is a compact car produced by the South Korean manufacturer Hyundai since 1990. The Elantra was initially marketed as the ''Lantra'' in Australia and some European m ...
in the
South Korea South Korea, officially the Republic of Korea (ROK), is a country in East Asia, constituting the southern part of the Korea, Korean Peninsula and sharing a Korean Demilitarized Zone, land border with North Korea. Its western border is formed ...
n domestic market in July 2009. The Elantra LPI (Liquefied Petroleum Injected) is the world's first
hybrid electric vehicle A hybrid electric vehicle (HEV) is a type of hybrid vehicle that combines a conventional internal combustion engine (ICE) system with an electric propulsion system (hybrid vehicle drivetrain). The presence of the electric powertrain is intended ...
to be powered by an internal combustion engine built to run on liquefied petroleum gas (LPG) as a fuel.


Formic acid

Formic acid is used by converting it first to hydrogen, and using that in a hydrogen
fuel cell A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen fuel, hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most bat ...
. It can also be used directly in formic acid fuel cells. Formic acid is much easier to store than hydrogen.


Hydrogen

A
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
car is an automobile which uses hydrogen as its primary source of power for locomotion. These cars generally use the hydrogen in one of two methods: combustion or fuel-cell conversion. In combustion, the hydrogen is "burned" in engines in fundamentally the same method as traditional gasoline cars. In fuel-cell conversion, the hydrogen is turned into electricity through fuel cells which then powers electric motors. With either method, the only byproduct from the spent hydrogen is water, however during combustion with air NOx can be produced.
Honda is a Japanese public multinational conglomerate manufacturer of automobiles, motorcycles, and power equipment, headquartered in Minato, Tokyo, Japan. Honda has been the world's largest motorcycle manufacturer since 1959, reaching a producti ...
introduced its fuel cell vehicle in 1999 called the FCX and have since then introduced the second generation FCX Clarity. Limited marketing of the FCX Clarity, based on the 2007 concept model, began in June 2008 in the United States, and it was introduced in Japan in November 2008. The FCX Clarity was available in the U.S. only in Los Angeles Area, where 16 hydrogen filling stations are available, and until July 2009, only 10 drivers have leased the Clarity for US$600 a month. At the 2012
World Hydrogen Energy Conference World Hydrogen Energy Conference (WHEC) is a series of international events covering the complex issues of utilizing hydrogen as an energy carrier. These include methods of production of hydrogen, materials for hydrogen storage, infrastructure d ...
, Daimler AG, Honda, Hyundai and Toyota all confirmed plans to produce hydrogen fuel cell vehicles for sale by 2015, with some types planned to enter the showroom in 2013. From 2008 to 2014, Honda leased a total of 45 FCX units in the US. A small number of prototype hydrogen cars currently exist, and a significant amount of research is underway to make the technology more viable. The common
internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal co ...
, usually fueled with gasoline (petrol) or diesel liquids, can be converted to run on gaseous hydrogen. However, the most efficient use of hydrogen involves the use of
fuel cell A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen fuel, hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most bat ...
s and
electric motor An electric motor is an electrical machine that converts electrical energy into mechanical energy. Most electric motors operate through the interaction between the motor's magnetic field and electric current in a wire winding to generate forc ...
s instead of a traditional engine. Hydrogen reacts with
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as we ...
inside the fuel cells, which produces electricity to power the motors. One primary area of research is hydrogen storage, to try to increase the range of hydrogen vehicles while reducing the weight, energy consumption, and complexity of the storage systems. Two primary methods of storage are metal hydrides and compression. Some believe that hydrogen cars will never be economically viable and that the emphasis on this technology is a diversion from the development and popularization of more efficient hybrid cars and other alternative technologies. A study by The Carbon Trust for the UK Department of Energy and Climate Change suggests that hydrogen technologies have the potential to deliver UK transport with near-zero emissions whilst reducing dependence on imported oil and curtailment of renewable generation. However, the technologies face very difficult challenges, in terms of cost, performance and policy.
Bus A bus (contracted from omnibus, with variants multibus, motorbus, autobus, etc.) is a road vehicle that carries significantly more passengers than an average car or van. It is most commonly used in public transport, but is also in use for cha ...
es, trains, PHB bicycles, canal boats,
cargo bikes A cargo bike (also known as a box bike, carrier cycle, freight bicycle, cycletruck, or freight tricycle) is a human powered vehicle designed and constructed specifically for transporting loads. Cargo bike designs include a cargo area consisting o ...
,
golf cart A golf cart (alternatively known as a golf buggy or golf car) is a small motorized vehicle designed originally to carry two golfers and their golf clubs around a golf course with less effort than walking. Over time, variants were introduced ...
s,
motorcycles A motorcycle (motorbike, bike, or trike (if three-wheeled)) is a two or three-wheeled motor vehicle steered by a handlebar. Motorcycle design varies greatly to suit a range of different purposes: long-distance travel, commuting, cruisin ...
, wheelchairs, ships, airplanes, submarines, and
rocket A rocket (from it, rocchetto, , bobbin/spool) is a vehicle that uses jet propulsion to accelerate without using the surrounding air. A rocket engine produces thrust by reaction to exhaust expelled at high speed. Rocket engines work entire ...
s can already run on hydrogen, in various forms.
NASA The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeedi ...
used hydrogen to launch
Space Shuttle The Space Shuttle is a retired, partially reusable low Earth orbital spacecraft system operated from 1981 to 2011 by the U.S. National Aeronautics and Space Administration (NASA) as part of the Space Shuttle program. Its official program na ...
s into space. A working toy model car runs on
solar power Solar power is the conversion of energy from sunlight into electricity, either directly using photovoltaics (PV) or indirectly using concentrated solar power. Photovoltaic cells convert light into an electric current using the photovoltaic ef ...
, using a
regenerative fuel cell A regenerative fuel cell or reverse fuel cell (RFC) is a fuel cell run in reverse mode, which consumes electricity and chemical B to produce chemical A. By definition, the process of any fuel cell could be reversed. However, a given device is usuall ...
to store energy in the form of hydrogen and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as we ...
gas. It can then convert the fuel back into water to release the solar energy. BMW's Clean Energy internal combustion hydrogen car has more power and is faster than hydrogen fuel cell electric cars. A limited series production of the 7 Series Saloon was announced as commencing at the end of 2006. A BMW hydrogen prototype (H2R) using the driveline of this model broke the speed record for hydrogen cars at 300 km/h (186 mi/h), making automotive history. Mazda has developed Wankel engines to burn hydrogen. The Wankel uses a rotary principle of operation, so the hydrogen burns in a different part of the engine from the intake. This reduces pre-detonation, a problem with hydrogen fueled piston engines. The other major car companies like Daimler, Chrysler, Honda, Toyota, Ford and General Motors, are investing in hydrogen fuel cells instead. VW, Nissan, and Hyundai/Kia also have fuel cell vehicle prototypes on the road. In addition, transit agencies across the globe are running prototype fuel cell buses. Fuel cell vehicles, such as the new Honda Clarity, can get up to on a kilogram of hydrogen. The Hyundai ix35 FCEV fuel cell vehicle is available for lease in the U.S. In 2014, a total of 54 units were leased. Sales of the Toyota Mirai to government and corporate customers began in Japan on December 15, 2014. Toyota delivered the first market placed Mirai to the Prime Minister's Official Residence and announced it got 1,500 orders in Japan in one month after sales began against a sales target of 400 for 12 months. Deliveries to retail customers began in California in October 2015. A total of 57 units were delivered between October and November 2015. Toyota scheduled to release the Mirai in the
Northeastern States The Northeastern United States, also referred to as the Northeast, the East Coast, or the American Northeast, is a geographic region of the United States. It is located on the Atlantic coast of North America, with Canada to its north, the Southe ...
in the first half of 2016. The market launch in Europe is slated for September 2015.


Liquid nitrogen car

Liquid nitrogen (LN2) is a method of storing energy. Energy is used to liquefy air, and then LN2 is produced by evaporation, and distributed. LN2 is exposed to ambient heat in the car and the resulting nitrogen gas can be used to power a piston or turbine engine. The maximum amount of energy that can be extracted from LN2 is 213 Watt-hours per kg (W·h/kg) or 173 W·h per liter, in which a maximum of 70 W·h/kg can be utilized with an isothermal expansion process. Such a vehicle with a 350-liter (93 gallon) tank can achieve ranges similar to a gasoline powered vehicle with a 50-liter (13 gallon) tank. Theoretical future engines, using cascading topping cycles, can improve this to around 110 W·h/kg with a quasi-isothermal expansion process. The advantages are zero harmful emissions and superior energy densities compared to a compressed-air vehicle as well as being able to refill the tank in a matter of minutes.


Nuclear power

In principle, it is possible to build a vehicle powered by nuclear fission or nuclear decay. However, there are two major problems: first one has to transform the energy, which comes as heat and radiation into energy usable for a drive. One possible would be to use a steam turbine as in a nuclear power plant, but such a device would take too much space. A more suitable way would be direct conversion into electricity for example with thermoelements or thermionic devices. The second problem is that nuclear fission produces high levels of neutron and gamma rays, which require excessive shielding, that would result in a vehicle too large for use on public roads. However studies were made in this way by Ford Nucleon. A better way for a nuclear powered vehicle would be the use of power of radioactive decay in radioisotope thermoelectric generators, which are also very safe and reliable. The required shielding of these devices depends on the used radio nuclide. Plutonium-238 as nearly pure alpha radiator does not require much shielding. As prices for suitable radionuclide are high and energy density is low (generating 1 watt with Plutonium-238 requires a half gram of it), this way of propulsion is too expensive for wide use. Also radioisotope thermoelectric generators offer according to their large content of high radioactive material an extreme danger in case of misuse for example by terrorists. The only vehicle in use, which is driven by radioisotope thermoelectric generators is the Mars rover Curiosity. Other forms of nuclear power as fusion and annihilation are at present not available for vehicle propulsion, as no working fusion reactor is available and it is questionable if one can ever built one with a size suitable for a road vehicle. Annihilation may perhaps work in some ways (see
antimatter drive An antimatter rocket is a proposed class of rockets that use antimatter as their power source. There are several designs that attempt to accomplish this goal. The advantage to this class of rocket is that a large fraction of the rest mass of ...
), but there is no technology existing to produce and store enough antimatter.


Flywheels

Flywheels can be also used for alternative fuel and were used in the 1950s for the propulsion of buses in Switzerland, the such called
gyrobus A gyrobus is an electric bus that uses flywheel energy storage, not overhead wires like a trolleybus. The name comes from the Greek language term for flywheel, ''gyros''. While there are no gyrobuses currently in use commercially, development in ...
es. The flywheel of the bus was loaded up by electric power at the terminals of the line and allowed it to travel a way up to 8 kilometres just with its flywheel. Flywheel-powered vehicles are quieter than vehicles with combustion engine, require no overhead wire and generate no exhausts, but the flywheel device has a great weight (1.5 tons for 5 kWh) and requires special safety measures due to its high rotational speed.


Silanes

Silanes higher than heptasilane can be stored like gasoline and may also work as fuel. They have the advantage that they can also burn with the nitrogen of the air, but have as major disadvantage its high price and that its combustion products are solid, which gives trouble in combustion engines.


Spring

The power of wound-up springs or twisted rubber cords can be used for the propulsion of small vehicles. However this way of energy storage allows only saving small energy amounts not suitable for the propulsion of vehicles for transporting people. Spring-powered vehicles are wind-up toys or mousetrap cars.


Steam

A steam car is a car that has a
steam engine A steam engine is a heat engine that performs mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a cylinder. This pushing force can be ...
. Wood, coal,
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a h ...
, or others can be used as
fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy bu ...
. The fuel is burned in a
boiler A boiler is a closed vessel in which fluid (generally water) is heated. The fluid does not necessarily boil. The heated or vaporized fluid exits the boiler for use in various processes or heating applications, including water heating, centr ...
and the heat converts water into
steam Steam is a substance containing water in the gas phase, and sometimes also an aerosol of liquid water droplets, or air. This may occur due to evaporation or due to boiling, where heat is applied until water reaches the enthalpy of vaporizat ...
. When the water turns to steam, it expands. The expansion creates
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country a ...
. The pressure pushes the
piston A piston is a component of reciprocating engines, reciprocating pumps, gas compressors, hydraulic cylinders and pneumatic cylinders, among other similar mechanisms. It is the moving component that is contained by a cylinder and is made gas- ...
s back and forth. This turns the driveshaft to spin the wheels which provides moves the car forward. It works like a coal-fueled steam train, or steam boat. The steam car was the next logical step in independent transport. Steam cars take a long time to start, but some can reach speeds over 100 mph (161 km/h) eventually. The late model Doble steam cars could be brought to operational condition in less than 30 seconds, had high top speeds and fast acceleration, but were expensive to buy. A steam engine uses external combustion, as opposed to internal combustion. Gasoline-powered cars are more efficient at about 25–28% efficiency. In theory, a
combined cycle A combined cycle power plant is an assembly of heat engines that work in tandem from the same source of heat, converting it into mechanical energy. On land, when used to make electricity the most common type is called a combined cycle gas tu ...
steam engine in which the burning material is first used to drive a
gas turbine A gas turbine, also called a combustion turbine, is a type of continuous flow internal combustion engine. The main parts common to all gas turbine engines form the power-producing part (known as the gas generator or core) and are, in the directio ...
can produce 50% to 60% efficiency. However, practical examples of steam engined cars work at only around 5–8% efficiency. The best known and best selling steam-powered car was the Stanley Steamer. It used a compact fire-tube boiler under the hood to power a simple two-piston engine which was connected directly to the rear axle. Before
Henry Ford Henry Ford (July 30, 1863 – April 7, 1947) was an American Technological and industrial history of the United States, industrialist, business magnate, founder of the Ford Motor Company, and chief developer of the assembly line technique of ...
introduced monthly payment financing with great success, cars were typically purchased outright. This is why the Stanley was kept simple; to keep the purchase price affordable. Steam produced in
refrigeration The term refrigeration refers to the process of removing heat from an enclosed space or substance for the purpose of lowering the temperature.International Dictionary of Refrigeration, http://dictionary.iifiir.org/search.phpASHRAE Terminology, ht ...
also can be use by a turbine in other vehicle types to produce electricity, that can be employed in electric motors or stored in a battery. Steam power can be combined with a standard oil-based engine to create a hybrid. Water is injected into the cylinder after the fuel is burned, when the piston is still superheated, often at temperatures of 1500 degrees or more. The water will instantly be vaporized into steam, taking advantage of the heat that would otherwise be wasted.


Wind

Wind-powered vehicles have been well-known for a long time. They can be realized with sails similar to those used on ships, by using an onboard wind turbine, which drives the wheels directly or which generates electricity for an electric motor, or can be pulled by a kite. Wind-powered land vehicles need an enormous clearance in height, especially when sails or kites are used and are unsuitable in urban area. They may be also be difficult to steer. Wind-powered vehicles are only used for recreational activities on beaches or other free areas. The concept is described in further detail here


Wood gas

Wood gas can be used to power cars with ordinary internal combustion engines if a
wood gasifier A wood gas generator is a gasification unit which converts timber or charcoal into wood gas, a producer gas consisting of atmospheric nitrogen, carbon monoxide, hydrogen, traces of methane, and other gases, which – after cooling and filtering ...
is attached. This was quite popular during World War II in several European and Asian countries because the war prevented easy and cost-effective access to oil. Herb Hartman of Woodward, Iowa currently drives a wood powered Cadillac. He claims to have attached the gasifier to the Cadillac for just $700. Hartman claims, "A full hopper will go about fifty miles depending on how you drive it," and he added that splitting the wood was "labor-intensive. That's the big drawback."


Multiple fuel source


Dual fuel

Dual fuel vehicle is referred as the vehicle using two types of fuel in the same time (can be gas + liquid, gas + gas, liquid + liquid) with different fuel tank. Diesel-CNG dual fuel is a system using two type of fuel which are diesel and compressed natural gas (CNG) at the same time. It is because of CNG need a source of ignition for combustion in diesel engine.


Flexible fuel

A flexible-fuel vehicle (FFV) or dual-fuel vehicle (DFF) is an alternative fuel automobile or light duty truck with a multifuel engine that can use more than one
fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy bu ...
, usually mixed in the same tank, and the blend is burned in the
combustion chamber A combustion chamber is part of an internal combustion engine in which the fuel/air mix is burned. For steam engines, the term has also been used for an extension of the firebox which is used to allow a more complete combustion process. Intern ...
together. These vehicles are
colloquial Colloquialism (), also called colloquial language, everyday language or general parlance, is the linguistic style used for casual (informal) communication. It is the most common functional style of speech, the idiom normally employed in convers ...
ly called flex-fuel, or flexifuel in Europe, or just flex in Brazil. FFVs are distinguished from bi-fuel vehicles, where two fuels are stored in separate tanks. The most common commercially available FFV in the world market is the
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a h ...
flexible-fuel vehicle, with the major markets concentrated in the United States, Brazil, Sweden, and some other European countries. In addition to flex-fuel vehicles running with
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a h ...
, in the US and Europe there were successful test programs with methanol flex-fuel vehicles, known as M85 FFVs, and more recently there have been also successful tests using p-series fuels with E85 flex fuel vehicles, but as of June 2008, this fuel is not yet available to the general public. Ethanol flexible-fuel vehicles have standard gasoline engines that are capable of running with
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a h ...
and gasoline mixed in the same tank. These mixtures have "E" numbers which describe the percentage of ethanol in the mixture, for example, E85 is 85% ethanol and 15% gasoline. (See common ethanol fuel mixtures for more information.) Though technology exists to allow ethanol FFVs to run on any mixture up to E100, in the U.S. and Europe, flex-fuel vehicles are optimized to run on E85. This limit is set to avoid cold starting problems during very cold weather. The alcohol content might be reduced during the winter, to E70 in the U.S. or to E75 in Sweden. Brazil, with a warmer climate, developed vehicles that can run on any mix up to
E100 E100 or E-100 may refer to: Electronics * Casio Cassiopeia E-100, a pocket of knife PC * iriver E100, a portable media player Vehicles Automobiles * Baojun E100, a Chinese electric microcar * JMEV E100, a Chinese electric city car * Toyota C ...
, though E20-E25 is the mandatory minimum blend, and no pure gasoline is sold in the country. About 48 million automobiles, motorcycles and light duty trucks manufactured and sold worldwide by mid 2015, and concentrated in four markets, Brazil (29.5 million by mid 2015), the United States (17.4 million by the end of 2014), Canada (1.6 million by 2014), and Sweden (243,100 through December 2014). ''As of September 2013, see Graph "Bought flexifuel vehicles"'' ''Download file "Definitiva nyregistreringar 2012" see table: "Nyregistrerade miljöbilar per typ december 2012" with summary of E85 passenger car registrations for 2012 and 2011'' ''Download file "Nyregistreringar december 2014 (prel)" see table: "Nyregistrerade miljöbilar per typ december 2014" with summary of E85 passenger car registrations for 2014 and 2013'' The Brazilian flex fuel fleet includes over 4 million flexible-fuel motorcycles produced since 2009 through March 2015. In Brazil, 65% of flex-fuel car owners were using ethanol fuel regularly in 2009, while, the actual number of American FFVs being run on E85 is much lower; surveys conducted in the U.S. have found that 68% of American flex-fuel car owners were not aware they owned an E85 flex. This is thought to be due to a number of factors, including: *The appearance of flex-fuel and non-flex-fuel vehicles is identical; *There is no price difference between a pure-gasoline vehicle and its flex-fuel variant; *The lack of consumer awareness of flex-fuel vehicles; *The lack of promotion of flex-fuel vehicles by American automakers, who often do not label the cars or market them in the same way they do to
hybrid cars A hybrid vehicle is one that uses two or more distinct types of power, such as submarines that use diesel when surfaced and batteries when submerged. Other means to store energy include pressurized fluid in hydraulic hybrids. The basic princi ...
By contrast, automakers selling FFVs in Brazil commonly affix badges advertising the car as a flex-fuel vehicle. As of 2007, new FFV models sold in the U.S. were required to feature a yellow gas cap emblazoned with the label "E85/gasoline", in order to remind drivers of the cars' flex-fuel capabilities. Use of E85 in the U.S. is also affected by the relatively low number of E85 filling stations in operation across the country, with just over 1,750 in August 2008, most of which are concentrated in the Corn Belt states, led by
Minnesota Minnesota () is a state in the upper midwestern region of the United States. It is the 12th largest U.S. state in area and the List of U.S. states and territories by population, 22nd most populous, with over 5.75 million residents. Minne ...
with 353 stations, followed by
Illinois Illinois ( ) is a state in the Midwestern United States. Its largest metropolitan areas include the Chicago metropolitan area, and the Metro East section, of Greater St. Louis. Other smaller metropolitan areas include, Peoria and Roc ...
with 181, and
Wisconsin Wisconsin () is a state in the upper Midwestern United States. Wisconsin is the 25th-largest state by total area and the 20th-most populous. It is bordered by Minnesota to the west, Iowa to the southwest, Illinois to the south, Lake M ...
with 114. ''For a complete and updated listing, go to www.e85refueling.com'' By comparison, there are some 120,000 stations providing regular non-ethanol gasoline in the United States alone. There have been claims that American automakers are motivated to produce flex-fuel vehicles due to a loophole in the Corporate Average Fuel Economy (CAFE) requirements, which gives the automaker a "fuel economy credit" for every flex-fuel vehicle sold, whether or not the vehicle is actually fueled with E85 in regular use. This loophole allegedly allows the U.S. auto industry to meet CAFE fuel economy targets not by developing more fuel-efficient models, but by spending between US$100 and US$200 extra per vehicle to produce a certain number of flex-fuel models, enabling them to continue selling less fuel-efficient vehicles such as SUVs, which netted higher profit margins than smaller, more fuel-efficient cars. In the United States, E85 FFVs are equipped with sensor that automatically detect the fuel mixture, signaling the ECU to tune spark timing and fuel injection so that fuel will burn cleanly in the vehicle's internal combustion engine. Originally, the sensors were mounted in the fuel line and exhaust system; more recent models do away with the fuel line sensor. Another feature of older flex-fuel cars is a small separate gasoline storage tank that was used for starting the car on cold days, when the ethanol mixture made ignition more difficult. Modern
Brazil Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...
ian flex-fuel technology enables FFVs to run an any blend between E20-E25
gasohol Several common ethanol fuel mixtures are in use around the world. The use of pure hydrous or anhydrous ethanol in internal combustion engines (ICEs) is only possible if the engines are designed or modified for that purpose, and used only in autom ...
and E100 ethanol fuel, using a lambda probe to measure the quality of combustion, which informs the engine control unit as to the exact composition of the gasoline-alcohol mixture. This technology, developed by the Brazilian subsidiary of Bosch in 1994, and further improved and commercially implemented in 2003 by the Italian subsidiary of Magneti Marelli, is known as "
Software Fuel Sensor Software is a set of computer programs and associated documentation and data. This is in contrast to hardware, from which the system is built and which actually performs the work. At the lowest programming level, executable code consists o ...
". The Brazilian subsidiary of Delphi Automotive Systems developed a similar technology, known as " Multifuel", based on research conducted at its facility in
Piracicaba Piracicaba ( or ) is a city located in the Brazilian state of São Paulo. The population is 407,252 (2020) in an area of 1378.07 km². It is at an elevation of 547 m above sea level. Name The place name comes from a word in the Tupi langu ...
,
São Paulo São Paulo (, ; Portuguese for 'Saint Paul') is the most populous city in Brazil, and is the capital of the state of São Paulo, the most populous and wealthiest Brazilian state, located in the country's Southeast Region. Listed by the Ga ...
. Print edition No. 1941 This technology allows the controller to regulate the amount of fuel injected and spark time, as fuel flow needs to be decreased to avoid
detonation Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with ...
due to the high compression ratio (around 12:1) used by flex-fuel engines. The first flex motorcycle was launched by
Honda is a Japanese public multinational conglomerate manufacturer of automobiles, motorcycles, and power equipment, headquartered in Minato, Tokyo, Japan. Honda has been the world's largest motorcycle manufacturer since 1959, reaching a producti ...
in March 2009. Produced by its Brazilian subsidiary Moto Honda da Amazônia, the CG 150 Titan Mix is sold for around US$2,700. Because the motorcycle does not have a secondary gas tank for a cold start like the Brazilian flex cars do, the tank must have at least 20% of gasoline to avoid start up problems at temperatures below 15 °C (59 °F). The motorcycle's panel includes a gauge to warn the driver about the actual ethanol-gasoline mix in the storage tank.


Hybrids


Hybrid electric vehicle

A
hybrid vehicle A hybrid vehicle is one that uses two or more distinct types of power, such as submarines that use diesel when surfaced and batteries when submerged. Other means to store energy include pressurized fluid in hydraulic hybrids. The basic princi ...
uses multiple propulsion systems to provide motive power. The most common type of hybrid vehicle is the gasoline-electric hybrid vehicles, which use gasoline (petrol) and electric batteries for the energy used to power internal-combustion engines (ICEs) and electric motors. These motors are usually relatively small and would be considered "underpowered" by themselves, but they can provide a normal driving experience when used in combination during acceleration and other maneuvers that require greater power. The
Toyota Prius The is a car built by Toyota which has a hybrid drivetrain, combining an internal combustion engine with an electric motor. Initially offered as a four-door sedan, it has been produced only as a five-door liftback since 2003. In 2007, t ...
first went on sale in Japan in 1997 and it is sold worldwide since 2000. By 2017 the Prius is sold in more than 90 countries and regions, with Japan and the United States as its largest markets. In May 2008, global cumulative Prius sales reached the 1 million units, and by September 2010, the Prius reached worldwide cumulative sales of 2 million units, and 3 million units by June 2013. , global hybrid sales are led by the Prius family, with cumulative sales of 6.0361 million units, excluding its plug-in hybrid variant. The
Toyota Prius The is a car built by Toyota which has a hybrid drivetrain, combining an internal combustion engine with an electric motor. Initially offered as a four-door sedan, it has been produced only as a five-door liftback since 2003. In 2007, t ...
liftback is the leading model of the Toyota brand with cumulative sales of 3.985 million units, followed by the Toyota Aqua/Prius c, with global sales of 1.380 million units, the Prius v/α/+ with 671,200, the
Camry Hybrid The Toyota Camry (; Japanese: トヨタ・カムリ ''Toyota Kamuri'') is an automobile sold internationally by the Japanese auto manufacturer Toyota since 1982, spanning multiple generations. Originally compact in size (narrow-body), the Camry ...
with 614,700 units, the Toyota Auris with 378,000 units, and the Toyota Yaris Hybrid with 302,700. The best-selling Lexus model is the Lexus RX 400h/RX 450h with global sales of 363,000 units. The Honda Insight is a two-seater hatchback hybrid automobile manufactured by Honda. It was the first mass-produced hybrid automobile sold in the United States, introduced in 1999, and produced until 2006. Honda introduced the second-generation Insight in Japan in February 2009, and the new Insight went on sale in the United States on April 22, 2009. Honda also offers the Honda Civic Hybrid since 2002. , there are over 50 models of hybrid electric cars available in several world markets, with more than 12 million hybrid electric vehicles sold worldwide since their inception in 1997. , Japan ranked as the market leader with more than 5 million hybrids sold, followed by the United States with cumulative sales of over 4 million units since 1999, and Europe with about 1.5 million hybrids delivered since 2000. Japan has the world's highest hybrid market penetration. By 2013 the hybrid market share accounted for more than 30% of new standard passenger car sold, and about 20% new passenger vehicle sales including kei cars. The Netherlands ranks second with a hybrid market share of 4.5% of new car sales in 2012. ''See Figure 1.3, pp 6. See also tables in pp. 88–110 for HEV market by country from 2001 to 2012.'' , global sales are by Toyota Motor Company with more than 10 million Lexus and Toyota hybrids sold, followed by Honda Motor Co., Ltd. with cumulative global sales of more than 1.35 million hybrids ; ''Honda sold 187,851 hybrids in 2013''. ''Honda sold 158,696 hybrids during the first six months of 2014''.
Ford Motor Corporation Ford Motor Company (commonly known as Ford) is an American multinational automobile manufacturer headquartered in Dearborn, Michigan, United States. It was founded by Henry Ford and incorporated on June 16, 1903. The company sells automobile ...
with over 424 thousand hybrids sold in the United States through June 2015, of which, around 10% are
plug-in hybrid A plug-in hybrid electric vehicle (PHEV) is a hybrid electric vehicle whose battery pack can be recharged by plugging a charging cable into an external electric power source, in addition to internally by its on-board internal combustion engin ...
s; ''By June 2012 Ford had sold 200,000 full hybrids in the US since 2004.'' ''See the section: December 2012 Hybrid Cars Numbers. A total of 434,498 hybrid electric vehicles were sold during 2012. Ford sold 32,543 hybrids in the U.S. during 2012, including 14,100 Ford Fusion Hybrids, 10,935 C-Max Hybrids, 6,067 Lincoln MKZ Hybrids, and 1,441 Ford Escape Hybrids.''
Hyundai Group Hyundai Group (; ) is a South Korean conglomerate founded by Chung Ju-yung. The first company in the group was founded in 1947 as a construction company. With government assistance, Chung and his family members rapidly expanded into various i ...
with cumulative global sales of 200 thousand hybrids , including both Hyundai Motors and
Kia Motors Kia Corporation, commonly known as Kia (, ; formerly known as Kyungsung Precision Industry and Kia Motors Corporation), is a South Korean multinational automobile manufacturer headquartered in Seoul, South Korea. It is South Korea's second la ...
hybrid models; and
PSA Peugeot Citroën The PSA Group (), legally known as Peugeot S.A. (Peugeot Société Anonyme, trading as Groupe PSA; formerly known as PSA Peugeot Citroën from 1991 to 2016) was a French Multinational corporation, multinational Automotive industry, automotive ma ...
with over 50,000 diesel-powered hybrids sold in Europe through December 2013. The
Elantra LPI Hybrid The Hyundai Elantra, also known as the Hyundai Avante ( ko, 현대 아반떼), is a compact car produced by the South Korean manufacturer Hyundai since 1990. The Elantra was initially marketed as the ''Lantra'' in Australia and some European m ...
, launched in the South Korean domestic market in July 2009, is a hybrid vehicle powered by an internal combustion engine built to run on liquefied petroleum gas (LPG) as a fuel. The Elantra PLI is a
mild hybrid Mild hybrids (also known as power-assist hybrids, battery-assisted hybrid vehicles or BAHVs) are generally cars with an internal combustion engine equipped with an electric machine (one motor/generator in a parallel hybrid configuration) allowing ...
and the first hybrid to adopt advanced lithium polymer (Li–Poly) batteries.


Plug-in hybrid electric vehicle

Until 2010 most
plug-in hybrid A plug-in hybrid electric vehicle (PHEV) is a hybrid electric vehicle whose battery pack can be recharged by plugging a charging cable into an external electric power source, in addition to internally by its on-board internal combustion engin ...
s on the road in the U.S. were conversions of conventional hybrid electric vehicles, and the most prominent PHEVs were conversions of 2004 or later Toyota Prius, which have had plug-in charging and more batteries added and their electric-only range extended. Chinese battery manufacturer and automaker BYD Auto released the
F3DM The BYD F3DM (Dual-mode) was a plug-in hybrid compact sedan manufactured by BYD with an all-electric range of and a hybrid electric powertrain that can extend the range an additional . The F3DM is the world's first mass-produced plug-in hybrid ...
to the Chinese fleet market in December 2008Crippen, A. (December 15, 2008
"Warren Buffett's Electric Car Hits the Chinese Market, But Rollout Delayed For U.S. & Europe"
''CNBC''. Retrieved December 2008.
Balfour, F. (December 15, 200

''Business Week''. Retrieved December 2008.
and began sales to the general public in
Shenzhen Shenzhen (; ; ; ), also historically known as Sham Chun, is a major Sub-provincial division, sub-provincial city and one of the Special economic zones of China, special economic zones of China. The city is located on the east bank of the Pea ...
in March 2010. General Motors began deliveries of the Chevrolet Volt in the U.S. in December 2010. Deliveries to retail customers of the
Fisker Karma The Fisker Karma is a luxury vehicle, luxury plug-in Range extender (vehicle), range-extended electric sports sedan produced by Fisker Automotive in 2012. The cars were manufactured at Valmet Automotive in Finland. The United States Environm ...
began in the U.S. in November 2011. During 2012, the
Toyota Prius Plug-in Hybrid The Toyota Prius Plug-in Hybrid (often abbreviated as the Prius and known as the Prius Prime in North America, South Korea, and New Zealand) is a plug-in hybrid liftback manufactured by Toyota. The first-generation model was produced from 2012 t ...
, Ford C-Max Energi, and Volvo V60 Plug-in Hybrid were released. The following models were launched during 2013 and 2015: Honda Accord Plug-in Hybrid, Mitsubishi Outlander P-HEV, Ford Fusion Energi, McLaren P1 (limited edition), Porsche Panamera S E-Hybrid, BYD Qin, Cadillac ELR, BMW i3 REx, BMW i8, Porsche 918 Spyder (limited production), Volkswagen XL1 (limited production), Audi A3 Sportback e-tron, Volkswagen Golf GTE,
Mercedes-Benz S 500 e The Mercedes-Benz W222 is the sixth generation of the S-Class produced from 2013 to 2020, the successor of the W221 S-Class and the predecessor of the W223 S-Class. The W222 was designed during 2009. The original design proposal of the car wa ...
, Porsche Cayenne S E-Hybrid, Mercedes-Benz C 350 e, BYD Tang,
Volkswagen Passat GTE The Volkswagen Passat (B8) is a mid-size car/large family car manufactured by Volkswagen that is available in a 4-door saloon and a 5-door estate body style sold as "Variant" in some markets. It was first introduced at the Volkswagen Design Center ...
, Volvo XC90 T8,
BMW X5 xDrive40e The BMW X5 (F15) is a mid-size luxury SUV manufactured and marketed worldwide by BMW since 2013. The car was unveiled in the 2013 Frankfurt International Motor Show. Early X5 models include xDrive50i, xDrive30d, M50d. BMW xDrive40d, xDrive35i, x ...
,
Hyundai Sonata PHEV The Hyundai Sonata is a mid-size car that has been manufactured by Hyundai since 1985. The first generation Sonata, which was introduced in 1985, was a facelifted Hyundai Stellar with an engine upgrade, and was withdrawn from the market in two ...
, and
Volvo S60L PHEV The Volvo Group ( sv, Volvokoncernen; legally Aktiebolaget Volvo, shortened to AB Volvo, stylized as VOLVO) is a Swedish multinational manufacturing corporation headquartered in Gothenburg. While its core activity is the production, distributi ...
. , about 500,000 highway-capable plug-in hybrid electric cars had been sold worldwide since December 2008, out of total cumulative global sales of 1.2 million light-duty
plug-in electric vehicle A plug-in electric vehicle (PEV) is any road vehicle that can utilize an external source of electricity (such as a wall socket that connects to the power grid) to store electrical power within its onboard rechargeable battery packs, which t ...
s. ''About 520,000 highway legal light-duty plug-in electric vehicles were sold worldwide in 2015, with cumulative global sales reaching 1,235,000
Plug-in hybrids represent about 40% of global plug-in electric vehicle sales
''
, the Volt/Ampera family of
plug-in hybrid A plug-in hybrid electric vehicle (PHEV) is a hybrid electric vehicle whose battery pack can be recharged by plugging a charging cable into an external electric power source, in addition to internally by its on-board internal combustion engin ...
s, with combined sales of about 134,500 units is the top selling plug-in hybrid in the world. Ranking next are the Mitsubishi Outlander P-HEV with about 119,500, and the
Toyota Prius Plug-in Hybrid The Toyota Prius Plug-in Hybrid (often abbreviated as the Prius and known as the Prius Prime in North America, South Korea, and New Zealand) is a plug-in hybrid liftback manufactured by Toyota. The first-generation model was produced from 2012 t ...
with almost 78,000.


Pedal-assisted electric hybrid vehicle

In very small vehicles, the power demand decreases, so human power can be employed to make a significant improvement in battery life. Three such commercially made vehicles are the
Sinclair C5 The Sinclair C5 is a small one-person battery electric recumbent tricycle, technically an "electrically assisted pedal cycle". It was the culmination of Sir Clive Sinclair's long-running interest in electric vehicles. Although widely described a ...
, ELF and TWIKE.


Comparative assessment of fossil and alternative fuels

According to a recent comparative energy and environmental analysis of the vehicle fuel end use (petroleum and natural gas derivatives & hydrogen; biofuels like ethanol or biodiesel, and their mixtures; as well as electricity intended to be used in
plug-in electric vehicles A plug-in electric vehicle (PEV) is any road vehicle that can utilize an external source of electricity (such as a wall socket that connects to the power grid) to store electrical power within its onboard rechargeable battery packs, which th ...
), the renewable and non-renewable unit energy costs and emission cost are suitable indicators for assessing the renewable energy consumption intensity and the environmental impact, and for quantifying the thermodynamic performance of the transportation sector. This analysis allows ranking the energy conversion processes along the vehicle fuels production routes and their end-use, so that the best options for the transportation sector can be determined and better energy policies may be issued. Thus, if a drastic emissions abatement of the transportation sector is pursued, a more intensive utilization of ethanol in the Brazilian transportation sector mix is advisable. However, as the overall exergy conversion efficiency of the sugar cane industry is still very low, which increases the unit energy cost of ethanol, better production and end-use technologies are required. Nonetheless, with the current scenario of a predominantly renewable Brazilian electricity mix, based on more than 80% of renewable sources, this source consolidates as the most promising energy source to reduce the large amount of greenhouse gas emissions which transportation sector is responsible for.


See also

*
Alternative Fuels Training Consortium The Clean Cities Coalition Network is a coordinated group of nearly 100 coalitions in the United States working in communities across the country to advance affordable, domestic transportation fuels, energy efficient mobility systems, and other fue ...
*
Alternatives to the automobile Established alternatives to car use include cycling, walking, kick scooters, rollerblading, skateboarding, twikes and (electric or internal combustion) motorcycles. Other alternatives are public transport vehicles (buses, guided buses, trolle ...
* Bi-fuel vehicle * Butanol fuel * Carbon-neutral fuel * Clean Cities * Engine control unit altering to optimize running on different fuels * Green vehicle * Fuel gas-powered scooter *
Hydrogen vehicle A hydrogen vehicle is a vehicle that uses hydrogen fuel for motive power. Hydrogen vehicles include hydrogen-fueled space rockets, as well as ships and aircraft. Power is generated by converting the chemical energy of hydrogen to mechanical ...
* List of hybrid vehicles *
Phase-out of fossil fuel vehicles Phase-out of fossil fuel vehicles means stopping selling and using vehicles which are powered by fossil fuels, such as gasoline (petrol), diesel, kerosene and fuel oil: it is one of the three most important parts of the general fossil fuel phase ...
* Renewable energy * Solar vehicle *'' The Hype about Hydrogen'' *
Vehicle classification by propulsion system There are numerous versions of vehicle propulsion systems. Many of those came into fruition due to need for cleaner vehicles. Each of them might have many abbreviations and some might be misleading. This article explains shortly what defines them. ...
* Water-fuelled car * Wind-powered vehicle


References


External links


Cradle-to-Grave Lifecycle Analysis of U.S. Light-Duty Vehicle-Fuel Pathways: A Greenhouse Gas Emissions and Economic Assessment of Current (2015) and Future (2025–2030) Technologies
(includes estimated cost of avoided GHG emissions from different AFV technologies),
Argonne National Laboratory Argonne National Laboratory is a science and engineering research national laboratory operated by UChicago Argonne LLC for the United States Department of Energy. The facility is located in Lemont, Illinois, outside of Chicago, and is the lar ...
, June 2016.
Official website of the Alternative Fuels Data Center
Office of Energy Efficiency and Renewable Energy,
United States Department of Energy The United States Department of Energy (DOE) is an executive department of the U.S. federal government that oversees U.S. national energy policy and manages the research and development of nuclear power and nuclear weapons in the United Stat ...

Transitions to Alternative Vehicles and Fuels
National Academy of Sciences The National Academy of Sciences (NAS) is a United States nonprofit, non-governmental organization. NAS is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of Engineering (NAE) and the Nat ...
(2013) {{DEFAULTSORT:Alternative Fuel Vehicle Vehicle technology Green vehicles Emerging technologies Alternative fuels