
In
organic chemistry
Organic chemistry is a subdiscipline within chemistry involving the science, scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clay ...
, an alkyl group is an
alkane
In organic chemistry
Organic chemistry is a subdiscipline within chemistry involving the science, scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms tha ...
missing one
hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
.
The term ''alkyl'' is intentionally unspecific to include many possible substitutions.
An acyclic alkyl has the general formula of . A cycloalkyl is derived from a
cycloalkane by removal of a hydrogen atom from a
ring and has the general formula .
Typically an alkyl is a part of a larger molecule. In
structural formulae, the symbol R is used to designate a generic (unspecified) alkyl group. The smallest alkyl group is
methyl, with the formula .
Related concepts
Alkylation is an important operation in refineries, for example in the production of high-octane gasoline.
Alkylating antineoplastic agents are a class of compounds that are used to treat cancer. In such case, the term alkyl is used loosely. For example,
nitrogen mustard
Nitrogen mustards are cytotoxic organic compounds with the chloroethylamine (Cl(CH2)2NR2) functional group. Although originally produced as chemical warfare agents, they were the first chemotherapeutic agents for treatment of cancer. Nitrogen ...
s are well-known alkylating agents, but they are not simple hydrocarbons.
In chemistry, alkyl is a group, a substituent, that is attached to other molecular fragments. For example,
alkyl lithium reagents have the empirical formula Li(alkyl), where alkyl = methyl, ethyl, etc. A ''dialkyl'' ether is an
ether with two alkyl groups, e.g., diethyl ether (O(C
2H
5)
2).
In medicinal chemistry
In