Alfred Maddock
   HOME

TheInfoList



OR:

Alfred Gavin Maddock (1917–2009) was an English
inorganic chemist Inorganic chemistry deals with synthesis and behavior of inorganic and organometallic compounds. This field covers chemical compounds that are not carbon-based, which are the subjects of organic chemistry. The distinction between the two disci ...
,
radiochemist Radiochemistry is the chemistry of radioactive materials, where radioactive isotopes of elements are used to study the properties and chemical reactions of non-radioactive isotopes (often within radiochemistry the absence of radioactivity leads to ...
and
spectroscopist Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter wav ...
who worked on the
Tube Alloys Tube Alloys was the research and development programme authorised by the United Kingdom, with participation from Canada, to develop nuclear weapons during the Second World War. Starting before the Manhattan Project in the United States, the Bri ...
Project and the
Manhattan Project The Manhattan Project was a research and development undertaking during World War II that produced the first nuclear weapons. It was led by the United States with the support of the United Kingdom and Canada. From 1942 to 1946, the project w ...
during World War II. Those projects resulted in the development of the atomic bomb. He may be best known for, during World War II, spilling Canada's entire supply of
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibi ...
which was 10 milligrams onto a wooden laboratory bench, and for recovered 9 and a half milligrams of
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibi ...
. He recovered it by
wet chemistry Wet chemistry is a form of analytical chemistry that uses classical methods such as observation to analyze materials. It is called wet chemistry since most analyzing is done in the liquid phase. Wet chemistry is also called bench chemistry since ...
. He also had a distinguished, though less eventful, post-war academic career.


Biography

Maddock was born in Bedford Park, a
garden suburb The garden city movement was a 20th century urban planning movement promoting satellite communities surrounding the central city and separated with greenbelts. These Garden Cities would contain proportionate areas of residences, industry, and ...
of London, and was educated at
Latymer Upper School (Slowly Therefore Surely) , established = , closed = , sister_school = Godolphin and Latymer School , type = Public schoolIndependent day school , head_label = H ...
. He won a state scholarship to study chemistry at the
Royal College of Science The Royal College of Science was a higher education institution located in South Kensington; it was a constituent college of Imperial College London from 1907 until it was wholly absorbed by Imperial in 2002. Still to this day, graduates from th ...
(RCS), then a constituent part of
Imperial College London Imperial College London (legally Imperial College of Science, Technology and Medicine) is a public research university in London, United Kingdom. Its history began with Prince Albert, consort of Queen Victoria, who developed his vision for a cu ...
. After his undergraduate education, he continued on to postgraduate studies at RCS under the supervision of inorganic chemist Professor H. J. Emeléus. Those studies related to silicon hydrides, and he was awarded his PhD in 1942. During the early years of World War II, his other studies included methods of protection against
arsine Arsine (IUPAC name: arsane) is an inorganic compound with the formula As H3. This flammable, pyrophoric, and highly toxic pnictogen hydride gas is one of the simplest compounds of arsenic. Despite its lethality, it finds some applications in th ...
, which had been proposed as a
chemical warfare Chemical warfare (CW) involves using the toxic properties of chemical substances as weapons. This type of warfare is distinct from nuclear warfare, biological warfare and radiological warfare, which together make up CBRN, the military acronym ...
agent. He also studied the toxicity of volatile compounds of
fluorine Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reacti ...
; which resulted in his suffering an acute case of poisoning. He and
Lord Rothschild Baron Rothschild, of Tring in the County of Hertfordshire, is a title in the Peerage of the United Kingdom. It was created in 1885 for Sir Nathan Rothschild, 2nd Baronet, a member of the Rothschild banking family. He was the first Jewish mem ...
devised a device based on
mercuric chloride Mercury(II) chloride (or mercury bichloride, mercury dichloride), historically also known as sulema or corrosive sublimate, is the inorganic chemical compound of mercury and chlorine with the formula HgCl2. It is white crystalline solid and is a ...
which was used by Allied parachutists into France. In 1941, he got to know several French nuclear physicists from the Curie Institute in Paris who had escaped the Nazi invasion. He initially worked with them at the
Cavendish Laboratory The Cavendish Laboratory is the Department of Physics at the University of Cambridge, and is part of the School of Physical Sciences. The laboratory was opened in 1874 on the New Museums Site as a laboratory for experimental physics and is named ...
in Cambridge, and later moved with them and others to
Ottawa Ottawa (, ; Canadian French: ) is the capital city of Canada. It is located at the confluence of the Ottawa River and the Rideau River in the southern portion of the province of Ontario. Ottawa borders Gatineau, Quebec, and forms the core ...
, Canada, where he helped build a
heavy water reactor A pressurized heavy-water reactor (PHWR) is a nuclear reactor that uses heavy water ( deuterium oxide D2O) as its coolant and neutron moderator. PHWRs frequently use natural uranium as fuel, but sometimes also use very low enriched uranium. T ...
, as part of what was first known as the Tube Alloys Project and later as the Manhattan Project. It was during that time that he spilled Canada's supply of plutonium (about 10 mg) onto a wooden laboratory bench. He pragmatically sawed it into pieces, ashed them, and recovered the plutonium by wet chemistry. After the War, he returned to England; was appointed lecturer in the Department of Chemistry at the
University of Cambridge , mottoeng = Literal: From here, light and sacred draughts. Non literal: From this place, we gain enlightenment and precious knowledge. , established = , other_name = The Chancellor, Masters and Schola ...
, where Emeléus now occupied the chair of inorganic chemistry; and was elected Fellow of St Catharine's College. He had a broad range of scientific interests, which included: the chemistry of the
actinide The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The inform ...
elements, in particular plutonium and
protactinium Protactinium (formerly protoactinium) is a chemical element with the symbol Pa and atomic number 91. It is a dense, silvery-gray actinide metal which readily reacts with oxygen, water vapor and inorganic acids. It forms various chemical compounds ...
; the chemistry associated with nuclear transformation; solvent extraction; radiation of inorganic solids; the chemistry of
positronium Positronium (Ps) is a system consisting of an electron and its antimatter, anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two parti ...
ions; and
Mössbauer spectroscopy Mössbauer spectroscopy is a spectroscopic technique based on the Mössbauer effect. This effect, discovered by Rudolf Mössbauer (sometimes written "Moessbauer", German: "Mößbauer") in 1958, consists of the nearly recoil-free emission and abso ...
, in which he was a pioneer. He was consultant to the
International Atomic Energy Agency The International Atomic Energy Agency (IAEA) is an intergovernmental organization that seeks to promote the peaceful use of nuclear energy and to inhibit its use for any military purpose, including nuclear weapons. It was established in 1957 ...
, and to atomic energy projects in various countries. He published more than 300
scientific paper : ''For a broader class of literature, see Academic publishing.'' Scientific literature comprises scholarly publications that report original empirical and theoretical work in the natural and social sciences. Within an academic field, scienti ...
s.


Honours and awards

These include: * 1960Awarded
DSc DSC may refer to: Academia * Doctor of Science (D.Sc.) * District Selection Committee, an entrance exam in India * Doctor of Surgical Chiropody, superseded in the 1960s by Doctor of Podiatric Medicine Educational institutions * Dalton State Col ...
and a personal
readership Readership may refer to: * The group of readers of a particular publication or writer: their target audience * The total number of readers of a particular publication (newspaper, magazine, book), as proxy-measured by web/app views or print circulat ...
by the
University of Cambridge , mottoeng = Literal: From here, light and sacred draughts. Non literal: From this place, we gain enlightenment and precious knowledge. , established = , other_name = The Chancellor, Masters and Schola ...
* Awarded DSc ''
honoris causa An honorary degree is an academic degree for which a university (or other degree-awarding institution) has waived all of the usual requirements. It is also known by the Latin phrases ''honoris causa'' ("for the sake of the honour") or ''ad hono ...
'' by the
University of Louvain A university () is an institution of higher (or tertiary) education and research which awards academic degrees in several academic disciplines. Universities typically offer both undergraduate and postgraduate programs. In the United States, the ...
, Belgium * Elected to the
Brazilian Academy of Sciences The Brazilian Academy of Sciences ( pt, italic=yes, Academia Brasileira de Ciências or ''ABC'') is the national academy of Brazil. It is headquartered in the city of Rio de Janeiro and was founded on May 3, 1916. Publications It publishes a lar ...
; in 1995, awarded by it its Grand Cross of the Order of Merit in Science * From 1981President of
St Catharine's College, Cambridge St Catharine's College is a constituent college of the University of Cambridge. Founded in 1473 as Katharine Hall, it adopted its current name in 1860. The college is nicknamed "Catz". The college is located in the historic city-centre of Camb ...
* 1996Awarded the
Becquerel The becquerel (; symbol: Bq) is the unit of radioactivity in the International System of Units (SI). One becquerel is defined as the activity of a quantity of radioactive material in which one nucleus decays per second. For applications relatin ...
Medal of the
Royal Society of Chemistry The Royal Society of Chemistry (RSC) is a learned society (professional association) in the United Kingdom with the goal of "advancing the chemistry, chemical sciences". It was formed in 1980 from the amalgamation of the Chemical Society, the Ro ...


Notes


References


Further reading and external links


The Papers of Alfred Maddock
held at the
Churchill Archives Centre The Churchill Archives Centre (CAC) at Churchill College at the University of Cambridge is one of the largest repositories in the United Kingdom for the preservation and study of modern personal papers. It is best known for housing the papers of ...
* * * * * * ; from the ''
Periodic Videos ''Periodic Videos'' (also known as ''The Periodic Table of Videos'') is a video project and YouTube channel on chemistry. It consists of a series of videos about chemical elements and the periodic table, with additional videos on other topics i ...
'' series, dated 5 September 2008; in which Professor
Sir Martyn Poliakoff Sir Martyn Poliakoff (born 16 December 1947) is a British chemist, working on gaining insights into fundamental chemistry, and on developing environmentally acceptable processes and materials. The core themes of his work are supercritical fluid ...
, who studied under Maddock, recounts the laboratory bench anecdote. * * * * * * * * * * * {{DEFAULTSORT:Maddock, Alfred 1917 births 2009 deaths People from the London Borough of Ealing People educated at Latymer Upper School Alumni of Imperial College London Alumni of the Royal College of Science Fellows of St Catharine's College, Cambridge Members of the Brazilian Academy of Sciences 20th-century British chemists Inorganic chemists Spectroscopists