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The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for liquid water to exist on the Earth's surface, absorbing ultraviolet solar radiation, warming the surface through heat retention (greenhouse effect), and reducing temperature extremes between day and night (the diurnal temperature variation).

By mole fraction (i.e., by number of molecules), dry air contains 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.04% carbon dioxide, and small amounts of other gases.
Air also contains a variable amount of water vapor, on average around 1% at sea level, and 0.4% over the entire atmosphere. Air composition, temperature, and atmospheric pressure vary with altitude. Within the atmosphere, air suitable for use in photosynthesis by terrestrial plants and breathing of terrestrial animals is found only in Earth's troposphere.

Earth's early atmosphere consisted of gases in the solar nebula, primarily hydrogen. The atmosphere changed significantly over time, affected by many factors such as volcanism, life, and weathering. Recently, human activity has also contributed to atmospheric changes, such as global warming, ozone depletion and acid deposition.

The atmosphere has a mass of about 5.15 kg, three quarters of which is within about of the surface. The atmosphere becomes thinner with increasing altitude, with no definite boundary between the atmosphere and outer space. The Kármán line, at or 1.57% of Earth's radius, is often used as the border between the atmosphere and outer space. Atmospheric effects become noticeable during atmospheric reentry of spacecraft at an altitude of around . Several layers can be distinguished in the atmosphere, based on characteristics such as temperature and composition.

The study of Earth's atmosphere and its processes is called atmospheric science (aerology), and includes multiple subfields, such as climatology and atmospheric physics. Early pioneers in the field include Léon Teisserenc de Bort and Richard Assmann. The study of historic atmosphere is called paleoclimatology.

Composition

The three major constituents of Earth's atmosphere are nitrogen, oxygen, and argon. Water vapor accounts for roughly 0.25% of the atmosphere by mass. The concentration of water vapor (a greenhouse gas) varies significantly from around 10 ppm by mole fraction in the coldest portions of the atmosphere to as much as 5% by mole fraction in hot, humid air masses, and concentrations of other atmospheric gases are typically quoted in terms of dry air (without water vapor).Wallace, John M. and Peter V. Hobbs
''Atmospheric Science: An Introductory Survey''
. Elsevier. Second Edition, 2006. . Chapter 1 The remaining gases are often referred to as trace gases, among which are other greenhouse gases, principally carbon dioxide, methane, nitrous oxide, and ozone. Besides argon, already mentioned, other noble gases, neon, helium, krypton, and xenon are also present. Filtered air includes trace amounts of many other chemical compounds. Many substances of natural origin may be present in locally and seasonally variable small amounts as aerosols in an unfiltered air sample, including dust of mineral and organic composition, pollen and spores, sea spray, and volcanic ash. Various industrial pollutants also may be present as gases or aerosols, such as chlorine (elemental or in compounds), fluorine compounds and elemental mercury vapor. Sulfur compounds such as hydrogen sulfide and sulfur dioxide (SO₂) may be derived from natural sources or from industrial air pollution.

The average molecular weight of dry air, which can be used to calculate densities or to convert between mole fraction and mass fraction, is about 28.946Detlev Möller: ''Luft: Chemie, Physik, Biologie, Reinhaltung, Recht.'' Walter de Gruyter, 2003, , S. 173
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or 28.96 g/mol. This is decreased when the air is humid.

The relative concentration of gases remains constant until about .

Stratification

In general, air pressure and density decrease with altitude in the atmosphere. However, the temperature has a more complicated profile with altitude, and may remain relatively constant or even increase with altitude in some regions (see the temperature section, below). Because the general pattern of the temperature/altitude profile, or lapse rate, is constant and measurable by means of instrumented balloon soundings, the temperature behavior provides a useful metric to distinguish atmospheric layers. In this way, Earth's atmosphere can be divided (called atmospheric stratification) into five main layers: troposphere, stratosphere, mesosphere, thermosphere, and exosphere. The altitudes of the five layers are as follows:
* Exosphere: 700 to 10,000 km (440 to 6,200 miles)
* Thermosphere: 80 to 700 km (50 to 440 miles)
* Mesosphere: 50 to 80 km (31 to 50 miles)
* Stratosphere: 12 to 50 km (7 to 31 miles)
* Troposphere: 0 to 12 km (0 to 7 miles)

Exosphere

The exosphere is the outermost layer of Earth's atmosphere (i.e. the upper limit of the atmosphere). It extends from the thermopause, at the top of the thermosphere at an altitude of about 700 km above sea level, to about 10,000 km (6,200 mi; 33,000,000 ft), where it merges into the solar wind.

This layer is mainly composed of extremely low densities of hydrogen, helium and several heavier molecules including nitrogen, oxygen and carbon dioxide closer to the exobase. The atoms and molecules are so far apart that they can travel hundreds of kilometers without colliding with one another. Thus, the exosphere no longer behaves like a gas, and the particles constantly escape into space. These free-moving particles follow ballistic trajectories and may migrate in and out of the magnetosphere or the solar wind.

The exosphere is too far above Earth for meteorological phenomena to be possible. However, Earth's auroras—the aurora borealis (northern lights) and aurora australis (southern lights)—sometimes occur in the lower part of the exosphere, where they overlap into the thermosphere. The exosphere contains many of the artificial satellites that orbit Earth.

Thermosphere

The thermosphere is the second-highest layer of Earth's atmosphere. It extends from the mesopause (which separates it from the mesosphere) at an altitude of about up to the thermopause at an altitude range of . The height of the thermopause varies considerably due to changes in solar activity. Because the thermopause lies at the lower boundary of the exosphere, it is also referred to as the exobase. The lower part of the thermosphere, from above Earth's surface, contains the ionosphere.

The temperature of the thermosphere gradually increases with height and can rise as high as , though the gas molecules are so far apart that its temperature in the usual sense is not very meaningful. The air is so rarefied that an individual molecule (of oxygen, for example) travels an average of between collisions with other molecules. Although the thermosphere has a high proportion of molecules with high energy, it would not feel hot to a human in direct contact, because its density is too low to conduct a significant amount of energy to or from the skin.

This layer is completely cloudless and free of water vapor. However, non-hydrometeorological phenomena such as the aurora borealis and aurora australis are occasionally seen in the thermosphere. The International Space Station orbits in this layer, between . It is this layer where many of the satellites orbiting the earth are present.

Mesosphere

The mesosphere is the third highest layer of Earth's atmosphere, occupying the region above the stratosphere and below the thermosphere. It extends from the stratopause at an altitude of about to the mesopause at above sea level.

Temperatures drop with increasing altitude to the mesopause that marks the top of this middle layer of the atmosphere. It is the coldest place on Earth and has an average temperature around .

Just below the mesopause, the air is so cold that even the very scarce water vapor at this altitude can sublimate into polar-mesospheric noctilucent clouds of ice particles. These are the highest clouds in the atmosphere and may be visible to the naked eye if sunlight reflects off them about an hour or two after sunset or similarly before sunrise. They are most readily visible when the Sun is around 4 to 16 degrees below the horizon. Lightning-induced discharges known as transient luminous events (TLEs) occasionally form in the mesosphere above tropospheric thunderclouds. The mesosphere is also the layer where most meteors burn up upon atmospheric entrance. It is too high above Earth to be accessible to jet-powered aircraft and balloons, and too low to permit orbital spacecraft. The mesosphere is mainly accessed by sounding rockets and rocket-powered aircraft.

Stratosphere

The stratosphere is the second-lowest layer of Earth's atmosphere. It lies above the troposphere and is separated from it by the tropopause. This layer extends from the top of the troposphere at roughly above Earth's surface to the stratopause at an altitude of about .

The atmospheric pressure at the top of the stratosphere is roughly 1/1000 the pressure at sea level. It contains the ozone layer, which is the part of Earth's atmosphere that contains relatively high concentrations of that gas. The stratosphere defines a layer in which temperatures rise with increasing altitude. This rise in temperature is caused by the absorption of ultraviolet radiation (UV) radiation from the Sun by the ozone layer, which restricts turbulence and mixing. Although the temperature ma