The atmosphere of Earth is the layer of
gases, known collectively as air, retained by
Earth's gravity that surrounds the planet and forms its planetary
atmosphere
An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A s ...
. The atmosphere of Earth protects
life on Earth by creating
pressure allowing for
liquid water to exist on the Earth's
surface, absorbing
ultraviolet solar radiation, warming the surface through heat retention (
greenhouse effect), and reducing temperature extremes between
day
A day is the time period of a full rotation of the Earth with respect to the Sun. On average, this is 24 hours, 1440 minutes, or 86,400 seconds. In everyday life, the word "day" often refers to a solar day, which is the length between two so ...
and
night (the
diurnal temperature variation).
By
mole fraction (i.e., by number of molecules), dry air contains 78.08%
nitrogen, 20.95%
oxygen, 0.93%
argon, 0.04%
carbon dioxide, and small amounts of other gases.
Air also contains a variable amount of
water vapor, on average around 1% at sea level, and 0.4% over the entire atmosphere. Air composition, temperature, and
atmospheric pressure vary with altitude. Within the atmosphere, air suitable for use in
photosynthesis by
terrestrial plants and
breathing
Breathing (or ventilation) is the process of moving air into and from the lungs to facilitate gas exchange with the internal environment, mostly to flush out carbon dioxide and bring in oxygen.
All aerobic creatures need oxygen for cellular ...
of
terrestrial animals is found only in Earth's
troposphere.
Earth's early atmosphere consisted of gases in the
solar nebula
The formation of the Solar System began about 4.6 billion years ago with the gravitational collapse of a small part of a giant molecular cloud. Most of the collapsing mass collected in the center, forming the Sun, while the rest flattened into a ...
, primarily hydrogen. The atmosphere changed significantly over time, affected by many factors such as
volcanism,
life, and
weathering. Recently, human activity has also contributed to
atmospheric changes, such as
global warming,
ozone depletion
Ozone depletion consists of two related events observed since the late 1970s: a steady lowering of about four percent in the total amount of ozone in Earth's atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone l ...
and
acid deposition.
The atmosphere has a mass of about 5.15 kg, three quarters of which is within about of the surface. The atmosphere becomes thinner with increasing altitude, with no definite boundary between the atmosphere and
outer space. The
Kármán line
The Kármán line (or von Kármán line ) is an attempt to define a boundary between Earth's atmosphere and outer space, and offers a specific definition set by the Fédération aéronautique internationale (FAI), an international record-keeping ...
, at or 1.57% of Earth's radius, is often used as the border between the atmosphere and outer space. Atmospheric effects become noticeable during
atmospheric reentry
Atmospheric entry is the movement of an object from outer space into and through the gases of an atmosphere of a planet, dwarf planet, or natural satellite. There are two main types of atmospheric entry: ''uncontrolled entry'', such as the entr ...
of spacecraft at an altitude of around . Several
layers
Layer or layered may refer to:
Arts, entertainment, and media
* ''Layers'' (Kungs album)
* ''Layers'' (Les McCann album)
* ''Layers'' (Royce da 5'9" album)
*"Layers", the title track of Royce da 5'9"'s sixth studio album
*Layer, a female Maveric ...
can be distinguished in the atmosphere, based on characteristics such as temperature and composition.
The study of Earth's atmosphere and its processes is called
atmospheric science
Atmospheric science is the study of the Atmosphere of Earth, Earth's atmosphere and its various inner-working physical processes. Meteorology includes atmospheric chemistry and atmospheric physics with a major focus on weather forecasting. Climat ...
(aerology), and includes multiple subfields, such as
climatology and
atmospheric physics. Early pioneers in the field include
Léon Teisserenc de Bort and
Richard Assmann
Richard Assmann (Anglicized spelling of the German name Richard Aßmann) (13 April 1845 in Magdeburg – 28 May 1918 in Gießen) was a German meteorologist and physician who was a native of Magdeburg. He made numerous contributions in high altitud ...
. The study of historic atmosphere is called
paleoclimatology.
Composition
The three major constituents of Earth's atmosphere are
nitrogen,
oxygen, and
argon. Water vapor accounts for roughly 0.25% of the atmosphere by mass. The concentration of water vapor (a greenhouse gas) varies significantly from around 10 ppm by mole fraction in the coldest portions of the atmosphere to as much as 5% by mole fraction in hot, humid air masses, and concentrations of other atmospheric gases are typically quoted in terms of dry air (without water vapor).
[Wallace, John M. and Peter V. Hobbs]
''Atmospheric Science: An Introductory Survey''
. Elsevier. Second Edition, 2006. . Chapter 1 The remaining gases are often referred to as trace gases, among which are other
greenhouse gas
A greenhouse gas (GHG or GhG) is a gas that Absorption (electromagnetic radiation), absorbs and Emission (electromagnetic radiation), emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse ...
es, principally carbon dioxide, methane, nitrous oxide, and ozone. Besides argon, already mentioned, other
noble gases, neon, helium, krypton, and xenon are also present. Filtered air includes trace amounts of many other
chemical compounds. Many substances of natural origin may be present in locally and seasonally variable small amounts as
aerosol
An aerosol is a suspension (chemistry), suspension of fine solid particles or liquid Drop (liquid), droplets in air or another gas. Aerosols can be natural or Human impact on the environment, anthropogenic. Examples of natural aerosols are fog o ...
s in an unfiltered air sample, including
dust of mineral and organic composition,
pollen
Pollen is a powdery substance produced by seed plants. It consists of pollen grains (highly reduced microgametophytes), which produce male gametes (sperm cells). Pollen grains have a hard coat made of sporopollenin that protects the gametophyt ...
and
spores,
sea spray, and
volcanic ash. Various industrial
pollutants also may be present as gases or aerosols, such as
chlorine (elemental or in compounds),
fluorine
Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reacti ...
compounds and elemental
mercury
Mercury commonly refers to:
* Mercury (planet), the nearest planet to the Sun
* Mercury (element), a metallic chemical element with the symbol Hg
* Mercury (mythology), a Roman god
Mercury or The Mercury may also refer to:
Companies
* Merc ...
vapor. Sulfur compounds such as
hydrogen sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The unde ...
and
sulfur dioxide
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
(SO
2) may be derived from natural sources or from industrial air pollution.
The average
molecular weight of dry air, which can be used to calculate densities or to convert between mole fraction and mass fraction, is about 28.946
[Detlev Möller: ''Luft: Chemie, Physik, Biologie, Reinhaltung, Recht.'' Walter de Gruyter, 2003, , S. 173]
(View in Google Books)
or 28.96 g/mol. This is decreased when the air is humid.
The relative concentration of gases remains constant until about .
Stratification
In general, air pressure and density decrease with altitude in the atmosphere. However, the temperature has a more complicated profile with altitude, and may remain relatively constant or even increase with altitude in some regions (see the
temperature section, below). Because the general pattern of the temperature/altitude profile, or
lapse rate
The lapse rate is the rate at which an atmospheric variable, normally temperature in Earth's atmosphere, falls with altitude. ''Lapse rate'' arises from the word ''lapse'', in the sense of a gradual fall. In dry air, the adiabatic lapse rate is ...
, is constant and measurable by means of instrumented
balloon soundings, the temperature behavior provides a useful metric to distinguish atmospheric layers. In this way, Earth's atmosphere can be divided (called atmospheric stratification) into five main layers: troposphere, stratosphere, mesosphere, thermosphere, and exosphere. The altitudes of the five layers are as follows:
* Exosphere: 700 to 10,000 km (440 to 6,200 miles)
* Thermosphere: 80 to 700 km (50 to 440 miles)
* Mesosphere: 50 to 80 km (31 to 50 miles)
* Stratosphere: 12 to 50 km (7 to 31 miles)
* Troposphere: 0 to 12 km (0 to 7 miles)
Exosphere
The exosphere is the outermost layer of Earth's atmosphere (i.e. the upper limit of the atmosphere). It extends from the
thermopause, at the top of the thermosphere at an altitude of about 700 km above sea level, to about 10,000 km (6,200 mi; 33,000,000 ft), where it merges into the
solar wind.
This layer is mainly composed of extremely low densities of hydrogen, helium and several heavier molecules including nitrogen, oxygen and carbon dioxide closer to the exobase. The atoms and molecules are so far apart that they can travel hundreds of kilometers without colliding with one another. Thus, the exosphere no longer behaves like a gas, and the particles constantly escape into space. These free-moving particles follow
ballistic trajectories
A trajectory or flight path is the path that an object with mass in motion follows through space as a function of time. In classical mechanics, a trajectory is defined by Hamiltonian mechanics via canonical coordinates; hence, a complete traj ...
and may migrate in and out of the
magnetosphere
In astronomy and planetary science, a magnetosphere is a region of space surrounding an astronomical object in which charged particles are affected by that object's mag