An AFm phase is an "alumina, ferric oxide, monosubstituted" phase, or aluminate ferrite monosubstituted, or , mono, in
cement chemist notation
Cement chemist notation (CCN) was developed to simplify the formulas cement chemists use on a daily basis. It is a shorthand way of writing the chemical formula of oxides of calcium, silicon, and various metals.
Abbreviations of oxides
The main o ...
. AFm phases are important hydration products in the
hydration Hydration may refer to:
* Hydrate, a substance that contains water
* Hydration enthalpy, energy released through hydrating a substance
* Hydration reaction, a chemical addition reaction where a hydroxyl group and proton are added to a compound
* ...
of
hydraulic cements.
They are crystalline hydrates with general, simplified formula where n may be comprised between 13 and 19 water molecules.
They form ''inter alia'' when
tricalcium aluminate
Tricalcium aluminate Ca3Al2O6, often formulated as 3CaO·Al2O3 to highlight the proportions of the oxides from which it is made, is the most basic of the calcium aluminates. It does not occur in nature, but is an important mineral phase in Port ...
() reacts with dissolved
calcium sulfate
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Pari ...
() or
calcium carbonate (). As their sulfate form is the dominant one, they are often referred to as Aluminate Ferrite monosulfate or calcium aluminate monosulfate. However, carbonate-AFm phases also exist: monocarbonate and hemicarbonate.
See also
*
Concrete degradation#Chloride attack
*
Layered double hydroxides
Layered double hydroxides (LDH) are a class of ionic solids characterized by a layered structure with the generic layer sequence cB Z AcBsub>''n'', where c represents layers of metal cations, A and B are layers of hydroxide () anions, and Z are l ...
(LDH)
*
Friedel's salt
Friedel's salt is an anion exchanger mineral belonging to the family of the layered double hydroxides (LDHs). It has affinity for anions as chloride and iodide and is capable of retaining them to a certain extent in its crystallographical stru ...
*
Ettringite
Ettringite is a hydrous calcium aluminium sulfate mineral with formula: . It is a colorless to yellow mineral crystallizing in the trigonal system. The prismatic crystals are typically colorless, turning white on partial dehydration. It is part of ...
(AFt)
*
Pitting corrosion
Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the random creation of small holes in metal. The driving power for pitting corrosion is the depassivation of a small area, which becomes anodic (oxidation re ...
of rebar induced by chloride attack
References
Further reading
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{{DEFAULTSORT:AFm Phase
Aluminium compounds
Cement
Concrete
Hydrates
Iron compounds
Iron(III) compounds
Silicates
Sulfate minerals
Sulfates