Zinc Cadmium Sulfide
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Zinc Cadmium Sulfide
Zinc cadmium sulfide is a mixture of zinc sulfide (ZnS) and cadmium sulfide (CdS). It is used for its fluorescent properties. Bioaccumulation of this chemical may occur along the food chain, for example in plants and in seafood. Long-term or repeated exposures are expected to have harmful effects on the kidneys, bones, and respiratory tract, resulting in kidney impairment, osteoporosis (bone weakness), and chronic inflammation of the respiratory tract. Use Operation LAC (Large Area Coverage) was a United States Army Chemical Corps operation in 1957 and 1958 which dispersed microscopic zinc cadmium sulfide (ZnCdS) particles over much of the United States. The purpose was to determine the dispersion and geographic range of biological or chemical agents. Zinc cadmium sulfide was used as it could be easily detected. It was also used in an experiment on unwitting civilians in the UK and Canada.
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Zinc Sulfide
Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment. In its dense synthetic form, zinc sulfide can be transparent, and it is used as a window for visible optics and infrared optics. Structure ZnS exists in two main crystalline forms. This dualism is an example of polymorphism. In each form, the coordination geometry at Zn and S is tetrahedral. The more stable cubic form is known also as zinc blende or sphalerite. The hexagonal form is known as the mineral wurtzite, although it also can be produced synthetically.. The transition from the sphalerite form to the wurtzite form occurs at around 1020 °C. A tetragonal form is also known as the very rare mineral called polhemusite, with the formula . Applicatio ...
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Cadmium Sulfide
Cadmium sulfide is the inorganic compound with the formula CdS. Cadmium sulfide is a yellow solid.Egon Wiberg, Arnold Frederick Holleman (2001''Inorganic Chemistry'' Elsevier It occurs in nature with two different crystal structures as the rare minerals greenockite and hawleyite, but is more prevalent as an impurity substituent in the similarly structured zinc ores sphalerite and wurtzite, which are the major economic sources of cadmium. As a compound that is easy to isolate and purify, it is the principal source of cadmium for all commercial applications. Its vivid yellow color led to its adoption as a pigment for the yellow paint "cadmium yellow" in the 18th century. Production Cadmium sulfide can be prepared by the precipitation from soluble cadmium(II) salts with sulfide ion. This reaction has been used for gravimetric analysis and qualitative inorganic analysis.The preparative route and the subsequent treatment of the product, affects the polymorphic form that is produced ( ...
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Fluorescence
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, than the absorbed radiation. A perceptible example of fluorescence occurs when the absorbed radiation is in the ultraviolet region of the electromagnetic spectrum (invisible to the human eye), while the emitted light is in the visible region; this gives the fluorescent substance a distinct color that can only be seen when the substance has been exposed to UV light. Fluorescent materials cease to glow nearly immediately when the radiation source stops, unlike phosphorescent materials, which continue to emit light for some time after. Fluorescence has many practical applications, including mineralogy, gemology, medicine, chemical sensors (fluorescence spectroscopy), fluorescent labelling, dyes, biological detectors, cosmic-ray detection, vacu ...
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Operation LAC
Operation LAC (Large Area Coverage) was a United States Army Chemical Corps operation which dispersed microscopic zinc cadmium sulfide (ZnCdS) particles over much of the United States and Canada in order to test dispersal patterns and the geographic range of chemical or biological weapons. Earlier tests There were several tests that occurred prior to the first spraying affiliated with Operation LAC that proved the concept of large-area coverage. Canadian historical files relating to participation in the tests cite in particular three previous series of tests leading up to those conducted in Operation LAC. * September 1950 – Six simulated attacks were conducted upon the San Francisco Bay Area. It was concluded that it was feasible to attack a seaport city with biological aerosol agents from a ship offshore. * March–April 1952 – Five trials were conducted off the coast of South Carolina and Georgia under Operation Dew. It was concluded that long-range aerosol clouds could ...
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United States Army
The United States Army (USA) is the land service branch of the United States Armed Forces. It is one of the eight U.S. uniformed services, and is designated as the Army of the United States in the U.S. Constitution.Article II, section 2, clause 1 of the United States Constitution (1789). See alsTitle 10, Subtitle B, Chapter 301, Section 3001 The oldest and most senior branch of the U.S. military in order of precedence, the modern U.S. Army has its roots in the Continental Army, which was formed 14 June 1775 to fight the American Revolutionary War (1775–1783)—before the United States was established as a country. After the Revolutionary War, the Congress of the Confederation created the United States Army on 3 June 1784 to replace the disbanded Continental Army.Library of CongressJournals of the Continental Congress, Volume 27/ref> The United States Army considers itself to be a continuation of the Continental Army, and thus considers its institutional inception to be th ...
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Chemical Corps
The Chemical Corps is the branch of the United States Army tasked with defending against chemical, biological, radiological, and nuclear (CBRN) weapons. The Chemical Warfare Service was established on 28 June 1918, combining activities that until then had been dispersed among five separate agencies of the United States federal government. It was made a permanent branch of the Regular Army by the National Defense Act of 1920. In 1945, it was redesignated the Chemical Corps. History Origins Discussion of the topic dates back to the American Civil War. A letter to the War Department dated 5 April 1862 from New York City resident John Doughty proposed the use of chlorine shells to drive the Confederate Army from its positions. Doughty included a detailed drawing of the shell with his letter. It is unknown how the military reacted to Doughty's proposal but the letter was unnoticed in a pile of old official documents until modern times. Another American, Forrest Shepherd, also propos ...
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The New York Times
''The New York Times'' (''the Times'', ''NYT'', or the Gray Lady) is a daily newspaper based in New York City with a worldwide readership reported in 2020 to comprise a declining 840,000 paid print subscribers, and a growing 6 million paid digital subscribers. It also is a producer of popular podcasts such as '' The Daily''. Founded in 1851 by Henry Jarvis Raymond and George Jones, it was initially published by Raymond, Jones & Company. The ''Times'' has won 132 Pulitzer Prizes, the most of any newspaper, and has long been regarded as a national " newspaper of record". For print it is ranked 18th in the world by circulation and 3rd in the U.S. The paper is owned by the New York Times Company, which is publicly traded. It has been governed by the Sulzberger family since 1896, through a dual-class share structure after its shares became publicly traded. A. G. Sulzberger, the paper's publisher and the company's chairman, is the fifth generation of the family to head the pa ...
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Leonard A
Leonard or ''Leo'' is a common English masculine given name and a surname. The given name and surname originate from the Old High German ''Leonhard'' containing the prefix ''levon'' ("lion") from the Greek Λέων ("lion") through the Latin '' Leo,'' and the suffix ''hardu'' ("brave" or "hardy"). The name has come to mean "lion strength", "lion-strong", or "lion-hearted". Leonard was the name of a Saint in the Middle Ages period, known as the patron saint of prisoners. Leonard is also an Irish origin surname, from the Gaelic ''O'Leannain'' also found as O'Leonard, but often was anglicised to just Leonard, consisting of the prefix ''O'' ("descendant of") and the suffix ''Leannan'' ("lover"). The oldest public records of the surname appear in 1272 in Huntingdonshire, England, and in 1479 in Ulm, Germany. Variations The name has variants in other languages: * Leen, Leendert, Lenard (Dutch) * Lehnertz, Lehnert (Luxembourgish) * Len (English) * :hu:Lénárd (Hungarian) * Lenart ( ...
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Operation Dew
Operation Dew refers to two separate field trials conducted by the United States in the 1950s. The tests were designed to study the behavior of aerosol-released biological agents. General description Operation Dew took place from 1951 to 1952 off the southeast coast of the United States, including near Georgia, and North and South Carolina. Operation Dew consisted of two sets of trials, Dew I and Dew II. The tests involved the release of 250 pounds (110 kg) of fluorescent particles from a minesweeper off the coast. Operation Dew I was described in a U.S. Army report known as "Dugway Special Report 162", dated August 1, 1952. The purpose of Operation Dew was to study the behavior of aerosol-released biological agents.Croddy, Eric, et al. ''Chemical and Biological Warfare: A Comprehensive Survey for the Concerned Citizen'',Google Books, Springer, 2002, p. 231, (). Dew I Operation Dew I consisted of five separate trials from March 26, 1952 until April 21, 1952 that were designed t ...
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Project SHAD
Project SHAD, an acronym for Shipboard Hazard and Defense, was part of a larger effort called Project 112, which was conducted during the 1960s. Project SHAD encompassed tests designed to identify U.S. warships' vulnerabilities to attacks with chemical agents or biological warfare agents and to develop procedures to respond to such attacks while maintaining a war-fighting capability. History Project SHAD was part of a larger effort by the Department of Defense called Project 112. Project 112 was a chemical and biological weapons research, development, and testing project conducted by the United States Department of Defense and CIA handled by the Deseret Test Center and United States Army Chemical Materials Agency from 1962 to 1973. The project started under John F. Kennedy's administration, and was authorized by his Secretary of Defense Robert McNamara, as part of a total review of the US military. The name of the project refers to its number in the 150 review process. Mission ...
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Unethical Human Experimentation In The United States
Numerous experiments which are performed on human test subjects in the United States are considered unethical, because they are performed without the knowledge or informed consent of the test subjects. Such tests have been performed throughout American history, but some of them are ongoing. The experiments include the exposure of humans to many chemical and biological weapons (including infections with deadly or debilitating diseases), human radiation experiments, injections of toxic and radioactive chemicals, surgical experiments, interrogation and torture experiments, tests which involve mind-altering substances, and a wide variety of other experiments. Many of these tests are performed on children, the sick, and mentally disabled individuals, often under the guise of "medical treatment". In many of the studies, a large portion of the subjects were poor, racial minorities, or prisoners. Many of these experiments violated US law. Some others were sponsored by government agenc ...
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Cadmium Compounds
Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of its compounds, and like mercury, it has a lower melting point than the transition metals in groups 3 through 11. Cadmium and its congeners in group 12 are often not considered transition metals, in that they do not have partly filled ''d'' or ''f'' electron shells in the elemental or common oxidation states. The average concentration of cadmium in Earth's crust is between 0.1 and 0.5 parts per million (ppm). It was discovered in 1817 simultaneously by Stromeyer and Hermann, both in Germany, as an impurity in zinc carbonate. Cadmium occurs as a minor component in most zinc ores and is a byproduct of zinc production. Cadmium was used for a long time as a corrosion-resistant plating on steel, and cadmium compounds are used as red, orange ...
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