Zinc-ion Battery
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Zinc-ion Battery
A zinc-ion battery or Zn-ion battery (abbreviated as ZIB) uses zinc ions (Zn2+) as the charge carriers. Specifically, ZIBs utilize Zn as the anode, Zn-intercalating materials as the cathode, and a Zn-containing electrolyte. Generally, the term zinc-ion battery is reserved for rechargeable (secondary) batteries, which are sometimes also referred to as rechargeable zinc metal batteries (RZMB). Thus, ZIBs are different than non-rechargeable (primary) batteries which use zinc, such as alkaline or zinc–carbon batteries. History In 2011, Feiyu Kang's group showcased for the first time the reversible Zn-ion insertion into the tunnel structure of alpha-type manganese dioxide (MnO2) host used as the cathode in a ZIB. The University of Waterloo in Canada owns patent rights to zinc-ion battery technology developed in its laboratories. The Canadian company Salient Energy is commercialising the zinc-ion battery technology. Other forms of rechargeable zinc batteries are also being devel ...
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Zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic table. In some respects, zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size.The elements are from different metal groups. See periodic table. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity ( electrowinning). Zinc is an essential trace element for humans, animals, plants and for microorganisms and is necessary for prenatal and postnatal development. It ...
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Energy Storage
Energy storage is the capture of energy produced at one time for use at a later time to reduce imbalances between energy demand and energy production. A device that stores energy is generally called an accumulator or battery. Energy comes in multiple forms including radiation, chemical, gravitational potential, electrical potential, electricity, elevated temperature, latent heat and kinetic. Energy storage involves converting energy from forms that are difficult to store to more conveniently or economically storable forms. Some technologies provide short-term energy storage, while others can endure for much longer. Bulk energy storage is currently dominated by hydroelectric dams, both conventional as well as pumped. Grid energy storage is a collection of methods used for energy storage on a large scale within an electrical power grid. Common examples of energy storage are the rechargeable battery, which stores chemical energy readily convertible to electricity to operate a ...
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Aqueous Solution
An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be represented as . The word ''aqueous'' (which comes from ''aqua'') means pertaining to, related to, similar to, or dissolved in, water. As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent in chemistry. Since water is frequently used as the solvent in experiments, the word solution refers to an aqueous solution, unless the solvent is specified. A ''non-aqueous solution'' is a solution in which the solvent is a liquid, but is not water. (See also Solvent and Inorganic nonaqueous solvent.) Characteristics Substances that are ''hydrophobic'' ('water-fearing') do not dissolve well in water, whereas those that are ''hydrophilic'' ('water-friendly') do. An example of a hydrophilic substance is sodium chlo ...
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Vanadium Oxide
Vanadium oxide may refer to: * Vanadium(II) oxide (vanadium monoxide), VO * Vanadium(III) oxide (vanadium sesquioxide ''or'' trioxide), V2O3 * Vanadium(IV) oxide (vanadium dioxide), VO2 * Vanadium(V) oxide (vanadium pentoxide), V2O5 * Vanadium(VI) oxide (vanadium hexoxide), a green oxide produced by a combination of hydrogen peroxide and vanadium metal In addition to these principal oxides of vanadium, various other distinct phases exist: * Phases with the general formula VnO2n+1 exist between V2O5 and VO2. Examples of these phases include V3O7, V4O9 and V6O13. * Phases with the general formula VnO2n−1 exist between VO2 and V2O3. Called Magnéli phases foArne Magnéli they are examples of crystallographic shear compounds based on the rutile structure. Examples of Magnéli phases include V4O7, V5O9, V6O11, V7O13 and V8O15. * V3O5 appears as the mineral oxyvanite. Many vanadium-oxygen phases are non-stoichiometric In chemistry, non-stoichiometric compounds are chemical comp ...
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Potassium Hydroxide
Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which exploit its caustic nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white solid that is dangerously corrosive. Properties and structure KOH exhibits high thermal stability. Because of this high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties. These pellets become tacky in air because KOH is hygroscopic. Most commercial samples are ca. 90% pure, the remainder being water and carbonates. Its dissolution in water is strongly exothermic. Concentrated aqueous solut ...
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Zinc Sulfate
Zinc sulfate is an inorganic compound. It is used as a dietary supplement to treat zinc deficiency and to prevent the condition in those at high risk. Side effects of excess supplementation may include abdominal pain, vomiting, headache, and tiredness. The most common form includes water of crystallization as the heptahydrate, with the formula . It was historically known as "white vitriol". Zinc sulfate and its hydrates are colourless solids. Uses Medicine In medicine it is used together with oral rehydration therapy (ORT) and an astringent. Manufacturing The hydrates, especially the heptahydrate, are the primary forms used commercially. The main application is as a coagulant in the production of rayon. It is also a precursor to the pigment lithopone. It is also used as an electrolyte for zinc electroplating, as a mordant in dyeing, and as a preservative for skins and leather. Other Zinc sulfate is used to supply zinc in animal feeds, fertilizers, toothpaste, and agricul ...
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Triflate
In organic chemistry, triflate (systematic name: trifluoromethanesulfonate), is a functional group with the formula and structure . The triflate group is often represented by , as opposed to −Tf, which is the triflyl group, . For example, ''n''-butyl triflate can be written as . The corresponding triflate anion, , is an extremely stable polyatomic ion; this comes from the fact that triflic acid () is a superacid; i.e. it is more acidic than pure sulfuric acid, already one of the strongest acids known. Applications A triflate group is an excellent leaving group used in certain organic reactions such as nucleophilic substitution, Suzuki couplings and Heck reactions. Since alkyl triflates are extremely reactive in SN2 reactions, they must be stored in conditions free of nucleophiles (such as water). The anion owes its stability to resonance stabilization which causes the negative charge to be spread symmetrically over the three oxygen atoms. An additional stabilization is a ...
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Bistriflimide
Bistriflimide, also known variously as bis(trifluoromethane)sulfonimide, bis(trifluoromethanesulfonyl)amide, bis(trifluoromethanesulfonyl)imidate (and variations thereof), informally and somewhat inaccurately as triflimide or triflimidate'','' or by the abbreviations TFSI or NTf2, is a non-coordinating anion with the chemical formula Cfluorine.html"_;"title="carbon.html"_;"title="carbon">Cfluorine">F3 Soxygen.html"_;"title="fluorine">F3sulfur.html"_;"title="carbon">Cfluorine.html"_;"title="carbon.html"_;"title="carbon">Cfluorine">F3sulfur">Soxygen">O2)2nitrogen.html" ;"title="sulfur">Soxygen.html" ;"title="fluorine">F3sulfur.html" ;"title="carbon">Cfluorine.html" ;"title="carbon.html" ;"title="carbon">Cfluorine">F3sulfur">Soxygen">O2)2nitrogen">N]−. Its salts are typically referred to as being metal triflimidates. Applications The anion is widely used in ionic liquids (such as trioctylmethylammonium bis(trifluoromethylsulfonyl)imide), since it is less toxic and more stable than ...
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Lithium-ion Battery
A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also sees significant use for grid-scale energy storage and military and aerospace applications. Compared to other rechargeable battery technologies, Li-ion batteries have high energy densities, low self-discharge, and no memory effect (although a small memory effect reported in LFP cells has been traced to poorly made cells). Chemistry, performance, cost and safety characteristics vary across types of lithium-ion batteries. Most commercial Li-ion cells use intercalation compounds as the active materials. The anode or negative electrode is usually graphite, although silicon-carbon is also being increasingly used. Cells can be manufactured to prioritize either energy or power density. Handheld electronics mostly use lithium polymer batteries ...
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Canadian Broadcasting Corporation
The Canadian Broadcasting Corporation (french: Société Radio-Canada), branded as CBC/Radio-Canada, is a Canadian public broadcaster for both radio and television. It is a federal Crown corporation that receives funding from the government. The English- and French-language service units of the corporation are commonly known as CBC and Radio-Canada, respectively. Although some local stations in Canada predate the CBC's founding, CBC is the oldest existing broadcasting network in Canada. The CBC was established on November 2, 1936. The CBC operates four terrestrial radio networks: The English-language CBC Radio One and CBC Music, and the French-language Ici Radio-Canada Première and Ici Musique. (International radio service Radio Canada International historically transmitted via shortwave radio, but since 2012 its content is only available as podcasts on its website.) The CBC also operates two terrestrial television networks, the English-language CBC Television and the Frenc ...
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Charge Carriers
In physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. The term is used most commonly in solid state physics. In a conducting medium, an electric field can exert force on these free particles, causing a net motion of the particles through the medium; this is what constitutes an electric current. In conducting media, particles serve to carry charge: *In many metals, the charge carriers are electrons. One or two of the valence electrons from each atom are able to move about freely within the crystal structure of the metal. The free electrons are referred to as conduction electrons, and the cloud of free electrons is called a Fermi gas. Many metals have electron and hole bands. In some, the majority carriers are holes. *In electrolytes, such as salt water, the charge carriers are ions, which are atoms or molecul ...
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University Of Waterloo
The University of Waterloo (UWaterloo, UW, or Waterloo) is a public research university with a main campus in Waterloo, Ontario Waterloo is a city in the Canadian province of Ontario. It is one of three cities in the Regional Municipality of Waterloo (formerly Waterloo County). Waterloo is situated about west-southwest of Toronto. Due to the close proximity of the ci ..., Canada. The main campus is on of land adjacent to "Uptown" Waterloo and Waterloo Park. The university also operates three satellite campuses and four affiliated school, affiliated university colleges. The university offers academic programs administered by six faculties and thirteen faculty-based schools. Waterloo operates the largest post-secondary co-operative education program in the world, with over 20,000 undergraduate students enrolled in the university's co-op program. Waterloo is a member of the U15 Group of Canadian Research Universities, U15, a group of research-intensive universities in Canada. ...
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