Whiteschist
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Whiteschist
A whiteschist is an uncommon metamorphic rock formed at high to ultra-high pressures. It has the characteristic mineral assemblage of kyanite + talc, responsible for its white colour. The name was introduced in 1973 by German mineralogist and petrologist Werner Schreyer. This rock is associated with the metamorphism of some pelites, evaporite sequences or altered basaltic or felsic intrusions. Whiteschists form in the MgO–––– (MFASH) system. Rocks of this primary chemistry are extremely uncommon and they are in most cases thought to be the result of metasomatism, metasomatic alteration, with the removal of various mobile elements. Occurrence Whiteschists occur as lenses or tectonic slices on a metre to kilometre scale within nine orogenic belts around the world. There are two occurrences in Central Africa, one in Tasmania, one in the Norwegian Caledonides, two in the Alps and three in Asia. One of the most extensive outcrops of whiteschist occurs within the L ...
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Talc
Talc, or talcum, is a Clay minerals, clay mineral, composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant. It is an ingredient in ceramics, paints, and roofing material. It is a main ingredient in many cosmetics. It occurs as Foliation (geology), foliated to Fiber, fibrous masses, and in an exceptionally rare crystal form. It has a perfect cleavage (crystal), basal cleavage and an uneven flat fracture, and it is foliated with a two-dimensional ped, platy form. The Mohs scale of mineral hardness, based on Scratch hardness, scratch hardness comparison, defines value 1 as the hardness of talc, the softest mineral. When scraped on a streak (mineralogy), streak plate, talc produces a white streak; though this indicator is of little importance, because most silicate minerals produce a white streak. Talc is translucent to ...
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Metamorphic Rock
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causing profound physical or chemical changes. During this process, the rock remains mostly in the solid state, but gradually recrystallizes to a new texture or mineral composition. The protolith may be an igneous, sedimentary, or existing metamorphic rock. Metamorphic rocks make up a large part of the Earth's crust and form 12% of the Earth's land surface. They are classified by their protolith, their chemical and mineral makeup, and their texture. They may be formed simply by being deeply buried beneath the Earth's surface, where they are subject to high temperatures and the great pressure of the rock layers above. They can also form from tectonic processes such as continental collisions, which cause horizontal pressure, friction, and distorti ...
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Anthophyllite
Anthophyllite is an orthorhombic amphibole mineral: ☐Mg2Mg5Si8O22(OH)2 (☐ is for a vacancy, a point defect in the crystal structure), magnesium iron inosilicate hydroxide. Anthophyllite is polymorphic with cummingtonite. Some forms of anthophyllite are lamellar or fibrous and are classed as asbestos. The name is derived from the Latin word ''anthophyllum'', meaning ''clove'', an allusion to the most common color of the mineral. The Anthophyllite crystal is characterized by its perfect cleavage along directions 126 degrees and 54 degrees. Occurrence Anthophyllite is the product of metamorphism of magnesium-rich rocks, especially ultrabasic igneous rocks and impure dolomitic shales. It also forms as a retrograde product rimming relict orthopyroxenes and olivine, and as an accessory mineral in cordierite-bearing gneisses and schists. Anthophyllite also occurs as a retrograde metamorphic mineral derived from ultramafic rocks along with serpentinite. Occurrence in ultramafic ...
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Hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . It has the same crystal structure as corundum () and ilmenite (). With this it forms a complete solid solution at temperatures above . Hematite naturally occurs in black to steel or silver-gray, brown to reddish-brown, or red colors. It is mined as an important ore mineral of iron. It is electrically conductive. Hematite varieties include ''kidney ore'', ''martite'' (pseudomorphs after magnetite), ''iron rose'' and ''specularite'' (specular hematite). While these forms vary, they all have a rust-red streak. Hematite is not only harder than pure iron, but also much more brittle. Maghemite is a polymorph of hematite (γ-) with the same chemical formula, but with a spinel structure like magnetite. Large deposits of hematite are found in ...
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Plagioclase Feldspar
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or 'record-groove' effect. Plagioclase is a major constituent mineral in the Earth's crust, and is consequently an important diagnostic tool in petrology for identifying the composition, origin and evolution of igneous rocks. Plagioclase is also a major constituent of rock in the highlands ...
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Phlogopite
Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica. Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O10(F,OH)2. Iron substitutes for magnesium in variable amounts leading to the more common biotite with higher iron content. For physical and optical identification, it shares most of the characteristic properties of biotite. Paragenesis Phlogopite is an important and relatively common end-member composition of biotite. Phlogopite micas are found primarily in igneous rocks, although it is also common in contact metamorphic aureoles of intrusive igneous rocks with magnesian country rocks and in marble formed from impure dolomite (dolomite with some siliclastic sediment). The occurrence of phlogopite mica within igneous rocks is difficult to constrain precisely because the primary control is rock composition as expected, but phlogopite is al ...
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Chlorite Group
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite. Chlorite minerals show a wide variety of compositions, in which magnesium, iron, aluminium, and silicon substitute for each other in the crystal structure. A complete solid solution series exists between the two most common end members, magnesium-rich clinochlore and iron-rich chamosite. In addition, manganese, zinc, lithium, and calcium species are known. The great range in composition results in considerable variation in physical, optical, and X-ray properties. Similarly, the range of chemical composition allows chlorite group minerals to exist over a wide range of temperature and pressure conditions. For this reason chlorite minerals are ubiquitous minerals within low and medium temperature metamorphic rocks, some igneous r ...
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Fugacity
In chemical thermodynamics, the fugacity of a real gas is an effective partial pressure which replaces the mechanical partial pressure in an accurate computation of the chemical equilibrium constant. It is equal to the pressure of an ideal gas which has the same temperature and molar Gibbs free energy as the real gas. Fugacities are determined experimentally or estimated from various models such as a Van der Waals gas that are closer to reality than an ideal gas. The real gas pressure and fugacity are related through the dimensionless fugacity coefficient . \varphi = \frac For an ideal gas, fugacity and pressure are equal and so . Taken at the same temperature and pressure, the difference between the molar Gibbs free energies of a real gas and the corresponding ideal gas is equal to . The fugacity is closely related to the thermodynamic activity. For a gas, the activity is simply the fugacity divided by a reference pressure to give a dimensionless quantity. This reference press ...
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Oxidation State
In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to different atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero. While fully ionic bonds are not found in nature, many bonds exhibit strong ionicity, making oxidation state a useful predictor of charge. The oxidation state of an atom does not represent the "real" formal charge on that atom, or any other actual atomic property. This is particularly true of high oxidation states, where the ionization energy required to produce a multiply positive ion is far greater than the energies available in chemical reactions. Additionally, the oxidation states of atoms in a given compound may vary depending on the choice of electronegativity scale used in their calculation. Thus, the oxidation state of an atom in a compound is purely a formalism. ...
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Metabasalt
Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance. Amphibolite frequently forms by metamorphism of mafic igneous rocks, such as basalt. However, because metamorphism creates minerals entirely based upon the chemistry of the protolith, certain 'dirty marls' and volcanic sediments may also metamorphose to an amphibolite assemblage. Deposits containing dolomite and siderite also readily yield amphibolite (tremolite-schist, grunerite-schist, and others) especially where there has been a certain amount of contact metamorphism by adjacent granitic masses. Metamorphosed basalt (metabasalt) creates ''ortho-amphibolite'' and other chemically appropriate lithologies create ''para-amphibolite''. ...
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Protolith
A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed. For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock and thus there is a wide variety of protoliths. Identifying a protolith is a major aim of metamorphic geology. Protoliths are non-metamorphic rocks and have no protoliths themselves. The non-metamorphic rocks fall into two classes: sedimentary rocks, formed from sediment, and igneous rocks, formed from magma. The source of the sediment of a sedimentary rock is termed its provenance. Magmatic protoliths can be further divided into three categories: ultramafic rock, mafic rock, and quartzo-feldspathic rock. Similarly, sedimentary protoliths can be classified as quartzo-feldspathic, pelitic, carbonate rocks, or some mixture of the three. On a geological time scale, the first protoliths were first formed shortly after the formation of the Earth ...
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Bentonite
Bentonite () is an absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-montmorillonite. Bentonite usually forms from the weathering of volcanic ash in seawater, or by hydrothermal circulation through the porosity of volcanic ash beds, which converts (devitrification) the volcanic glass ( obsidian, rhyolite, dacite) present in the ash into clay minerals. In the mineral alteration process, a large fraction (up to 40-50 wt.%) of amorphous silica is dissolved and leached away, leaving the bentonite deposit in place. Bentonite beds are white or pale blue or green (traces of reduced ) in fresh exposures, turning to a cream color and then yellow, red, or brown (traces of oxidized ) as the exposure is weathered further. As a swelling clay, bentonite has the ability to absorb large quantities of water, which increa ...
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