Water Gel Explosive
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Water Gel Explosive
A water-gel explosive is a fuel sensitized explosive mixture consisting of an aqueous ammonium nitrate solution that acts as the oxidizer. Water gels that are cap-insensitive are referred to under United States safety regulations as blasting agents. Water gel explosives have a jelly-like consistency and come in sausage-like packing stapled shut on both sides. Water-gel explosives have almost completely displaced dynamite, becoming the most-used civil blasting agents. Composition Water gels usually have many different ingredients. They contain a gelatinizing agent, also known as a thickener, that modifies their consistency, ranging from easily pourable gels to hard solids. Polyvinyl alcohol, guar gum, dextran gums, and urea-formaldehyde resins are the typical gelling agents. Guar, specifically, is a gelling agent used for the aqueous portion of the water gel explosives. The primary component of water gels is methylamine nitrate. Methylamine nitrate is the salt formed by the neu ...
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Nitro Compound
In organic chemistry, nitro compounds are organic compounds that contain one or more nitro functional groups (). The nitro group is one of the most common explosophores (functional group that makes a compound explosive) used globally. The nitro group is also strongly electron-withdrawing. Because of this property, bonds alpha (adjacent) to the nitro group can be acidic. For similar reasons, the presence of nitro groups in aromatic compounds retards electrophilic aromatic substitution but facilitates nucleophilic aromatic substitution. Nitro groups are rarely found in nature. They are almost invariably produced by nitration reactions starting with nitric acid. Synthesis Preparation of aromatic nitro compounds Aromatic nitro compounds are typically synthesized by nitration. Nitration is achieved using a mixture of nitric acid and sulfuric acid, which produce the nitronium ion (), which is the electrophile:  +    The nitration product produced on the la ...
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PETN
Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythritol, and is structurally very similar to nitroglycerin. Penta refers to the five carbon atoms of the neopentane skeleton. PETN is a very powerful explosive material with a relative effectiveness factor of 1.66. When mixed with a plasticizer, PETN forms a plastic explosive. Along with RDX it is the main ingredient of Semtex. PETN is also used as a vasodilator drug to treat certain heart conditions, such as for management of angina. History Pentaerythritol tetranitrate was first prepared and patented in 1894 by the explosives manufacturer Rheinisch-Westfälische Sprengstoff A.G. of Cologne, Germany. The production of PETN started in 1912, when the improved method of production was patented by the German government. PETN was used by the Germ ...
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Trinitrotoluene
Trinitrotoluene (), more commonly known as TNT, more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene, is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry, TNT is used to generate charge transfer salts. History TNT was first prepared in 1863 by German chemist Julius Wilbrand and originally used as a yellow dye. Its potential as an explosive was not recognized for three decades, mainly because it was too difficult to detonate because it was less sensitive than alternatives. Its explosive properties were first discovered in 1891 by another German chemist, Carl Häussermann. TNT can be safely poured when liquid into shell cases, and is so insensitive that i ...
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Casting
Casting is a manufacturing process in which a liquid material is usually poured into a mold, which contains a hollow cavity of the desired shape, and then allowed to solidify. The solidified part is also known as a ''casting'', which is ejected or broken out of the mold to complete the process. Casting materials are usually metals or various ''time setting'' materials that cure after mixing two or more components together; examples are epoxy, concrete, plaster and clay. Casting is most often used for making complex shapes that would be otherwise difficult or uneconomical to make by other methods. Heavy equipment like machine tool beds, ships' propellers, etc. can be cast easily in the required size, rather than fabricating by joining several small pieces. Casting is a 7,000-year-old process. The oldest surviving casting is a copper frog from 3200 BC. History Throughout history, metal casting has been used to make tools, weapons, and religious objects. Metal casting history and de ...
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Cartridge (firearms)
A cartridge or a round is a type of pre-assembled firearm ammunition packaging a projectile (bullet, shot, or slug), a propellant substance (usually either smokeless powder or black powder) and an ignition device (primer) within a metallic, paper, or plastic case that is precisely made to fit within the barrel chamber of a breechloading gun, for the practical purpose of convenient transportation and handling during shooting. Although in popular usage the term "bullet" is often informally used to refer to a complete cartridge, it is correctly used only to refer to the projectile. Cartridges can be categorized by the type of their primers – a small charge of an impact- or electric-sensitive chemical mixture that is located: at the center of the case head (centerfire); inside the rim ( rimfire); inside the walls on the fold of the case base that is shaped like a cup (cupfire, now obsolete); in a sideways projection that is shaped like a pin (pinfire, now obsolete); or a ...
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Nitroglycerin
Nitroglycerin (NG), (alternative spelling of nitroglycerine) also known as trinitroglycerin (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is an organic nitrate compound rather than a nitro compound, but the traditional name is retained. Invented in 1847 by Ascanio Sobrero, nitroglycerin has been used ever since as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. Since the 1880s, it has been used by militaries as an active ingredient and gelatinizer for nitrocellulose in some solid propellants such as cordite and ballistite. It is a major component in double-based smokeless propellants used by reloaders. Combined with nitrocellulose, hund ...
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Hazard
A hazard is a potential source of harm Harm is a moral and legal concept. Bernard Gert construes harm as any of the following: * pain * death * disability * mortality * loss of abil ity or freedom * loss of pleasure. Joel Feinberg gives an account of harm as setbacks to inte .... Substances, events, or circumstances can constitute hazards when their nature would allow them, even just theoretically, to cause damage to health, life, property, or any other interest of value. The probability of that harm being realized in a specific ''incident'', combined with the magnitude of potential harm, make up its risk, a term often used synonymously in colloquial speech. Hazards can be classified in several ways; they can be classified as Natural hazard, natural, Anthropogenic hazard, anthropogenic, technological, or any combination, such as in the case of the natural phenomenon of wildfire becoming more common due to human-made climate change or more harmful due to changes in buil ...
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Toxic
Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a substructure of the organism, such as a cell ( cytotoxicity) or an organ such as the liver (hepatotoxicity). By extension, the word may be metaphorically used to describe toxic effects on larger and more complex groups, such as the family unit or society at large. Sometimes the word is more or less synonymous with poisoning in everyday usage. A central concept of toxicology is that the effects of a toxicant are dose-dependent; even water can lead to water intoxication when taken in too high a dose, whereas for even a very toxic substance such as snake venom there is a dose below which there is no detectable toxic effect. Toxicity is species-specific, making cross-species analysis problematic. Newer paradigms and metrics are evolving to bypass ...
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Mononitrotoluene
Mononitrotoluene or nitrotoluene (MNT or NT), is any of three organic compounds with the formula C6H4(CH3)(NO2). They can be viewed as nitro derivatives of toluene or as methylated derivatives of nitrobenzene. Mononitrotoluene comes in three isomers, differing by the relative position of the methyl and nitro groups. All are pale yellow with faint fragrances: * ''ortho''-nitrotoluene (ONT), ''o''-nitrotoluene, or 2-nitrotoluene. m.p. = -10.4 °C * ''meta''-nitrotoluene (MNT), ''m''-nitrotoluene, or 3-nitrotoluene. m.p. = 16 °C * ''para''-nitrotoluene (PNT), ''p''-nitrotoluene, or 4-nitrotoluene. m.p. = 44.5 °C Typical use of nitrotoluene is in production of pigments, antioxidants, agricultural chemicals, and photographic chemicals. ''Ortho''-mononitrotoluene and ''para''-mononitrotoluene can be also used as detection taggants for explosive detection. See also * Toluene * Dinitrotoluene * Nitrobenzene * Trinitrotoluene Trinitrotoluene (), more c ...
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Nitrobenzene
Nitrobenzene is an organic compound with the chemical formula C6H5 NO2. It is a water-insoluble pale yellow oil with an almond-like odor. It freezes to give greenish-yellow crystals. It is produced on a large scale from benzene as a precursor to aniline. In the laboratory, it is occasionally used as a solvent, especially for electrophilic reagents. Production Nitrobenzene is prepared by nitration of benzene with a mixture of concentrated sulfuric acid, water, and nitric acid. This mixture is sometimes called "mixed acid." The production of nitrobenzene is one of the most dangerous processes conducted in the chemical industry because of the exothermicity of the reaction (Δ''H'' = −117 kJ/mol). World capacity for nitrobenzene in 1985 was about 1,700,000 tonnes. The nitration process involves formation of the nitronium ion (NO2+), followed by an electrophilic aromatic substitution reaction of it with benzene. The nitronium ion is generated by the reaction of nitric aci ...
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Galactomannan
Galactomannans are polysaccharides consisting of a mannose backbone with galactose side groups, more specifically, a (1-4)-linked beta-D-mannopyranose backbone with branchpoints from their 6-positions linked to alpha-D-galactose, (i.e. 1-6-linked alpha-D-galactopyranose). In order of increasing number of mannose-to-galactose ratio: *fenugreek, fenugreek gum, mannose:galactose ~1:1 *guar gum, mannose:galactose ~2:1 *tara gum, mannose:galactose ~3:1 *locust bean gum or ''carob gum'', mannose:galactose ~4:1 *cassia gum, mannose:galactose ~5:1 Galactomannans are often used in food products to increase the viscosity of the water phase. Guar gum has been used to add viscosity to artificial tears, but is not as stable as Carboxymethyl cellulose, carboxymethylcellulose. Food use Galactomannans are used in foods as stabilizer (chemistry), stabilisers. Guar and locust bean gum (LBG) are commonly used in ice cream to improve texture and reduce ice cream meltdown. LBG is also used extensiv ...
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