Trinitrotoluene
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Trinitrotoluene
Trinitrotoluene (), more commonly known as TNT, more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene, is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry, TNT is used to generate charge transfer salts. History TNT was first prepared in 1863 by German chemist Julius Wilbrand and originally used as a yellow dye. Its potential as an explosive was not recognized for three decades, mainly because it was too difficult to detonate because it was less sensitive than alternatives. Its explosive properties were first discovered in 1891 by another German chemist, Carl Häussermann. TNT can be safely poured when liquid into shell cases, and is so insensitive that i ...
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TNT Equivalent
TNT equivalent is a convention for expressing energy, typically used to describe the energy released in an explosion. The is a unit of energy defined by that convention to be , which is the approximate energy released in the detonation of a metric ton (1,000 kilograms) of TNT. In other words, for each gram of TNT exploded, (or 4184 joules) of energy is released. This convention intends to compare the destructiveness of an event with that of conventional explosive materials, of which TNT is a typical example, although other conventional explosives such as dynamite contain more energy. Kiloton and megaton The "kiloton (of TNT)" is a unit of energy equal to 4.184 terajoules (). The "megaton (of TNT)" is a unit of energy equal to 4.184 petajoules (). The kiloton and megaton of TNT have traditionally been used to describe the energy output, and hence the destructive power, of a nuclear weapon. The TNT equivalent appears in various nuclear weapon control treaties, and has b ...
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Shell (projectile)
A shell, in a military context, is a projectile whose payload contains an explosive, incendiary, or other chemical filling. Originally it was called a bombshell, but "shell" has come to be unambiguous in a military context. Modern usage sometimes includes large solid kinetic projectiles that is properly termed shot. Solid shot may contain a pyrotechnic compound if a tracer or spotting charge is used. All explosive- and incendiary-filled projectiles, particularly for mortars, were originally called ''grenades'', derived from the French word for pomegranate, so called because of the similarity of shape and that the multi-seeded fruit resembles the powder-filled, fragmentizing bomb. Words cognate with ''grenade'' are still used for an artillery or mortar projectile in some European languages. Shells are usually large-caliber projectiles fired by artillery, armored fighting vehicles (e.g. tanks, assault guns, and mortar carriers), warships, and autocannons. The shape ...
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Explosive Material
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or BLEVE * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate are said to be "low explosives". Explosives may a ...
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Julius Wilbrand
Julius Bernhard Friedrich Adolph Wilbrand (22 August 1839 – 22 June 1906)''Familienarchiv Familie Wilbrand'' O13, Nr. 139, Hessisches Landesmuseum Darmstadt. was a German chemist. Born in Gießen to Franz Joseph Julius Wilbrand and Albertine Knapp, he discovered trinitrotoluene in 1863,G. Carlton Smith: ''TNT. Trinitrotoluenes and Mono- and Dinitrotoluenes, Their Manufacture and Properties'', New York 1918, S. 17-18. but the compound's use as an explosive was not developed until later. Wilbrand obtained trinitrotoluene or TNT by the nitration of toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) a .... References 1839 births 1906 deaths 19th-century German chemists People from Giessen University of Giessen alumni {{Germany-chemist-stub ...
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Hexanitrobenzene
Hexanitrobenzene, also known as HNB, is a high-density explosive compound with chemical formula , obtained by oxidizing the amine group of pentanitroaniline with hydrogen peroxide in sulfuric acid. Properties HNB has the undesirable property of being moderately sensitive to light and, therefore, hard to utilize safely. As of 2021, it is not used in any production explosives applications, though it is used as a precursor chemical in one method of production of TATB, another explosive. HNB was experimentally used as a gas source for explosively pumped gas dynamic laser.Condensed explosive gas dynamic laser
United States Patent 4099142 In this application, HNB and are preferred ...
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Picric Acid
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). The name "picric" comes from el, πικρός (''pikros''), meaning "bitter", due to its bitter taste. It is one of the most acidic phenols. Like other strongly nitrated organic compounds, picric acid is an explosive, which is its primary use. It has also been used as medicine (antiseptic, burn treatments) and as a dye. History Picric acid was probably first mentioned in the alchemical writings of Johann Rudolf Glauber. Initially, it was made by nitrating substances such as animal horn, silk, indigo, and natural resin, the synthesis from indigo first being performed by Peter Woulfe during 1771. The German chemist Justus von Liebig had named picric acid (rendered in French as ). Picric acid was given that name by the French chemist Jean-Baptiste Dumas in 1841. Its synthesis from phenol, and the correct determination of its formula, were accomplished during 1841. I ...
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Picric Acid
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). The name "picric" comes from el, πικρός (''pikros''), meaning "bitter", due to its bitter taste. It is one of the most acidic phenols. Like other strongly nitrated organic compounds, picric acid is an explosive, which is its primary use. It has also been used as medicine (antiseptic, burn treatments) and as a dye. History Picric acid was probably first mentioned in the alchemical writings of Johann Rudolf Glauber. Initially, it was made by nitrating substances such as animal horn, silk, indigo, and natural resin, the synthesis from indigo first being performed by Peter Woulfe during 1771. The German chemist Justus von Liebig had named picric acid (rendered in French as ). Picric acid was given that name by the French chemist Jean-Baptiste Dumas in 1841. Its synthesis from phenol, and the correct determination of its formula, were accomplished during 1841. I ...
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Armour-piercing
Armour-piercing ammunition (AP) is a type of projectile designed to penetrate either body armour or vehicle armour. From the 1860s to 1950s, a major application of armour-piercing projectiles was to defeat the thick armour carried on many warships and cause damage to their lightly-armoured interiors. From the 1920s onwards, armour-piercing weapons were required for anti-tank warfare. AP rounds smaller than 20 mm are intended for lightly-armoured targets such as body armour, bulletproof glass, and lightly-armoured vehicles. As tank armour improved during World War II, anti-vehicle rounds began to use a smaller but dense penetrating body within a larger shell, firing at very high muzzle velocity. Modern penetrators are long rods of dense material like tungsten or depleted uranium (DU) that further improve the terminal ballistics. History The late 1850s saw the development of the ironclad warship, which carried wrought iron armour of considerable thickness. This armour ...
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Artillery
Artillery is a class of heavy military ranged weapons that launch munitions far beyond the range and power of infantry firearms. Early artillery development focused on the ability to breach defensive walls and fortifications during sieges, and led to heavy, fairly immobile siege engines. As technology improved, lighter, more mobile field artillery cannons developed for battlefield use. This development continues today; modern self-propelled artillery vehicles are highly mobile weapons of great versatility generally providing the largest share of an army's total firepower. Originally, the word "artillery" referred to any group of soldiers primarily armed with some form of manufactured weapon or armor. Since the introduction of gunpowder and cannon, "artillery" has largely meant cannons, and in contemporary usage, usually refers to shell-firing guns, howitzers, and mortars (collectively called ''barrel artillery'', ''cannon artillery'', ''gun artillery'', or - a layman t ...
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Chemistry
Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during a Chemical reaction, reaction with other Chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the properties ...
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Capital Ships
The capital ships of a navy are its most important warships; they are generally the larger ships when compared to other warships in their respective fleet. A capital ship is generally a leading or a primary ship in a naval fleet. Strategic implications There is usually no formal criterion for the classification, but it is a useful concept in naval strategy; for example, it permits comparisons between relative naval strengths in a theatre of operations without the need for considering specific details of tonnage or gun diameters. A notable example of this is the Mahanian doctrine, which was applied in the planning of the defence of Singapore in World War II, where the Royal Navy had to decide the allocation of its battleships and battlecruisers between the Atlantic and Pacific theatres. The Mahanian doctrine was also applied by the Imperial Japanese Navy, leading to its preventive move to attack Pearl Harbor and the battleships of the U.S. Pacific Fleet. The naval nature o ...
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History Of Fire Safety Legislation In The United Kingdom
The history of fire safety legislation in the United Kingdom formally covers the period from the formation of the United Kingdom of Great Britain and Ireland in 1801 but is founded in the history of such legislation in England and Wales, and Scotland before 1708, and that of the Kingdom of Great Britain from 1707 to 1800. While much British legislation applied to the United Kingdom as a whole, Scotland and Northern Ireland often had their own versions of the legislation, with slight differences. United Kingdom legislation before 1922 remained in force in the Irish Free State after its independence in that year. Legislation from predecessor states At the time of the creation of the United Kingdom in 1801, England, Scotland, and Great Britain had some legislation already in place dealing with the issues of fire safety. Kingdom of England As a result of the Great Fire of London, which started on 2 September 1666, it was soon clear that the wooden construction of London's build ...
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