Ultrahydrophobicity
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Ultrahydrophobicity
Ultrahydrophobic (or superhydrophobic) surfaces are highly hydrophobic, i.e., extremely difficult to wet. The contact angles of a water droplet on an ultrahydrophobic material exceed 150°. This is also referred to as the lotus effect, after the superhydrophobic leaves of the lotus plant. A droplet striking these kinds of surfaces can fully rebound like an elastic ball. Interactions of bouncing drops can be further reduced using special superhydrophobic surfaces that promote symmetry breaking, pancake bouncing or waterbowl bouncing. Theory In 1805, Thomas Young defined the contact angle ''θ'' by analysing the forces acting on a fluid droplet resting on a smooth solid surface surrounded by a gas. :\gamma_\ =\gamma_+\gamma_\cos where :\gamma_\ = Interfacial tension between the solid and gas :\gamma_\ = Interfacial tension between the solid and liquid :\gamma_\ = Interfacial tension between the liquid and gas ''θ'' can be measured using a contact angle goniometer. Wenzel ...
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Nelumbo
''Nelumbo'' is a genus of aquatic plants with large, showy flowers. Members are commonly called lotus, though the name is also applied to various other plants and plant groups, including the unrelated genus '' Lotus''. Members outwardly resemble those in the family Nymphaeaceae ("water lilies"), but ''Nelumbo'' is actually very distant to that family. There are only two known living species of lotus; ''Nelumbo nucifera'' is native to East Asia, South Asia, Southeast Asia and probably Australia, and is better-known. It is commonly cultivated; it is eaten and used in traditional Chinese medicine. The other lotus is ''Nelumbo lutea'', which is native to North America and the Caribbean. Horticultural hybrids have been produced between these two allopatric species. Description Ultrahydrophobicity The leaves of ''Nelumbo'' are highly water-repellent (i.e. they exhibit ultrahydrophobicity) and have given the name to what is called the lotus effect. Ultrahydrophobicity involves ...
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Lotus Effect
The lotus effect refers to self-cleaning properties that are a result of ultrahydrophobicity as exhibited by the leaves of ''Nelumbo'', the lotus flower. Dirt particles are picked up by water droplets due to the micro- and nanoscopic architecture on the surface, which minimizes the droplet's adhesion to that surface. Ultrahydrophobicity and self-cleaning properties are also found in other plants, such as ''Tropaeolum'' (nasturtium), ''Opuntia'' (prickly pear), ''Alchemilla'', cane, and also on the wings of certain insects. The phenomenon of ultrahydrophobicity was first studied by Dettre and Johnson in 1964 using rough hydrophobic surfaces. Their work developed a theoretical model based on experiments with glass beads coated with paraffin or Polytetrafluoroethylene, PTFE fluorotelomer, telomer. The self-cleaning property of ultrahydrophobic micro-nanotechnology, nanostructured surfaces was studied by Wilhelm Barthlott and Ehler in 1977, who described such self-cleaning and ultr ...
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Insect
Insects (from Latin ') are pancrustacean hexapod invertebrates of the class Insecta. They are the largest group within the arthropod phylum. Insects have a chitinous exoskeleton, a three-part body ( head, thorax and abdomen), three pairs of jointed legs, compound eyes and one pair of antennae. Their blood is not totally contained in vessels; some circulates in an open cavity known as the haemocoel. Insects are the most diverse group of animals; they include more than a million described species and represent more than half of all known living organisms. The total number of extant species is estimated at between six and ten million; In: potentially over 90% of the animal life forms on Earth are insects. Insects may be found in nearly all environments, although only a small number of species reside in the oceans, which are dominated by another arthropod group, crustaceans, which recent research has indicated insects are nested within. Nearly all insects hatch from eggs. ...
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Nanopin Film
Nanopin film is an experimental material in nanotechnology developed in 2005 with unusual superhydrophobic properties . A droplet of water makes contact with the surface of this film and forms an almost perfect sphere with a contact angle of 178 °. This happens because it is covered with nanoscale, topped-off pins or cones perpendicular to the surface. The surface is regarded as a composite material with mostly air and a small fraction constituted by the tops of the cones. When the contact angle of the cone material is sufficiently large, Cassie's law predicts large contact angle values for the composite. This particular nanopin film is produced with borosilicate glass. A solution of CoCl2•6H2O or cobalt chloride hexahydrate is heated at 60 °C for 24 hours in a chemical bath deposition to form a brucite type cobalt(II) hydroxide layer with composition :CoOH1.13Cl0.09(CO3)0.39.0.05H20 The top coating is provided by lauric acid in a separate step. A 3 square micrometer surface now ...
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Bionics
Bionics or biologically inspired engineering is the application of biological methods and systems found in nature to the study and design of engineering systems and modern technology. The word ''bionic'', coined by Jack E. Steele in August 1958, is a portmanteau from ''biology'' and ''electronics'' that was popularized by the 1970s U.S. television series ''The Six Million Dollar Man'' and ''The Bionic Woman'', both based upon the novel ''Cyborg'' by Martin Caidin. All three stories feature humans given various superhuman powers by their electromechanical implants. According to proponents of bionic technology, the transfer of technology between lifeforms and manufactured objects is desirable because evolutionary pressure typically forces living organisms – fauna and flora – to become optimized and efficient. For example, dirt- and water-repellent paint (coating) developed from the observation that practically nothing sticks to the surface of the lotus flower plant (the lot ...
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Activation Energy
In chemistry and physics, activation energy is the minimum amount of energy that must be provided for compounds to result in a chemical reaction. The activation energy (''E''a) of a reaction is measured in joules per mole (J/mol), kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). Activation energy can be thought of as the magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic state. For a chemical reaction to proceed at a reasonable rate, the temperature of the system should be high enough such that there exists an appreciable number of molecules with translational energy equal to or greater than the activation energy. The term "activation energy" was introduced in 1889 by the Swedish scientist Svante Arrhenius. Other uses Although less commonly used, activation energy also applies to nuclear reactions and various other physical phenomena. Te ...
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Langmuir (journal)
''Langmuir'' is a peer-reviewed scientific journal that was established in 1985 and is published by the American Chemical Society. It is the leading journal focusing on the science and application of systems and materials in which the interface dominates structure and function. Research areas covered include surface and colloid chemistry. The total number of citations in 2021 is 129,693 and the 2021 Impact Factor is 4.331. Langmuir publishes original research articles, invited feature articles, perspectives, and editorials. The title honors Irving Langmuir, winner of the 1932 Nobel Prize for Chemistry. The founding editor-in-chief was Arthur W. Adamson. Abstracting and indexing ''Langmuir'' is indexed in Chemical Abstracts Service, Scopus, EBSCOhost, British Library, PubMed PubMed is a free search engine accessing primarily the MEDLINE database of references and abstracts on life sciences and biomedical topics. The United States National Library of Medicine (NLM) at the N ...
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Dimer (chemistry)
A dimer () ('' di-'', "two" + ''-mer'', "parts") is an oligomer consisting of two monomers joined by bonds that can be either strong or weak, covalent or intermolecular. Dimers also have significant implications in polymer chemistry, inorganic chemistry, and biochemistry. The term ''homodimer'' is used when the two molecules are identical (e.g. A–A) and ''heterodimer'' when they are not (e.g. A–B). The reverse of dimerization is often called dissociation. When two oppositely charged ions associate into dimers, they are referred to as ''Bjerrum pairs'', after Niels Bjerrum. Noncovalent dimers Anhydrous carboxylic acids form dimers by hydrogen bonding of the acidic hydrogen and the carbonyl oxygen. For example, acetic acid forms a dimer in the gas phase, where the monomer units are held together by hydrogen bonds. Under special conditions, most OH-containing molecules form dimers, e.g. the water dimer. Excimers and exciplexes are excited structures with a short lifetime. ...
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Planta (journal)
''Planta'' is a monthly peer-reviewed scientific journal covering all areas of botany. It was established in 1925 and is published by Springer Science+Business Media. The editors-in-chief are Anastasios Melis (UC-Berkeley) and Dorothea Bartels ( Universitat Bonn). According to the ''Journal Citation Reports'', the journal has a 2012 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a scientometric index calculated by Clarivate that reflects the yearly mean number of citations of articles published in the last two years in a given journal, as i ... of 3.347. References External links * Botany journals Publications established in 1925 Springer Science+Business Media academic journals Monthly journals English-language journals {{botany-journal-stub ...
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Electrowetting
Electrowetting is the modification of the wetting properties of a surface (which is typically hydrophobic) with an applied electric field. History The electrowetting of mercury and other liquids on variably charged surfaces was probably first explained by Gabriel Lippmann in 1875 and was certainly observed much earlier. A. N. Frumkin used surface charge to change the shape of water drops in 1936. The term electrowetting was first introduced in 1981 by G. Beni and S. Hackwood to describe an effect proposed for designing a new type of display device for which they received a patent. The use of a "fluid transistor" in microfluidic circuits for manipulating chemical and biological fluids was first investigated by J. Brown in 1980 and later funded in 1984–1988 under NSF Grants 8760730 & 8822197, employing insulating dielectric and hydrophobic layer(s) (EWOD), immiscible fluids, DC or RF power; and mass arrays of miniature interleaved (saw tooth) electrodes with large or matching Indi ...
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