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Trisulfur
The molecule, known as trisulfur, sulfur trimer, thiozone, or triatomic sulfur, is a cherry-red allotrope of sulfur. It comprises about 10% of vaporised sulfur at and . It has been observed at cryogenic temperatures as a solid. Under ordinary conditions it converts to cyclooctasulfur. :8 S3 → 3 S8 Structure and bonding In terms of structure and bonding and ozone () are similar. Both adopt bent structures and are diamagnetic. Although represented with S=S double bonds, the bonding situation is more complex. The S–S distances are equivalent and are , and with an angle at the central atom of . However, cyclic , where the sulfur atoms are arranged in an equilateral triangle with three single bonds (similar to cyclic ozone and cyclopropane), is calculated to be lower in energy than the bent structure experimentally observed. The name thiozone was invented by Hugo Erdmann in 1908 who hypothesized that comprises a large proportion of liquid sulfur. However its existen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lapis Lazuli
Lapis lazuli (; ), or lapis for short, is a deep-blue metamorphic rock used as a semi-precious stone that has been prized since antiquity for its intense color. As early as the 7th millennium BC, lapis lazuli was mined in the Sar-i Sang mines,David Bomford and Ashok Roy, ''A Closer Look- Colour'' (2009), National Gallery Company, London, () in Shortugai, and in other mines in Badakhshan province in northeast Afghanistan. Lapis lazuli artifacts, dated to 7570 BC, have been found at Bhirrana, which is the oldest site of Indus Valley civilisation. Lapis was highly valued by the Indus Valley Civilisation (7570–1900 BC). Lapis beads have been found at Neolithic burials in Mehrgarh, the Caucasus, and as far away as Mauritania. It was used in the funeral mask of Tutankhamun (1341–1323 BC). By the end of the Middle Ages, lapis lazuli began to be exported to Europe, where it was ground into powder and made into ultramarine, the finest and most expensive of all blue pigments. U ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Allotrope Of Sulfur
The element sulfur exists as many allotropes. In number of allotropes, sulfur is second only to carbon. Greenwood, 652 In addition to the allotropes, each allotrope often exists in polymorphs (different crystal structures of the same covalently bonded S molecules) delineated by Greek prefixes (α, β, etc.). Furthermore, because elemental sulfur has been an item of commerce for centuries, its various forms are given traditional names. Early workers identified some forms that have later proved to be single or mixtures of allotropes. Some forms have been named for their appearance, e.g. "mother of pearl sulfur", or alternatively named for a chemist who was pre-eminent in identifying them, e.g. "Muthmann's sulfur I" or "Engel's sulfur". Steudel, 17 The most commonly encountered form of sulfur is the orthorhombic polymorph of , which adopts a puckered ring – or "crown" – structure. Two other polymorphs are known, also with nearly identical molecular structures. Greenwood, 654 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ozone
Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lower atmosphere to (dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the latter, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation. Ozone's odour is reminiscent of chlorine, and detectable by many people at concentrations of as little as in air. Ozone's O3 structure was determined in 1865. The molecule was later proven to have a bent structure and to be weakly diamagnetic. In standard conditions, ozone is a pale blue gas that condenses at cryogenic temperatures to a dark blue liquid and finally a violet-black ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Monoxide
Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest molecule of the oxocarbon family. In coordination complexes the carbon monoxide ligand is called carbonyl. It is a key ingredient in many processes in industrial chemistry. The most common source of carbon monoxide is the partial combustion of carbon-containing compounds, when insufficient oxygen or heat is present to produce carbon dioxide. There are also numerous environmental and biological sources that generate and emit a significant amount of carbon monoxide. It is important in the production of many compounds, including drugs, fragrances, and fuels. Upon emission into the atmosphere, carbon monoxide affects several processes that contribute to climate change. Carbon monoxide has important biological roles across phylogenetic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrothermal Fluid
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with the assistance of. Roderick McKenzie.'' Oxford: Clarendon Press. and θέρμη, ''heat'' ). Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earth's crust. In general, this occurs near volcanic activity, but can occur in the shallow to mid crust along deeply penetrating fault irregularities or in the deep crust related to the intrusion of granite, or as the result of orogeny or metamorphism. Seafloor hydrothermal circulation Hydrothermal circulation in the oceans is the passage of the water through mid-oceanic ridge systems. The term includes both the circulation of the well-known, high-temperature vent waters near the ridge crests, and the much-lower-temperature, diffuse flow of water through sedi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Raman Frequency
Raman spectroscopy () (named after Indian physicist C. V. Raman) is a spectroscopic technique typically used to determine vibrational modes of molecules, although rotational and other low-frequency modes of systems may also be observed. Raman spectroscopy is commonly used in chemistry to provide a structural fingerprint by which molecules can be identified. Raman spectroscopy relies upon inelastic scattering of photons, known as Raman scattering. A source of monochromatic light, usually from a laser in the visible, near infrared, or near ultraviolet range is used, although X-rays can also be used. The laser light interacts with molecular vibrations, phonons or other excitations in the system, resulting in the energy of the laser photons being shifted up or down. The shift in energy gives information about the vibrational modes in the system. Infrared spectroscopy typically yields similar yet complementary information. Typically, a sample is illuminated with a laser beam. Elec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Yves Klein
Yves Klein (; 28 April 1928 – 6 June 1962) was a French artist and an important figure in post-war European art. He was a leading member of the French artistic movement of Nouveau réalisme founded in 1960 by art critic Pierre Restany. Klein was a pioneer in the development of performance art, and is seen as an inspiration to and as a forerunner of minimal art, as well as pop art. Biography Klein was born in Nice, in the Alpes-Maritimes department of France. His parents, Fred Klein and Marie Raymond, were both painters. His father painted in a loose post-impressionist style, while his mother was a leading figure in Art informel, and held regular soirées with other leading practitioners of this Parisian abstract movement. Klein received no formal training in art, but his parents exposed him to different styles. His father was a figurative style painter, while his mother had an interest in abstract expressionism. From 1942 to 1946, Klein studied at the École Nationale de ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
International Klein Blue
International Klein Blue (IKB) is a deep blue hue first mixed by the French artist Yves Klein. IKB's visual impact comes from its heavy reliance on ultramarine, as well as Klein's often thick and textured application of paint to canvas. History International Klein Blue (IKB) was developed by Yves Klein in collaboration with Edouard Adam, a Parisian art paint supplier whose shop is still in business on the Boulevard Edgar-Quinet in Montparnasse. IKB uses a matte, synthetic resin binder which suspends the color and allows the pigment to maintain as much of its original qualities and intensity of color as possible. The synthetic resin used in the binder is a polyvinyl acetate developed and marketed at the time under the name Rhodopas M or M60A by the French pharmaceutical company Rhône-Poulenc. Adam still sells the binder under the name "Médium Adam 25". [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ultramarine
Ultramarine is a deep blue color pigment which was originally made by grinding lapis lazuli into a powder. The name comes from the Latin ''ultramarinus'', literally 'beyond the sea', because the pigment was imported into Europe from mines in Afghanistan by Italian traders during the 14th and 15th centuries. Ultramarine was the finest and most expensive blue used by Renaissance painters. It was often used for the robes of the Virgin Mary and symbolized holiness and humility. It remained an extremely expensive pigment until a synthetic ultramarine was invented in 1826. Structure The pigment consists primarily of a zeolite-based mineral containing small amounts of polysulfides. It occurs in nature as a proximate component of lapis lazuli containing a blue cubic mineral called lazurite. In the Colour Index International, the pigment of ultramarine is identified as P. Blue 29 77007. The major component of lazurite is a complex sulfur-containing sodium-silicate (Na8–10Al6Si6 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lazurite
Lazurite is a tectosilicate mineral with sulfate, sulfur and chloride with formula . It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually massive and forms the bulk of the gemstone lapis lazuli. Lazurite is a deep‐blue to greenish‐blue. The colour is due to the presence of anions. It has a Mohs hardness of 5.0 to 5.5 and a specific gravity of 2.4. It is translucent with a refractive index of 1.50. It is fusible at 3.5 on Wolfgang Franz von Kobell's fusibility scale, and soluble in HCl. It commonly contains or is associated with grains of pyrite. Lazurite is a product of contact metamorphism of limestone and is typically associated with calcite, pyrite, diopside, humite, forsterite, hauyne and muscovite. Other blue minerals, such as the carbonate azurite and the phosphate lazulite, may be confused with lazurite, but are easily distinguished with careful examina ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Valence Isoelectronic
Isoelectronicity is a phenomenon observed when two or more molecules have the same structure (positions and connectivities among atoms) and the same electronic configurations, but differ by what specific elements are at certain locations in the structure. For example, , , and are isoelectronic, while and = are not. This definition is sometimes termed ''valence isoelectronicity''. Definitions can sometimes be not as strict, sometimes requiring identity of the ''total'' electron count and with it the entire electronic configuration. More usually, definitions are broader, and may extend to allowing different numbers of atoms in the species being compared.A. A. Aradi & T. P. Fehlner, "Isoelectronic Organometallic Molecules", in F. G. A. Stone & Robert West (eds.) ''Advances in Organometallic Chemistry Vol. 30'' (1990), Chapter 5 (at p. 190google books link/ref> The importance of the concept lies in identifying significantly related species, as pairs or series. Isoelectroni ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ozonide
Ozonide is the polyatomic anion . Cyclic organic compounds formed by the addition of ozone () to an alkene are also called ozonides. Ionic ozonides Inorganic ozonides are dark red salts. The anion has the bent shape of the ozone molecule. Inorganic ozonides are formed by burning potassium, rubidium, or caesium in ozone, or by treating the alkali metal hydroxide with ozone; this yields potassium ozonide, rubidium ozonide, and caesium ozonide respectively. They are very sensitive explosives that have to be handled at low temperatures in an atmosphere consisting of an inert gas. Lithium and sodium ozonide are extremely labile and must be prepared by low-temperature ion exchange starting from . Sodium ozonide, , which is prone to decomposition into NaOH and , was previously thought to be impossible to obtain in pure form. However, with the help of cryptands and methylamine, pure sodium ozonide may be obtained as red crystals isostructural to . Ionic ozonides are being investi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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