Tribocorrosion
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Tribocorrosion
Tribocorrosion is a material degradation process due to the combined effect of corrosion and wear. The name tribocorrosion expresses the underlying disciplines of tribology and corrosion. Tribology is concerned with the study of friction, lubrication and wear (its name comes from the Greek "tribo" meaning to rub) and corrosion is concerned with the chemical and electrochemical interactions between a material, normally a metal, and its environment. As a field of research tribocorrosion is relatively new, but tribocorrosion phenomena have been around ever since machines and installations are being used. Wear is a mechanical material degradation process occurring on rubbing or impacting surfaces, while corrosion involves chemical or electrochemical reactions of the material. Corrosion may accelerate wear and wear may accelerate corrosion. One then speaks of corrosion accelerated wear or wear accelerated corrosion. Both these phenomena, as well as fretting corrosion (which results from ...
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Wear
Wear is the damaging, gradual removal or deformation of material at solid surfaces. Causes of wear can be mechanical (e.g., erosion) or chemical (e.g., corrosion). The study of wear and related processes is referred to as tribology. Wear in machine elements, together with other processes such as fatigue and creep, causes functional surfaces to degrade, eventually leading to material failure or loss of functionality. Thus, wear has large economic relevance as first outlined in the Jost Report. Abrasive wear alone has been estimated to cost 1-4% of the gross national product of industrialized nations. Wear of metals occurs by plastic displacement of surface and near-surface material and by detachment of particles that form wear debris. The particle size may vary from millimeters to nanometers. This process may occur by contact with other metals, nonmetallic solids, flowing liquids, solid particles or liquid droplets entrained in flowing gasses. The wear rate is affected by f ...
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Elegant Degradation
Elegant degradation is a term used in engineering to describe what occurs to machines which are subject to constant, repetitive stress. Externally, such a machine maintains the same appearance to the user, appearing to function properly. Internally, the machine slowly weakens over time. Eventually, unable to withstand the stress, it eventually breaks down. Compared to graceful degradation, the operational quality does not decrease at all, but the breakdown may be just as sudden. This term's meaning varies depending on context and field, and may not be strictly considered exclusive to engineering. For instance, this is used as a mechanism in the food industry as applied in the degradation of lignin, cellulose, pentosan, and polymers, among others. The concept is also used to extract chemicals such as the elegant degradation of ''Paederus fuscipes'' to obtain pederin and hemiacetal pseuodopederin. In this process degradation is induced by heat. A play with the same name also used it a ...
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Titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in sea water, aqua regia, and chlorine. Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791 and was named by Martin Heinrich Klaproth after the Titans of Greek mythology. The element occurs within a number of minerals, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere; it is found in almost all living things, as well as bodies of water, rocks, and soils. The metal is extracted from its principal mineral ores by the Kroll and Hunter processes. The most common compound, titanium dioxide, is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and catalysts; and ...
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Tribology
Tribology is the science and engineering of interacting surfaces in relative Motion (physics), motion. It includes the study and application of the principles of friction, lubrication and wear. Tribology is highly interdisciplinary, drawing on many academic fields, including physics, chemistry, materials science, mathematics, biology and engineering. People who work in the field of tribology are referred to as ''tribologists''. The fundamental objects of study in tribology are tribosystems, which are physical systems of contacting surfaces. In lubricated tribosystems, contact stress can create tribofilms. Subfields of tribology include biotribology, nanotribology, space tribology and tribotronics. Etymology The word ''tribology'' derives from the Ancient Greek, Greek root τριβ- of the verb , ''wiktionary:tribo-, tribo'', "I rub" in classic Greek, and the suffix ''-logy'' from , ''wiktionary:-logia, -logia'' "study of", "knowledge of". Peter Jost coined the word in 1966, in t ...
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Glaze (metallurgy)
Compacted oxide layer glaze describes the often shiny, wear-protective layer of oxide formed when two metals (or a metal and ceramic) are slid against each other at high temperature in an oxygen-containing atmosphere. The layer forms on either or both of the surfaces in contact and can protect against wear. Background A not often used definition of ''glaze'' is the highly sintered compacted oxide layer formed due to the sliding of either two metallic surfaces (or sometimes a metal surface and ceramic surface) at high temperatures (normally several hundred degrees Celsius) in oxidizing conditions. The sliding or tribological action generates oxide debris that can be compacted against one or both sliding surfaces and, under the correct conditions of load, sliding speed and oxide chemistry as well as (high) temperature, sinter together to form a 'glaze' layer. The 'glaze' formed in such cases is actually a crystalline oxide, with a very small crystal or grain size having been shown ...
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Faraday's Laws Of Electrolysis
Faraday's laws of electrolysis are quantitative relationships based on the electrochemical research published by Michael Faraday in 1833. First law Michael Faraday reported that the mass (m) of elements deposited at an electrode is directly proportional to the charge (Q; SI units are ampere seconds or coulombs). \begin m &\propto Q \\ \implies \frac &= Z \end Here, the constant of proportionality, Z, is called the electro-chemical equivalent (e.c.e) of the substance. Thus, the e.c.e. can be defined as the mass of the substance deposited/liberated per unit charge. Second law Faraday discovered that when the same amount of electric current is passed through different electrolytes/elements connected in series, the mass of the substance liberated/deposited at the electrodes is directly proportional to their chemical equivalent/equivalent weight (E). This turns out to be the molar mass (M) divided by the valence (v) : m \propto E : E = \frac : \implies m_1 : m_2 : m_3 : ... ...
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Wear (journal)
Wear is a scientific journal publishing papers on wear and friction. The papers may fall within the subjects of physics, chemistry, material science or mechanical engineering. It is published by Elsevier. See also * List of periodicals published by Elsevier This is a list of scientific, technical and general interest periodicals published by Elsevier or one of its imprints or subsidiary companies. Both printed items and electronic publications are included in this list. A B C D E F G ... External links Wear homepage Elsevier academic journals Physics journals {{physics-journal-stub ...
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EPFL Press
The Presses polytechniques et universitaires romandes (PPUR, literally "Polytechnic and university press of French-speaking Switzerland") is a Swiss academic publishing house. It is based in Lausanne, on the Lausanne campus, in the Rolex Learning Center.http://www.ppur.org (page visited on 11 October 2013). The Presses polytechniques et universitaires romandes has an English-language imprint called EPFL Press. Publications The Presses polytechniques et universitaires romandes publish « Le savoir suisse » (literally "The Swiss knowledge"). This series was created in 2002 in collaboration with Bertil Galland. Between 2002 and 2012, it edited 88 books and sold 150'000 copies (in French).Nicolas Dufour, "La collection « Le Savoir suisse » vise d'autres terres", ''Le Temps ''Le Temps'' ( literally "The Time") is a Swiss French-language daily newspaper published in Berliner format in Geneva by Le Temps SA. It is the sole nationwide French-language non-specialised daily new ...
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Oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and fats, as ...
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Aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity tow ...
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Passive Metal
Passive may refer to: * Passive voice, a grammatical voice common in many languages, see also Pseudopassive * Passive language, a language from which an interpreter works * Passivity (behavior), the condition of submitting to the influence of one's superior * Passive-aggressive behavior, resistance to following through with expectations in interpersonal or occupational situations * Passive income, income resulting from cash flow received on a regular basis * Passive immunity, the transfer of active humoral immunity * Passive experience, observation lacking recipricol interaction; and wrought with delusion of control. Science and technology * Passivation (chemistry), process of making a material "passive" in relation to another material prior to using the materials together * Passivity (engineering) a property of engineering systems, particularly in analog electronics and control systems * Passive solar building design, which uses (or avoids) sunlight as an energy source without a ...
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Corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion. In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen, hydrogen or hydroxide. Rusting, the formation of iron oxides, is a well-known example of electrochemical corrosion. This type of damage typically produces oxide(s) or salt(s) of the original metal and results in a distinctive orange colouration. Corrosion can also occur in materials other than metals, such as ceramics or polymers, although in this context, the term "degradation" is more common. Corrosion degrades the useful properties of materials and structures including strength, appearance and permeability to liquids and gases. Many structural ...
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