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Table Of Explosive Detonation Velocities
This is a compilation of published detonation velocities for various high explosive compounds. Detonation velocity is the speed with which the detonation shock wave travels through the explosive. It is a key, directly measurable indicator of explosive performance, but depends on density which must always be specified, and may be too low if the test charge diameter is not large enough. Especially for little studied explosives there may be divergent published values due to charge diameter issues. In liquid explosives, like nitroglycerin, there may be two detonation velocities, one much higher than the other. The detonation velocity values presented here are typically for the highest practical density which maximizes achievable detonation velocity.Cooper, Paul W. (1996). ''Explosives Engineering'', New York: Wiley-VCH. The velocity of detonation is an important indicator for overall energy and power of detonation, and in particular for the brisance or shattering effect of an explosive ...
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Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds in the range of 1 km/sec and differ from deflagrations which have subsonic flame speeds in the range of 1 m/sec. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. The detonation velocity , velocity of detonation in solid and liquid explosives is much higher than that in gaseous ones, which allows the wave system to be observed with greater detail (higher Image resolution , resolution). A very wide variety of fuels may occur as gases (e.g. hydrogen), droplet fogs, or dust suspensions. In addition to dioxygen, oxidants can include halogen compounds, ozone, hydrogen peroxide and Nitrogen oxide , oxides of nitrogen. Gaseous detonations are often associated with a mixture of fuel and oxidan ...
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Aliphatic Compound
In organic chemistry, hydrocarbons ( compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (; G. ''aleiphar'', fat, oil). Aliphatic compounds can be saturated, like hexane, or unsaturated, like hexene and hexyne. Open-chain compounds, whether straight or branched, and which contain no rings of any type, are always aliphatic. Cyclic compounds can be aliphatic if they are not aromatic. Structure Aliphatic compounds can be saturated, joined by single bonds ( alkanes), or unsaturated, with double bonds (alkenes) or triple bonds ( alkynes). Besides hydrogen, other elements can be bound to the carbon chain, the most common being oxygen, nitrogen, sulfur, and chlorine. The least complex aliphatic compound is methane (CH4). Properties Most aliphatic compounds are flammable, allowing the use of hydrocarbons as fuel, such as methane in Bunsen burners and as liquefied natural gas (LNG), and ethyne ( acetylen ...
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Cyclotetramethylene Tetranitramine
HMX, also called octogen, is a powerful and relatively insensitive nitroamine high explosive, chemically related to RDX. Like RDX, the compound's name is the subject of much speculation, having been variously listed as High Melting Explosive, Her Majesty's Explosive, High-velocity Military Explosive, or High-Molecular-weight RDX. The molecular structure of HMX consists of an eight-membered ring of alternating carbon and nitrogen atoms, with a nitro group attached to each nitrogen atom. Because of its high molecular weight, it is one of the most potent chemical explosives manufactured, although a number of newer ones, including HNIW and ONC, are more powerful. Production HMX is more complicated to manufacture than most explosives, and this confines it to specialist applications. It may be produced by nitration of hexamine in the presence of acetic anhydride, paraformaldehyde and ammonium nitrate. RDX produced using the Bachmann Process usually contains 8–10% HMX. Applicati ...
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Cyclotrimethylenetrinitramine
RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, is an organic compound with the formula (O2N2CH2)3. It is a white solid without smell or taste, widely used as an explosive. Chemically, it is classified as a nitroamine alongside HMX, which is a more energetic explosive than TNT. It was used widely in World War II and remains common in military applications. RDX is often used in mixtures with other explosives and plasticizers or phlegmatizers (desensitizers); it is the explosive agent in C-4 plastic explosive. It is stable in storage and is considered one of the most energetic and brisant of the military high explosives, with a relative effectiveness factor of 1.60. Name RDX is also known, but less commonly, as cyclonite, hexogen (particularly in Russian, French, German and German-influenced languages), T4, and, chemically, as cyclotrimethylenetrinitramine. In the 1930s, the Royal Arsenal, Woolwich, started investigating cyclonite to use ...
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Nitroguanidine
Nitroguanidine - sometimes abbreviated NGu - is a colorless, crystalline solid that melts at 257 °C and decomposes at 254 °C. Nitroguanidine is an extremely insensitive but powerful high explosive. Wetting it with > 20 wt.-% water effects desensitization from HD 1.1 down to HD 4.1 (flammable solid). Nitroguanidine is used as an energetic material, i.e., propellant or high explosive, precursor for insecticides, and for other purposes. Manufacture Nitroguanidine is produced worldwide on a large scale starting with the reaction of dicyandiamide (DCD) with ammonium nitrate to afford the salt guanidinium nitrate, which is then nitrated by treatment with concentrated sulfuric acid at low temperature. : (NH2)3O3 → (NH2)2CNNO2 + H2O Nitroguanidine can also be generated by treatment of urea with ammonium nitrate (via the BMA process). However, owing to problems of reliability and safety, this process has never been commercialized despite its attractive economic feat ...
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Ethylenedinitramine
Ethylenedinitramine (EDNA, also Haleite or Explosive H) is an explosive chemical compound of the nitroamine class, a derivative of the ethylenediamine. Ednatol Ednatol is a yellow high explosive, comprising about ethylenedinitramine (aka Haleite or Explosive H) and 45% TNT. It was developed in the United States circa 1935 and used as a substitute for Composition B in large general purpose and fragmentati ... is a high explosive comprising about 58% ethylenedinitramine and 42% TNT. References {{explosive-stub Explosive chemicals Nitroamines ...
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Xylitol Pentanitrate
Xylitol pentanitrate (XPN) is a nitrated ester primary explosive first synthesized in 1891 by Gabriel Bertrand. Law enforcement has taken an interest in XPN along with erythritol tetranitrate (ETN) and pentaerythritol tetranitrate (PETN) due to their ease of synthesis, which makes them accessible to amateur chemists and terrorists.{{Cite journal, last1=Dong, first1=Jun, last2=Yan, first2=Qi-Long, last3=Liu, first3=Pei-Jin, last4=He, first4=Wei, last5=Qi, first5=Xiao-Fei, last6=Zeman, first6=Svatopluk, date=2018, title=The correlations among detonation velocity, heat of combustion, thermal stability and decomposition kinetics of nitric esters, url=http://link.springer.com/10.1007/s10973-017-6706-5, journal=Journal of Thermal Analysis and Calorimetry, language=en, volume=131, issue=2, pages=1391–1403, doi=10.1007/s10973-017-6706-5, s2cid=102678177 , issn=1388-6150 Properties At room temperature XPN exists as a white crystalline solid. When heated to 163 °C, liquid xylito ...
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Erythritol Tetranitrate
Erythritol tetranitrate (ETN) is an explosive compound chemically similar to PETN, though it is thought to be slightly more sensitive to friction and impact. Like many nitrate esters, ETN acts as a vasodilator, and was the active ingredient in the original "sustained release" tablets, made under a process patent in the early 1950s, called " nitroglyn". Ingesting ETN or prolonged skin contact can lead to absorption and what is known as a "nitro headache". Properties ETN has a relatively high velocity of detonation of 8206 m/s at a density of 1.7219 (±0.0025) g/cm3. It is white in color and odorless. ETN is commonly cast into mixtures with other high explosives. It is somewhat sensitive to shock and friction, so care needs to be taken while handling. ETN dissolves readily in acetone and other ketone solvents. The impact and friction sensitivity is slightly higher than the sensitivity of pentaerythritol tetranitrate (PETN). The sensitivity of melt cast and press ...
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Pentaerythritol Tetranitrate
Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythritol, and is structurally very similar to nitroglycerin. Penta refers to the five carbon atoms of the neopentane skeleton. PETN is a very powerful explosive material with a relative effectiveness factor of 1.66. When mixed with a plasticizer, PETN forms a plastic explosive. Along with RDX it is the main ingredient of Semtex. PETN is also used as a vasodilator drug to treat certain heart conditions, such as for management of angina. History Pentaerythritol tetranitrate was first prepared and patented in 1894 by the explosives manufacturer Rheinisch-Westfälische Sprengstoff A.G. of Cologne, Germany. The production of PETN started in 1912, when the improved method of production was patented by the German government. PETN was used by the ...
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Mannitol Hexanitrate
Mannitol hexanitrate is a powerful explosive. Physically, it is a powdery solid at normal temperature ranges, with density of 1.73 g/cm3. The chemical name is hexanitromannitol and it is also known as nitromannite, MHN, and nitromannitol, and by the trademarks Nitranitol and Mannitrin. It is more stable than nitroglycerin, and it is used in detonators. Mannitol hexanitrate is a secondary explosive formed by the nitration of mannitol, a sugar alcohol. The product is used in medicine as a vasodilator and as an explosive in blasting caps. Its sensitivity is high, particularly at high temperatures (> 75 °C) where it is slightly more sensitive than nitroglycerine. Nitromannite is a class B explosive. The production of pure MHN is not a trivial task, since most preparations will yield a mixture of MHN and lower esters (pentanitrate and lower). See also * Pentaerythritol tetranitrate Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, p ...
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Nitroglycerine
Nitroglycerin (NG), (alternative spelling of nitroglycerine) also known as trinitroglycerin (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is an organic nitrate compound rather than a nitro compound, but the traditional name is retained. Invented in 1847 by Ascanio Sobrero, nitroglycerin has been used ever since as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. Since the 1880s, it has been used by militaries as an active ingredient and gelatinizer for nitrocellulose in some solid propellants such as cordite and ballistite. It is a major component in double-based smokeless propellants used by reloaders. Combined with nitrocel ...
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Ethylene Glycol Dinitrate
Ethylene glycol dinitrate, abbreviated EGDN and NGC, also known as Nitroglycol, is a colorless, oily, explosive liquid obtained by nitrating ethylene glycol. It is similar to nitroglycerine in both manufacture and properties, though it is more volatile and less viscous. Unlike nitroglycerine, the chemical has a perfect oxygen balance, meaning that its ideal exothermic decomposition would completely convert it to low energy carbon dioxide, water, and nitrogen gas, with no excess unreacted substances, without needing to react with anything else. History and production Pure EGDN was first produced by the Belgian chemist Louis Henry (1834–1913) in 1870 by dropping a small amount of ethylene glycol into a mixture of nitric and sulfuric acids cooled to 0 °C. The previous year, August Kekulé had produced EGDN by the nitration of ethylene, but this was actually contaminated with beta-nitroethyl nitrate. Other investigators preparing NGc before publication in 1926 of Rinke ...
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