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Trihydrogen Cation
The trihydrogen cation or protonated molecular hydrogen ( IUPAC name: hydrogen onium ion) is a cation (positive ion) with formula , consisting of three hydrogen nuclei (protons) sharing two electrons. The trihydrogen cation is one of the most abundant ions in the universe. It is stable in the interstellar medium (ISM) due to the low temperature and low density of interstellar space. The role that plays in the gas-phase chemistry of the ISM is unparalleled by any other polyatomic ion. The trihydrogen cation is the simplest triatomic molecule, because its two electrons are the only valence electrons in the system. It is also the simplest example of a three-center two-electron bond system. History was first discovered by J. J. Thomson in 1911. While using an early form of mass spectrometry to study the resultant species of plasma discharges, he discovered a large abundance of a polyatomic ion with a mass-to-charge ratio of 3. He stated that the only two possibilities were ...
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Space-filling Model
In chemistry, a space-filling model, also known as a ''calotte model'', is a type of three-dimensional (3D) molecular model where the atoms are represented by spheres whose radii are proportional to the radii of the atoms and whose center-to-center distances are proportional to the distances between the atomic nuclei, all in the same scale. Atoms of different chemical elements are usually represented by spheres of different colors. Space-filling calotte models are also referred to as CPK models after the chemists Robert Corey, Linus Pauling, and Walter Koltun, who over a span of time developed the modeling concept into a useful form. They are distinguished from other 3D representations, such as the ball-and-stick and skeletal models, by the use of the "full size" space-filling spheres for the atoms. The models are tactile and manually rotatable. They are useful for visualizing the effective shape and relative dimensions of a molecule, and (because of the rotatability) the s ...
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Valence Electron
In chemistry and physics, valence electrons are electrons in the outermost shell of an atom, and that can participate in the formation of a chemical bond if the outermost shell is not closed. In a single covalent bond, a shared pair forms with both atoms in the bond each contributing one valence electron. The presence of valence electrons can determine the element's chemical properties, such as its valence—whether it may bond with other elements and, if so, how readily and with how many. In this way, a given element's reactivity is highly dependent upon its electronic configuration. For a main-group element, a valence electron can exist only in the outermost electron shell; for a transition metal, a valence electron can also be in an inner shell. An atom with a closed shell of valence electrons (corresponding to a noble gas configuration) tends to be chemically inert. Atoms with one or two valence electrons more than a closed shell are highly reactive due to the relativ ...
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Emission Line
A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules. These "fingerprints" can be compared to the previously collected ones of atoms and molecules, and are thus used to identify the atomic and molecular components of stars and planets, which would otherwise be impossible. Types of line spectra Spectral lines are the result of interaction between a quantum system (usually atoms, but sometimes molecules or atomic nuclei) and a single photon. When a photon has about the right amount of energy (which is connected to its frequency) to allow a change in the energy state of the system (in the case of an atom this is usually an electron changing orbitals), the photon is absorbed. Then the energy will be spontaneously re-emitted, either as one photon at the same f ...
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Frequency Modulation
Frequency modulation (FM) is a signal modulation technique used in electronic communication, originally for transmitting messages with a radio wave. In frequency modulation a carrier wave is varied in its instantaneous frequency in proportion to a property, primarily the instantaneous amplitude, of a message signal, such as an audio signal. The technology is used in telecommunications, radio broadcasting, signal processing, and Run-length limited#FM: .280.2C1.29 RLL, computing. In Analog signal, analog frequency modulation, such as radio broadcasting of voice and music, the instantaneous frequency deviation, i.e. the difference between the frequency of the carrier and its center frequency, has a functional relation to the modulating signal amplitude. Digital data can be encoded and transmitted with a type of frequency modulation known as frequency-shift keying (FSK), in which the instantaneous frequency of the carrier is shifted among a set of frequencies. The frequencies m ...
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Spectroscopy
Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum. Spectroscopy, primarily in the electromagnetic spectrum, is a fundamental exploratory tool in the fields of astronomy, chemistry, materials science, and physics, allowing the composition, physical structure and electronic structure of matter to be investigated at the atomic, molecular and macro scale, and over astronomical distances. Historically, spectroscopy originated as the study of the wavelength dependence of the absorption by gas phase matter of visible light dispersed by a prism. Current applications of spectroscopy include biomedical spectroscopy in the areas of tissue analysis and medical imaging. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associa ...
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Physical Review Letters
''Physical Review Letters'' (''PRL''), established in 1958, is a peer-reviewed, scientific journal that is published 52 times per year by the American Physical Society. The journal is considered one of the most prestigious in the field of physics. Over a quarter of Physics Nobel Prize-winning papers between 1995 and 2017 were published in it. ''PRL'' is published both online and as a print journal. Its focus is on short articles ("letters") intended for quick publication. The Lead Editor is Hugues Chaté. The Managing Editor is Robert Garisto. History The journal was created in 1958. Samuel Goudsmit, who was then the editor of '' Physical Review'', the American Physical Society's flagship journal, organized and published ''Letters to the Editor of Physical Review'' into a new standalone journal'','' which became ''Physical Review Letters''. It was the first journal intended for the rapid publication of short articles, a format that eventually became popular in many other fiel ...
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Astrophysical Journal
''The Astrophysical Journal'' (''ApJ'') is a peer-reviewed scientific journal of astrophysics and astronomy, established in 1895 by American astronomers George Ellery Hale and James Edward Keeler. The journal discontinued its print edition and became an electronic-only journal in 2015. Since 1953, ''The Astrophysical Journal Supplement Series'' (''ApJS'') has been published in conjunction with ''The Astrophysical Journal'', with generally longer articles to supplement the material in the journal. It publishes six volumes per year, with two 280-page issues per volume. ''The Astrophysical Journal Letters'' (''ApJL''), established in 1967 by Subrahmanyan Chandrasekhar as Part 2 of ''The Astrophysical Journal'', is now a separate journal focusing on the rapid publication of high-impact astronomical research. The three journals were published by the University of Chicago Press for the American Astronomical Society until, in January 2009, publication was transferred to IOP Publis ...
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Electronvolt
In physics, an electronvolt (symbol eV), also written electron-volt and electron volt, is the measure of an amount of kinetic energy gained by a single electron accelerating through an Voltage, electric potential difference of one volt in vacuum. When used as a Units of energy, unit of energy, the numerical value of 1 eV in joules (symbol J) is equal to the numerical value of the Electric charge, charge of an electron in coulombs (symbol C). Under the 2019 revision of the SI, this sets 1 eV equal to the exact value Historically, the electronvolt was devised as a standard unit of measure through its usefulness in Particle accelerator#Electrostatic particle accelerators, electrostatic particle accelerator sciences, because a particle with electric charge ''q'' gains an energy after passing through a voltage of ''V''. Definition and use An electronvolt is the amount of energy gained or lost by a single electron when it moves through an Voltage, electric potential differenc ...
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Exothermic
In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity (e.g. a battery), or sound (e.g. explosion heard when burning hydrogen). The term ''exothermic'' was first coined by 19th-century French chemist Marcellin Berthelot. The opposite of an exothermic process is an endothermic process, one that absorbs energy, usually in the form of heat. The concept is frequently applied in the physical sciences to chemical reactions where chemical bond energy is converted to thermal energy (heat). Two types of chemical reactions Exothermic and endothermic describe two types of chemical reactions or systems found in nature, as follows: Exothermic An exothermic reaction occurs when heat is released to the surroundings. According to the IUPAC, an exothermic reaction is "a reaction for which the overall stand ...
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Physical Review
''Physical Review'' is a peer-reviewed scientific journal. The journal was established in 1893 by Edward Nichols. It publishes original research as well as scientific and literature reviews on all aspects of physics. It is published by the American Physical Society (APS). The journal is in its third series, and is split in several sub-journals each covering a particular field of physics. It has a sister journal, '' Physical Review Letters'', which publishes shorter articles of broader interest. History ''Physical Review'' commenced publication in July 1893, organized by Cornell University professor Edward Nichols and helped by the new president of Cornell, J. Gould Schurman. The journal was managed and edited at Cornell in upstate New York from 1893 to 1913 by Nichols, Ernest Merritt, and Frederick Bedell. The 33 volumes published during this time constitute ''Physical Review Series I''. The American Physical Society (APS), founded in 1899, took over its publicati ...
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Mass-to-charge Ratio
The mass-to-charge ratio (''m''/''Q'') is a physical quantity Ratio, relating the ''mass'' (quantity of matter) and the ''electric charge'' of a given particle, expressed in Physical unit, units of kilograms per coulomb (kg/C). It is most widely used in the electrodynamics of charged particles, e.g. in electron optics and ion optics. It appears in the scientific fields of electron microscopy, cathode ray tubes, accelerator physics, nuclear physics, Auger electron spectroscopy, physical cosmology, cosmology and mass spectrometry. The importance of the mass-to-charge ratio, according to classical electrodynamics, is that two particles with the same mass-to-charge ratio move in the same path in a vacuum, when subjected to the same electric and magnetic fields. Some disciplines use the charge-to-mass ratio (''Q''/''m'') instead, which is the multiplicative inverse of the mass-to-charge ratio. The CODATA recommended value for an electron is Origin When charged particles move in ...
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Plasma (physics)
Plasma () is a state of matter characterized by the presence of a significant portion of charged particles in any combination of ions or electrons. It is the most abundant form of ordinary matter in the universe, mostly in stars (including the Sun), but also dominating the rarefied intracluster medium and Outer space#Intergalactic space, intergalactic medium. Plasma can be artificially generated, for example, by heating a neutral gas or subjecting it to a strong electromagnetic field. The presence of charged particles makes plasma electrically conductive, with the dynamics of individual particles and macroscopic plasma motion governed by collective electromagnetic fields and very sensitive to externally applied fields. The response of plasma to electromagnetic fields is used in many modern devices and technologies, such as plasma display, plasma televisions or plasma etching. Depending on temperature and density, a certain number of neutral particles may also be present, in wh ...
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