Trichloroanisole
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Trichloroanisole
2,4,6-Trichloroanisole (TCA) is a chemical compound that is a chlorine, chlorinated derivative of anisole. TCA is a fungal metabolite of 2,4,6-Trichlorophenol, 2,4,6-trichlorophenol, which is used as a fungicide. It can be found in minute traces on packaging materials stored in the presence of fiberboard treated with trichlorophenol. TCA has an unpleasant earthy, musty and moldy smell and is the chemical primarily responsible for cork taint in wines. TCA has also been implicated as a major component of the "Rio defect" in coffees from Central and South America, which refers to a taste described as medicinal, phenolic, or iodine-like. TCA is usually produced when naturally occurring airborne fungus, fungi and bacteria (usually ''Aspergillus'' sp., ''Penicillium'' sp., ''Actinomycetes'', ''Botrytis cinerea'', ''Rhizobium'' sp., or ''Streptomyces'') are presented with halogenation, chlorinated phenols, phenolic compounds, which they then convert into chlorinated anisole derivative (c ...
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Cork Taint
Cork taint is a broad term referring to a wine fault characterized by a set of undesirable smells or tastes found in a bottle of wine, especially spoilage that can only be detected after bottling, aging and opening. Though modern studies have shown that other factors can also be responsible for taint – including wooden barrels, storage conditions and the transport of corks and wine – the cork stopper is normally considered to be responsible, and a wine found to be tainted on opening is said to be corked or "corky". Cork taint can affect wines irrespective of price and quality level. The chief cause of cork taint is the presence of the chemical compounds 2,4,6-trichloroanisole (TCA) or 2,4,6-tribromoanisole (TBA) in the wine, which in many cases will have been transferred from the cork, but which also can have been transferred through the cork rather than from it. TCA is a compound which does not occur naturally. It is created when some fungi are treated with chlor ...
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