Thiosulfate Reductase
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Thiosulfate Reductase
Thiosulfate ( IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula . Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, e.g. sodium thiosulfate . Thiosulfate also refers to the esters of thiosulfuric acid, e.g. ''O'',''S''-dimethyl thiosulfate . The prefix thio- indicates that the thiosulfate is a sulfate with one oxygen replaced by sulfur. Thiosulfate is tetrahedral at the central S atom. Thiosulfate salts occur naturally. Thiosulfate ion has C3v symmetry, and is produced by certain biochemical processes. It rapidly dechlorinates water and is notable for its use to halt bleaching in the paper-making industry. Thiosulfate salts are mainly used in dying in textiles and the bleaching of natural substances. Sodium thiosulfate, commonly called ''hypo'' (from "hyposulfite"), was widely used in photography to fix black and white negatives and prints after the ...
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Thiosulfuric Acid
Thiosulfuric acid is the inorganic compound with the formula . It has attracted academic interest as a simple, easily accessed compound that is labile. It has few practical uses. Preparation and degradation The acid cannot be made by acidifying aqueous thiosulfate salt solutions as the acid readily decomposes in water. The decomposition products can include sulfur, sulfur dioxide, hydrogen sulfide, polysulfanes, sulfuric acid and polythionates, depending on the reaction conditions.. Anhydrous methods of producing the acid were developed by Max Schmidt: : : : The anhydrous acid also decomposes above −5 °C: : Structure The isomer is more stable than the isomer as established by Hartree–Fock/ ab initio calculations with a 6-311 G** basis set and MP2 to MP4 refinements. The theoretically predicted structure conforms with the double bond rule. An isomer of thiosulfuric acid is the adduct An adduct (from the Latin ''adductus'', "drawn toward" alternative ...
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