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Thioarsenite
Trithioarsenite, also called sulfarsenite, is the trianion . It is a pyramidal anion, as is typical of other compounds. It is generated by treatment of with a sulfide: : Thioarsenites are components of many sulfosalt minerals. An example is relatively common mineral proustite, ,Trevelyan B. 1969: The electro-optic effect in proustite. Optical and Quantum Electronics, 1(1), pp. 1969/ref> which is silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...(I) trithioarsenite. References Sulfosalt minerals {{mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arsenic Trisulfide
Arsenic trisulfide is the inorganic compound with the formula . It is a dark yellow solid that is insoluble in water. It also occurs as the mineral orpiment (Latin: auripigmentum), which has been used as a pigment called King's yellow. It is produced in the analysis of arsenic compounds. It is a group V/VI, intrinsic p-type semiconductor and exhibits photo-induced phase-change properties. Structure occurs both in crystalline and amorphous forms. Both forms feature polymeric structures consisting of trigonal pyramidal As(III) centres linked by sulfide centres. The sulfide centres are two-fold coordinated to two arsenic atoms. In the crystalline form, the compound adopts a ruffled sheet structure. The bonding between the sheets consists of van der Waals forces. The crystalline form is usually found in geological samples. Amorphous does not possess a layered structure but is more highly cross-linked. Like other glasses, there is no medium or long-range order, but the first co-ordin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (SH−) are the conjugate acids of sulfide. Chemical properties The sulfide ion, S2−, does not exist in aqueous alkaline solutions of Na2S. Instead sulfide converts to hydrosulfide: :S2− + H2O → SH− + OH− Upon treatment with an acid, sulfide salts convert to hydrogen sulfide: :S2− + H+ → SH− :SH− + H+ → H2S Oxidation of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur, polysulfides, polythionates, sulfite, or sulfate. Metal sulfides react with halogens, forming sulfur and metal salts. :8 MgS + 8 I2 → S8 + 8 M ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfosalt Minerals
Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury (element), mercury, zinc, vanadium *B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely germanium, or metals like tin and rarely vanadium *X is sulfur or rarely selenium and/or tellurium. The Strunz classification includes the sulfosalts in a ''sulfides and sulfosalts'' superclass. A group which have similar appearing formulas are the Sulfarsenide mineral, sulfarsenides (for example cobaltite (Co,Fe)AsS). In sulfarsenides the arsenic substitutes for sulfide anions whereas in the sulfosalts the arsenic substitutes for a metal cation.Klein, Cornelis and Cornelius S. Hurlbut (1985). ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York . About 200 sulfosalt minerals are known. Examples include: File:Proustite (long prismatic crystal) - Chanarcillo, Copiapo Province, Atacama Region, Chile.jpg, As ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Proustite
Proustite is a sulfosalt mineral consisting of silver sulfarsenide, Ag3 As S3, known also as light red silver or ruby silver ore, and an important source of the metal. It is closely allied to the corresponding sulfantimonide, pyrargyrite, from which it was distinguished by the chemical analyses of Joseph L. Proust (1754–1826) in 1804, after whom the mineral received its name. The prismatic crystals are often terminated by the scalenohedron and the obtuse rhombohedron, thus resembling calcite (dog-tooth-spar) in habit. The color is scarlet-vermilion and the luster adamantine; crystals are transparent and very brilliant, but on exposure to light they soon become dull black and opaque. The streak is scarlet, the hardness 2 to 2.5, and the specific gravity 5.57. Its transparency differs from specimen to specimen, but most are opaque or translucent. Proustite occurs in hydrothermal deposits as a phase in the oxidized and supergene zone. It is associated with other silver minerals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silver
Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in the Earth's crust in the pure, free elemental form ("native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a byproduct of copper, gold, lead, and zinc Refining (metallurgy), refining. Silver has long been valued as a precious metal. Silver metal is used in many bullion coins, sometimes bimetallism, alongside gold: while it is more abundant than gold, it is much less abundant as a native metal. Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
