Sulfosalt
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Sulfosalt
Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury, zinc, vanadium *B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely germanium, or metals like tin and rarely vanadium *X is sulfur or rarely selenium and/or tellurium. The Strunz classification includes the sulfosalts in a ''sulfides and sulfosalts'' superclass. A group which have similar appearing formulas are the sulfarsenides (for example cobaltite (Co,Fe)AsS). In sulfarsenides the arsenic substitutes for sulfide anions whereas in the sulfosalts the arsenic substitutes for a metal cation.Klein, Cornelis and Cornelius S. Hurlbut (1985). ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York . About 200 sulfosalt minerals are known. Examples include: File:Proustite (long prismatic crystal) - Chanarcillo, Copiapo Province, Atacama Region, Chile.jpg, As illustrated by this specimen of proustite ...
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Tennantite
Tennantite is a copper arsenic sulfosalt mineral with an ideal formula . Due to variable substitution of the copper by iron and zinc the formula is . It is gray-black, steel-gray, iron-gray or black in color. A closely related mineral, tetrahedrite ) has antimony substituting for arsenic and the two form a solid solution series. The two have very similar properties and is often difficult to distinguish between tennantite and tetrahedrite. Iron, zinc, and silver substitute up to about 15% for the copper site. The mineral was first described for an occurrence in Cornwall, England in 1819, where it occurs as small crystals of cubic or dodecahedral form, and was named after the English chemist Smithson Tennant (1761–1815). It is found in hydrothermal veins and contact metamorphic deposits in association with other Cu–Pb–Zn–Ag sulfides and sulfosalts, pyrite, calcite, dolomite, siderite, barite, fluorite and quartz. The arsenic component of tennantite causes the metal smelte ...
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Copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form ( native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create ...
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Tetrahedrite
Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, the antimony rich phase is more common. Other elements also substitute in the structure, most notably iron and zinc, along with less common silver, mercury and lead. Bismuth also substitutes for the antimony site and ''bismuthian tetrahedrite'' or ''annivite'' is a recognized variety. The related, silver dominant, mineral species freibergite, although rare, is notable in that it can contain up to 18% silver. Mineralogy Tetrahedrite gets its name from the distinctive tetrahedron shaped cubic crystals. The mineral usually occurs in massive form, it is a steel gray to black metallic mineral with Mohs hardness of 3.5 to 4 and specific gravity of 4.6 to 5.2. Tetrahedrite occurs in low to moderate temperature hydrothermal veins and in some co ...
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Sulfarsenide Mineral
The sulfarsenide minerals are a subgroup of the sulfide minerals which include arsenic replacing sulfur as an anion in the formula.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, p. 290 Antimony and bismuth may occur with or in place of the arsenic as in ullmannite. The chemical formula of a sulfarsenide looks like a sulfosalt, however the structures are distinctly different. In sulfosalts the arsenic replaces a metal ion. The sulfarsenides are grouped with the sulfides in both the Dana and Strunz mineral classification systems. Examples include:Palache, C., H. Berman, and C. Frondel (1944) ''Dana’s system of mineralogy,'' (7th edition), v. I, p. 296 *Arsenopyrite group: **Arsenopyrite **Glaucodot ** Gudmundite **Lautite **Alloclasite *Cobaltite group **Cobaltite **Gersdorffite **Ullmannite Ullmannite is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with coba ...
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Proustite
Proustite is a sulfosalt mineral consisting of silver sulfarsenide, Ag3 As S3, known also as light red silver or ruby silver ore, and an important source of the metal. It is closely allied to the corresponding sulfantimonide, pyrargyrite, from which it was distinguished by the chemical analyses of Joseph L. Proust (1754–1826) in 1804, after whom the mineral received its name. The prismatic crystals are often terminated by the scalenohedron and the obtuse rhombohedron, thus resembling calcite (dog-tooth-spar) in habit. The color is scarlet-vermilion and the luster adamantine; crystals are transparent and very brilliant, but on exposure to light they soon become dull black and opaque. The streak is scarlet, the hardness 2 to 2.5, and the specific gravity 5.57. Its transparency differs from specimen to specimen, but most are opaque or translucent. Proustite occurs in hydrothermal deposits as a phase in the oxidized and supergene zone. It is associated with other silver minerals ...
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Sulfide Minerals
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite *Galena *Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Proustite *Tetrahedrite *Tennantite *Enargite *Bournonite *Jame ...
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Samsonite (mineral)
Samsonite is a silver manganese antimony sulfosalt mineral with formula Ag4 Mn Sb2 S6. It crystallizes in the monoclinic crystal system with a typical slender radiating prismatic habit. It is metallic black to steel black with no cleavage and a brittle to conchoidal fracture. In thin fragments it appears reddish brown in transmitted light and also leaves a red streak. It is soft, Mohs hardness of 2.5, and has a specific gravity of 5.51. It was first named in 1910 after an occurrence in the Samson Vein of the Sankt Andreasberg silver mines, Harz Mountains, Germany. See also * Classification of minerals * List of minerals References *Palache ''(Previously, this page expanded into a family history–now in separate entry: q.v. "Pallache family.")'' The Pallache (see Pallache family for many spellings of name) are a Sephardic Jewish family who originated on the Iberian Peninsula, sprea ..., C., H. Berman, and C. Frondel (1944) Dana's system of mineralogy, (7th edition), v. I ...
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Enargite
Enargite is a copper arsenic sulfosalt mineral with formula Cu3AsS4. It takes its name from the Greek word , "distinct". Enargite is a steel gray, blackish gray, to violet black mineral with metallic luster. It forms slender orthorhombic prisms as well as massive aggregates. It has a hardness of 3 and a specific gravity of 4.45. Enargite is dimorph of the tetragonal luzonite. Occurrence It is a medium to low temperature hydrothermal mineral occurring with quartz, pyrite, sphalerite, galena, bornite, tetrahedrite–tennantite, chalcocite, covellite and baryte. It occurs in the mineral deposits at Butte, Montana, San Juan Mountains, Colorado and at both Bingham Canyon and Tintic, Utah. It is also found in the copper mines of Canada, Mexico, Argentina, Chile, Peru, and the Philippines. Enargite was originally described as a new species from the copper mines of the San Francisco vein, Junin Department, Peru , image_flag = Flag of Peru.svg , image_coat ...
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Pyrargyrite
Pyrargyrite is a sulfosalt mineral consisting of silver sulfantimonite, Ag3SbS3. Known also as dark red silver ore or ruby silver, it is an important source of the metal. It is closely allied to, and isomorphous with, the corresponding sulfarsenide known as proustite or light red silver ore. Ruby silver or red silver ore (German ''Rotgültigerz'') was mentioned by Georg Agricola in 1546, but the two species so closely resemble one another that they were not completely distinguished until chemical analyses of both were made. Both crystallize in the ditrigonal pyramidal (hemimorphic-hemihedral) class of the rhombohedral system, possessing the same degree of symmetry as tourmaline. Crystals are perfectly developed and are usually prismatic in habit; they are frequently attached at one end, the hemimorphic character being then evident by the fact that the oblique striations on the prism faces are directed towards one end only of the crystal. Twinning according to several laws is no ...
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Proustite
Proustite is a sulfosalt mineral consisting of silver sulfarsenide, Ag3 As S3, known also as light red silver or ruby silver ore, and an important source of the metal. It is closely allied to the corresponding sulfantimonide, pyrargyrite, from which it was distinguished by the chemical analyses of Joseph L. Proust (1754–1826) in 1804, after whom the mineral received its name. The prismatic crystals are often terminated by the scalenohedron and the obtuse rhombohedron, thus resembling calcite (dog-tooth-spar) in habit. The color is scarlet-vermilion and the luster adamantine; crystals are transparent and very brilliant, but on exposure to light they soon become dull black and opaque. The streak is scarlet, the hardness 2 to 2.5, and the specific gravity 5.57. Its transparency differs from specimen to specimen, but most are opaque or translucent. Proustite occurs in hydrothermal deposits as a phase in the oxidized and supergene zone. It is associated with other silver minerals ...
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Geocronite
Geocronite is a mineral, a mixed sulfosalt containing lead, antimony, and arsenic with a formula of Pb14(Sb, As)6S23. Geocronite is the antimony-rich endmember of a solid solution series. The arsenic-rich endmember is named jordanite. It occurs as grey, black, to silvery white monoclinic crystals. It is found in hydrothermal veins usually associated with other similar minerals, particularly the sulfides of iron and copper. The mineral has been found in Spain, Ireland and Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ... where it was first identified in 1839. References External links Webmineral
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Arsenic
Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but only the gray form, which has a metallic appearance, is important to industry. The primary use of arsenic is in alloys of lead (for example, in car batteries and ammunition). Arsenic is a common n-type dopant in semiconductor electronic devices. It is also a component of the III-V compound semiconductor gallium arsenide. Arsenic and its compounds, especially the trioxide, are used in the production of pesticides, treated wood products, herbicides, and insecticides. These applications are declining with the increasing recognition of the toxicity of arsenic and its compounds. A few species of bacteria are able to use arsenic compounds as respiratory metabolites. Trace quantities of arsenic are an essential dietary element in rats, ham ...
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