Strontianite
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Strontianite
Strontianite ( Sr C O3) is an important raw material for the extraction of strontium. It is a rare carbonate mineral and one of only a few strontium minerals. It is a member of the aragonite group. Aragonite group members: aragonite (CaCO3), witherite (BaCO3), strontianite (SrCO3), cerussite (PbCO3) The ideal formula of strontianite is SrCO3, with molar mass 147.63 g, but calcium (Ca) can substitute for up to 27% of the strontium (Sr) cations, and barium (Ba) up to 3.3%. The mineral was named in 1791 for the locality, Strontian, Argyllshire, Scotland, where the element strontium had been discovered the previous year. Although good mineral specimens of strontianite are rare, strontium is a fairly common element, with abundance in the Earth's crust of 370 parts per million by weight, 87 parts per million by moles, much more common than copper with only 60 parts per million by weight, 19 by moles. Strontium is never found free in nature. The principal strontium ores are c ...
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Carbonate Minerals
Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Siderite FeCO3 **Smithsonite ZnCO3 **Spherocobaltite CoCO3 *Aragonite group: orthorhombic **Aragonite CaCO3 **Cerussite PbCO3 **Strontianite SrCO3 **Witherite BaCO3 **Rutherfordine UO2CO3 **Natrite Na2CO3 Anhydrous carbonates with compound formulas *Dolomite group: trigonal **Ankerite CaFe(CO3)2 **Dolomite (mineral), Dolomite CaMg(CO3)2 **Huntite Mg3Ca(CO3)4 **Minrecordite CaZn(CO3)2 **Barytocalcite BaCa(CO3)2 Carbonates with hydroxyl or halogen *Carbonate with hydroxide: monoclinic **Azurite Cu3(CO3)2(OH)2 **Hydrocerussite Pb3(CO3)2(OH)2 **Malachite Cu2CO3(OH)2 **Rosasite (Cu,Zn)2CO3(OH)2 **Phosgenite Pb2(CO3)Cl2 **Hydrozincite Zn5(CO3)2(OH)6 **Aurichalcite (Zn,Cu)5(CO3)2(OH)6 Hydrated carbonates *Hydromagnesite Mg5(CO3)4(OH)2.4H2O *Ikaite ...
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Carbonate Mineral
Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Siderite FeCO3 **Smithsonite ZnCO3 **Spherocobaltite CoCO3 *Aragonite group: orthorhombic **Aragonite CaCO3 **Cerussite PbCO3 **Strontianite SrCO3 **Witherite BaCO3 **Rutherfordine UO2CO3 **Natrite Na2CO3 Anhydrous carbonates with compound formulas *Dolomite group: trigonal **Ankerite CaFe(CO3)2 **Dolomite (mineral), Dolomite CaMg(CO3)2 **Huntite Mg3Ca(CO3)4 **Minrecordite CaZn(CO3)2 **Barytocalcite BaCa(CO3)2 Carbonates with hydroxyl or halogen *Carbonate with hydroxide: monoclinic **Azurite Cu3(CO3)2(OH)2 **Hydrocerussite Pb3(CO3)2(OH)2 **Malachite Cu2CO3(OH)2 **Rosasite (Cu,Zn)2CO3(OH)2 **Phosgenite Pb2(CO3)Cl2 **Hydrozincite Zn5(CO3)2(OH)6 **Aurichalcite (Zn,Cu)5(CO3)2(OH)6 Hydrated carbonates *Hydromagnesite Mg5(CO3)4(OH)2.4H2O *Ikaite ...
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Slovakia
Slovakia (; sk, Slovensko ), officially the Slovak Republic ( sk, Slovenská republika, links=no ), is a landlocked country in Central Europe. It is bordered by Poland to the north, Ukraine to the east, Hungary to the south, Austria to the southwest, and the Czech Republic to the northwest. Slovakia's mostly mountainous territory spans about , with a population of over 5.4 million. The capital and largest city is Bratislava, while the second largest city is Košice. The Slavs arrived in the territory of present-day Slovakia in the fifth and sixth centuries. In the seventh century, they played a significant role in the creation of Samo's Empire. In the ninth century, they established the Principality of Nitra, which was later conquered by the Principality of Moravia to establish Great Moravia. In the 10th century, after the dissolution of Great Moravia, the territory was integrated into the Principality of Hungary, which then became the Kingdom of Hungary in 1000. In 1241 a ...
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Crystal Structure
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of Three-dimensional space (mathematics), three-dimensional space in matter. The smallest group of particles in the material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive Translation (geometry), translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of the crystal are described by the con ...
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Unit Cell
In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector, for example) does not necessarily have unit size, or even a particular size at all. Rather, the primitive cell is the closest analogy to a unit vector, since it has a determined size for a given lattice and is the basic building block from which larger cells are constructed. The concept is used particularly in describing crystal structure in two and three dimensions, though it makes sense in all dimensions. A lattice can be characterized by the geometry of its unit cell, which is a section of the tiling (a parallelogram or parallelepiped) that generates the whole tiling using only translations. There are two special cases of the unit cell: the primitive cell and the conventional cell. The primitive cell is a unit cell corresponding to a single lattice point, it is the ...
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Space Group
In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it unchanged. In three dimensions, space groups are classified into 219 distinct types, or 230 types if chiral copies are considered distinct. Space groups are discrete cocompact groups of isometries of an oriented Euclidean space in any number of dimensions. In dimensions other than 3, they are sometimes called Bieberbach groups. In crystallography, space groups are also called the crystallographic or Fedorov groups, and represent a description of the symmetry of the crystal. A definitive source regarding 3-dimensional space groups is the ''International Tables for Crystallography'' . History Space groups in 2 dimensions are the 17 wallpaper groups which have been known for several centuries, though the proof that the list was complete was only ...
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Bipyramid
A (symmetric) -gonal bipyramid or dipyramid is a polyhedron formed by joining an -gonal pyramid and its mirror image base-to-base. An -gonal bipyramid has triangle faces, edges, and vertices. The "-gonal" in the name of a bipyramid does not refer to a face but to the internal polygon base, lying in the mirror plane that connects the two pyramid halves. (If it were a face, then each of its edges would connect three faces instead of two.) "Regular", right bipyramids A ''"regular"'' bipyramid has a ''regular'' polygon base. It is usually implied to be also a ''right'' bipyramid. A ''right'' bipyramid has its two apices ''right'' above and ''right'' below the center or the ''centroid'' of its polygon base. A "regular" right (symmetric) -gonal bipyramid has Schläfli symbol . A right (symmetric) bipyramid has Schläfli symbol , for polygon base . The "regular" right (thus face-transitive) -gonal bipyramid with regular vertices is the dual of the -gonal uniform (thus right) ...
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Rhombus
In plane Euclidean geometry, a rhombus (plural rhombi or rhombuses) is a quadrilateral whose four sides all have the same length. Another name is equilateral quadrilateral, since equilateral means that all of its sides are equal in length. The rhombus is often called a "diamond", after the diamonds suit in playing cards which resembles the projection of an octahedral diamond, or a lozenge, though the former sometimes refers specifically to a rhombus with a 60° angle (which some authors call a calisson after the French sweet – also see Polyiamond), and the latter sometimes refers specifically to a rhombus with a 45° angle. Every rhombus is simple (non-self-intersecting), and is a special case of a parallelogram and a kite. A rhombus with right angles is a square. Etymology The word "rhombus" comes from grc, ῥόμβος, rhombos, meaning something that spins, which derives from the verb , romanized: , meaning "to turn round and round." The word was used both by Eucl ...
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Orthorhombic Crystal System
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primiti ...
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Aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity tow ...
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Strontium Oxide
Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3. It is a strongly basic oxide. Uses About 8% by weight of cathode ray tubes is strontium oxide, which has been the major use of strontium since 1970. Color televisions and other devices containing color cathode ray tubes sold in the United States are required by law to use strontium in the faceplate to block X-ray emission (these X-ray emitting TVs are no longer in production). Lead(II) oxide can be used in the neck and funnel, but causes discoloration when used in the faceplate. Reactions Elemental strontium is formed when strontium oxide is heated with aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other co ...
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Redox
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogen ...
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