Space Time (chemical Engineering)
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Space Time (chemical Engineering)
The residence time of a fluid parcel is the total time that the parcel has spent inside a control volume (e.g.: a chemical reactor, a lake, a human body). The residence time of a set of parcels is quantified in terms of the frequency distribution of the residence time in the set, which is known as residence time distribution (RTD), or in terms of its average, known as mean residence time. Residence time plays an important role in chemistry and especially in environmental science and pharmacology. Under the name ''lead time'' or ''waiting time'' it plays a central role respectively in supply chain management and queueing theory, where the material that flows is usually discrete instead of continuous. History The concept of residence time originated in models of chemical reactors. The first such model was an ''axial dispersion model'' by Irving Langmuir in 1908. This received little attention for 45 years; other models were developed such as the plug flow reactor model and ...
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Fluid Parcel
In fluid dynamics, within the framework of continuum mechanics, a fluid parcel is a very small amount of fluid, identifiable throughout its dynamic history while moving with the fluid flow. As it moves, the mass of a fluid parcel remains constant, while—in a compressible flow—its volume may change. And its shape changes due to the distortion by the flow. In an incompressible flow the volume of the fluid parcel is also a constant ( isochoric flow). This mathematical concept is closely related to the description of fluid motion—its kinematics and dynamics—in a Lagrangian frame of reference. In this reference frame, fluid parcels are labelled and followed through space and time. But also in the Eulerian frame of reference the notion of fluid parcels can be advantageous, for instance in defining the material derivative, streamlines, streaklines, and pathlines; or for determining the Stokes drift. The fluid parcels, as used in continuum mechanics, are to be distinguished fro ...
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Control Volume
In continuum mechanics and thermodynamics, a control volume (CV) is a mathematical abstraction employed in the process of creating mathematical models of physical processes. In an inertial frame of reference, it is a fictitious region of a given volume fixed in space or moving with constant flow velocity through which the continuum (gas, liquid or solid) flows. The closed surface enclosing the region is referred to as the control surface. At steady state, a control volume can be thought of as an arbitrary volume in which the mass of the continuum remains constant. As a continuum moves through the control volume, the mass entering the control volume is equal to the mass leaving the control volume. At steady state, and in the absence of work and heat transfer, the energy within the control volume remains constant. It is analogous to the classical mechanics concept of the free body diagram. Overview Typically, to understand how a given physical law applies to the system under conside ...
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Water Vapor
(99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous phase of water. It is one state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from the sublimation of ice. Water vapor is transparent, like most constituents of the atmosphere. Under typical atmospheric conditions, water vapor is continuously generated by evaporation and removed by condensation. It is less dense than most of the other constituents of air and triggers convection currents that can lead to clouds. Being a component of Earth's hydrosphere and hydrologic cycle, it is particularly abundant in Earth's atmosphere, where it acts as a greenhouse gas and warming feedback, contributing more to total greenhouse effect than non-condensable gases such as carbon dioxide an ...
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Reactant
In chemistry, a reagent ( ) or analytical reagent is a substance or compound added to a system to cause a chemical reaction, or test if one occurs. The terms ''reactant'' and ''reagent'' are often used interchangeably, but reactant specifies a substance ''consumed'' in the course of a chemical reaction. ''Solvents'', though involved in the reaction mechanism, are usually not called reactants. Similarly, ''catalysts'' are not consumed by the reaction, so they are not reactants. In biochemistry, especially in connection with enzyme-catalyzed reactions, the reactants are commonly called substrates. Definitions Organic chemistry In organic chemistry, the term "reagent" denotes a chemical ingredient (a compound or mixture, typically of inorganic or small organic molecules) introduced to cause the desired transformation of an organic substance. Examples include the Collins reagent, Fenton's reagent, and Grignard reagents. Analytical chemistry In analytical chemistry, a reagent ...
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Rate Equation
In chemistry, the rate law or rate equation for a reaction is an equation that links the initial or forward reaction rate with the concentrations or pressures of the reactants and constant parameters (normally rate coefficients and partial reaction orders). For many reactions, the initial rate is given by a power law such as :v_0\; =\; k mathrmx mathrmy where and express the concentration of the species and usually in moles per liter (molarity, ). The exponents and are the partial ''orders of reaction'' for and and the ''overall'' reaction order is the sum of the exponents. These are often positive integers, but they may also be zero, fractional, or negative. The constant is the reaction rate constant or ''rate coefficient'' of the reaction. Its value may depend on conditions such as temperature, ionic strength, surface area of an adsorbent, or light irradiation. If the reaction goes to completion, the rate equation for the reaction rate v\; =\; k cex cey applies throug ...
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Radioactive Decay
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is considered radioactive. Three of the most common types of decay are alpha decay ( ), beta decay ( ), and gamma decay ( ), all of which involve emitting one or more particles. The weak force is the mechanism that is responsible for beta decay, while the other two are governed by the electromagnetism and nuclear force. A fourth type of common decay is electron capture, in which an unstable nucleus captures an inner electron from one of the electron shells. The loss of that electron from the shell results in a cascade of electrons dropping down to that lower shell resulting in emission of discrete X-rays from the transitions. A common example is iodine-125 commonly used in medical settings. Radioactive decay is a stochastic (i.e. random) proce ...
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Exponential Distribution
In probability theory and statistics, the exponential distribution is the probability distribution of the time between events in a Poisson point process, i.e., a process in which events occur continuously and independently at a constant average rate. It is a particular case of the gamma distribution. It is the continuous analogue of the geometric distribution, and it has the key property of being memoryless. In addition to being used for the analysis of Poisson point processes it is found in various other contexts. The exponential distribution is not the same as the class of exponential families of distributions. This is a large class of probability distributions that includes the exponential distribution as one of its members, but also includes many other distributions, like the normal, binomial, gamma, and Poisson distributions. Definitions Probability density function The probability density function (pdf) of an exponential distribution is : f(x;\lambda) = \begin \lambda ...
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Troposphere
The troposphere is the first and lowest layer of the atmosphere of the Earth, and contains 75% of the total mass of the planetary atmosphere, 99% of the total mass of water vapour and aerosols, and is where most weather phenomena occur. From the planetary surface of the Earth, the average height of the troposphere is in the tropics; in the middle latitudes; and in the high latitudes of the polar regions in winter; thus the average height of the troposphere is . The term ''troposphere'' derives from the Greek words ''tropos'' (rotating) and '' sphaira'' (sphere) indicating that rotational turbulence mixes the layers of air and so determines the structure and the phenomena of the troposphere. The rotational friction of the troposphere against the planetary surface affects the flow of the air, and so forms the planetary boundary layer (PBL) that varies in height from hundreds of meters up to . The measures of the PBL vary according to the latitude, the landform, and th ...
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Nuclear Weapons Testing
Nuclear weapons tests are experiments carried out to determine nuclear weapons' effectiveness, Nuclear weapon yield, yield, and explosive capability. Testing nuclear weapons offers practical information about how the weapons function, how detonations are affected by different conditions, and how personnel, structures, and equipment are affected when subjected to Nuclear explosion, nuclear explosions. However, nuclear testing has often been used as an indicator of scientific and military strength. Many tests have been overtly political in their intention; most List of countries with nuclear weapons, nuclear weapons states publicly declared their nuclear status through a nuclear test. The first nuclear device was detonated as a test by the United States at the Trinity site in New Mexico on July 16, 1945, with a yield approximately TNT equivalent, equivalent to 20 kilotons of TNT. The first thermonuclear weapon technology test of an engineered device, codenamed "Ivy Mike", was teste ...
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Stratosphere
The stratosphere () is the second layer of the atmosphere of the Earth, located above the troposphere and below the mesosphere. The stratosphere is an atmospheric layer composed of stratified temperature layers, with the warm layers of air high in the sky and the cool layers of air in the low sky, close to the planetary surface of the Earth. The increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet (UV) radiation by the ozone layer. The temperature inversion is in contrast to the troposphere, near the Earth's surface, where temperature decreases with altitude. Between the troposphere and stratosphere is the tropopause border that demarcates the beginning of the temperature inversion. Near the equator, the lower edge of the stratosphere is as high as , at midlatitudes around , and at the poles about . Temperatures range from an average of near the tropopause to an average of near the mesosphere. Stratospheric temperatures also vary w ...
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Nuclear Fallout
Nuclear fallout is the residual radioactive material propelled into the upper atmosphere following a nuclear blast, so called because it "falls out" of the sky after the explosion and the shock wave has passed. It commonly refers to the radioactive dust and ash created when a nuclear weapon explodes. The amount and spread of fallout is a product of the size of the weapon and the altitude at which it is detonated. Fallout may get entrained with the products of a pyrocumulus cloud and fall as black rain (rain darkened by soot and other particulates, which fell within 30–40 minutes of the atomic bombings of Hiroshima and Nagasaki). This radioactive dust, usually consisting of fission products mixed with bystanding atoms that are neutron-activated by exposure, is a form of radioactive contamination. Types of fallout Fallout comes in two varieties. The first is a small amount of carcinogenic material with a long half-life. The second, depending on the height of detonation, is ...
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Drinking Trough Cut In Log
Drinking is the act of ingesting water or other liquids into the body through the mouth, proboscis, or elsewhere. Humans drink by swallowing, completed by peristalsis in the esophagus. The physiological processes of drinking vary widely among other animals. Most animals drink water to maintain bodily hydration, although many can survive on the water gained from their food. Water is required for many physiological processes. Both inadequate and (less commonly) excessive water intake are associated with health problems. Methods of drinking In humans When a liquid enters a human mouth, the swallowing process is completed by peristalsis which delivers the liquid through the esophagus to the stomach; much of the activity is abetted by gravity. The liquid may be poured from the hands or drinkware may be used as vessels. Drinking can also be performed by acts of inhalation, typically when imbibing hot liquids or drinking from a spoon. Infants employ a method of suction wherein ...
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