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Semiochemical
A semiochemical, from the Greek σημεῖον (''semeion''), meaning "signal", is a chemical substance or mixture released by an organism that affects the behaviors of other individuals. Semiochemical communication can be divided into two broad classes: communication between individuals of the same species (intraspecific) or communication between different species (interspecific). It is usually used in the field of chemical ecology to encompass pheromones, allomones, kairomones, attractants and repellents. Many insects, including parasitic insects, use semiochemicals. Pheromones are intraspecific signals that aid in finding mates, food and habitat resources, warning of enemies, and avoiding competition. Interspecific signals known as allomones and kairomones have similar functions. In nature Pheromone A pheromone (from Greek ''phero'' "to bear" + ''hormone'' from Greek – "impetus") is a secreted or excreted chemical factor that triggers a social response in members of ...
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Allomone
An allomone (from Ancient Greek ' "other" and pheromone) is a type of semiochemical produced and released by an individual of one species that affects the behaviour of a member of another species to the benefit of the originator but not the receiver. Production of allomones is a common form of defense against predators, particularly by plant species against insect herbivores. In addition to defense, allomones are also used by organisms to obtain their prey or to hinder any surrounding competitors. Many insects have developed ways to defend against these plant defenses (in an evolutionary arms race). One method of adapting to allomones is to develop a positive reaction to them; the allomone then becomes a kairomone. Others alter the allomones to form pheromones or other hormones, and yet others adopt them into their own defensive strategies, for example by regurgitating them when attacked by an insectivorous insect. A third class of allelochemical (chemical used in interspecif ...
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Pheromone
A pheromone () is a secreted or excreted chemical factor that triggers a social response in members of the same species. Pheromones are chemicals capable of acting like hormones outside the body of the secreting individual, to affect the behavior of the receiving individuals. There are ''alarm signal, alarm pheromones'', ''food trail pheromones'', ''sex pheromones'', and many others that affect behavior or physiology. Pheromones are used by many organisms, from basic unicellular prokaryotes to complex multicellular eukaryotes. Their use among insects has been particularly well documented. In addition, some vertebrates, plants and ciliates communicate by using pheromones. The ecological functions and evolution of pheromones are a major topic of research in the field of chemical ecology. Background The portmanteau word "pheromone" was coined by Peter Karlson and Martin Lüscher in 1959, based on the Greek φερω ''pheroo'' ('I carry') and ὁρμων ''hormon'' ('stimulating'). P ...
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Kairomone
A kairomone (a coinage using the Greek καιρός ''opportune moment'', paralleling pheromone"kairomone, n.". OED Online. September 2012. Oxford University Press. http://www.oed.com/view/Entry/241005?redirectedFrom=kairomone (accessed 3 October 2012).) is a semiochemical, emitted by an organism, which mediates interspecific interactions in a way that benefits an individual of another species which receives it and harms the emitter. This "eavesdropping" is often disadvantageous to the producer (though other benefits of producing the substance may outweigh this cost, hence its persistence over evolutionary time). The kairomone improves the fitness of the recipient and in this respect differs from an allomone (which is the opposite: it benefits the producer and harms the receiver) and a synomone (which benefits both parties). The term is mostly used in the field of entomology (the study of insects). Two main ecological cues are provided by kairomones; they generally either indicat ...
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Attractant
An attractant is any chemical that attracts an organism, e.g. i) synthetic lures; ii) aggregation and sex pheromones (intraspecific interactions); and iii) synomone (interspecific interactions) Synomone An interspecific semiochemical that is beneficial to both interacting organisms, the emitter and receiver, e.g. floral synomone of certain ''Bulbophyllum'' species (Orchidaceae) attracts fruit fly males (Tephritidae: Diptera) as pollinators. In this true mutualistic inter-relationship, both organisms gain benefits in their respective sexual reproduction - i.e. orchid flowers are pollinated and the '' Dacini'' fruit fly males are rewarded with a sex pheromone precursor or booster; and the floral synomones, also act as rewards to pollinators, are in the form of phenylpropanoids (e.g. methyl eugenol) and phenylbutanoids (e.g. raspberry ketone zingerone Zingerone, also called vanillylacetone, is a major flavor component of ginger, providing the sweet flavor of cooked ginger. Zinge ...
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Bombykol
Bombykol is a pheromone released by the female silkworm moth to attract mates. It is also the sex pheromone in the wild silk moth (''Bombyx mandarina''). Discovered by Adolf Butenandt in 1959, it was the first pheromone to be characterized chemically. Minute quantities of this pheromone can be used per acre of land to confuse male insects about the location of their female partners. It can thus serve as a lure in traps to remove insects effectively without spraying crops with large amounts of pesticides. Butenandt named the substance after the moth's Latin name ''Bombyx mori.'' ''In vivo'' it appears that bombykol is the natural ligand for a pheromone binding protein, BmorPBP, which escorts the pheromone to the pheromone receptor. Biosynthesis Bombykol is known to be derived from acetyl-CoA Acetyl-CoA (acetyl coenzyme A) is a molecule that participates in many biochemical reactions in protein, carbohydrate and lipid metabolism. Its main function is to deliver the acetyl gro ...
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Orchidaceae
Orchids are plants that belong to the family Orchidaceae (), a diverse and widespread group of flowering plants with blooms that are often colourful and fragrant. Along with the Asteraceae, they are one of the two largest families of flowering plants. The Orchidaceae have about 28,000 currently accepted species, distributed in about 763 genera. (See ''External links'' below). The determination of which family is larger is still under debate, because verified data on the members of such enormous families are continually in flux. Regardless, the number of orchid species is nearly equal to the number of bony fishes, more than twice the number of bird species, and about four times the number of mammal species. The family encompasses about 6–11% of all species of seed plants. The largest genera are ''Bulbophyllum'' (2,000 species), ''Epidendrum'' (1,500 species), ''Dendrobium'' (1,400 species) and ''Pleurothallis'' (1,000 species). It also includes ''Vanilla'' (the genus of the ...
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Zingerone
Zingerone, also called vanillylacetone, is a major flavor component of ginger, providing the sweet flavor of cooked ginger. Zingerone is a crystalline solid that is sparingly soluble in water and soluble in ether. Zingerone is similar in chemical structure to other flavor chemicals such as vanillin and eugenol. It is used as a flavor additive in spice oils and in perfumery to introduce spicy aromas. Fresh ginger does not contain zingerone, but it is produced by cooking or drying of the ginger root, which causes a reverse aldol reaction on gingerol. Production History Zingerone was first isolated from the ginger root in 1917 by Hiroshi Nomura, a chemistry professor at Tokyo Imperial University. Nomura named the compound and identified the empirical formula of zingerone in his studies at the laboratory of the Agricultural College. He initially identified it as the chemical component contributing pungency to ginger, something further work has disproven. Current methods No ...
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Raspberry Ketone
Raspberry ketone is a natural phenolic compound that is the primary aroma compound of red raspberry, red raspberries. Occurrence Raspberry ketone occurs in a variety of fruits, including raspberries, cranberry, cranberries, and blackberry, blackberries. It is biosynthesis, biosynthesized from coumaroyl-CoA. It can be extracted from the fruit, yielding about 1–4 mg per kg of raspberries. Preparation Since the natural abundance of raspberry ketone is very low, it is prepared industrially by a variety of methods from chemical intermediates. One of the ways this can be done is through a crossed aldol condensation followed by catalytic hydrogenation. First, acetone is condensed with 4-hydroxybenzaldehyde to form an Alpha-beta Unsaturated carbonyl compounds, α,β-unsaturated ketone. Then the alkene part is reduced to the alkane. This two-step method produces raspberry ketone in 99% yield. There is a less expensive hydrogenation catalyst, Nickel boride catalyst, nickel boride, wh ...
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Methyl Eugenol
Methyl eugenol (allylveratrol) is a natural chemical compound classified as a phenylpropene, a type of phenylpropanoid. It is the methyl ether of eugenol and is important to insect behavior and pollination. It is found in various essential oils. Methyl eugenol is found in a number of plants (over 450 species from 80 families including both angiosperm and gymnosperm families) and has a role in attracting pollinators. About 350 plant species have them as a component of floral fragrance. Their ability to attract insects, particularly '' Bactrocera'' fruit flies (particularly, ''Bactrocera dorsalis'' male flies) was first noticed in 1915 by F. M. Howlett. The compound may have evolved in response to pathogens, as methyl eugenol has some antifungal activity. It also repels many insects. As of October 2018, the US FDA withdrew authorization for the use of methyl eugenol as a synthetic flavoring substance for use in food because petitioners (including the Natural Resources Defense Coun ...
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Phenylpropanoid
The phenylpropanoids are a diverse family of organic compounds that are synthesized by plants from the amino acids phenylalanine and tyrosine. Their name is derived from the six-carbon, aromatic phenyl group and the three-carbon propene tail of coumaric acid, which is the central intermediate in phenylpropanoid biosynthesis. From 4-coumaroyl-CoA emanates the biosynthesis of myriad natural products including lignols (precursors to lignin and lignocellulose), flavonoids, isoflavonoids, coumarins, aurones, stilbenes, catechin, and phenylpropanoids. The coumaroyl component is produced from cinnamic acid. Phenylpropanoids are found throughout the plant kingdom, where they serve as essential components of a number of structural polymers, provide protection from ultraviolet light, defend against herbivores and pathogens, and also mediate plant-pollinator interactions as floral pigments and scent compounds. Hydroxycinnamic acids Phenylalanine is first converted to cinnamic aci ...
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Dacini
The Dacinae are a subfamily of the fruit fly family Tephritidae. Its 41 genera are distributed among three tribes: * Tribe Ceratitidini: ** '' Capparimyia'' ** '' Carpophthoromyia'' ** '' Ceratitella'' ** '' Ceratitis'' ** '' Eumictoxenus'' ** ''Neoceratitis'' ** ''Nippia'' ** '' Paraceratitella'' ** '' Paratrirhithrum'' ** ''Perilampsis'' ** ''Trirhithrum'' ** '' Xanthorrachista'' * Tribe Dacini: ** '' Bactrocera'' ** '' Dacus'' ** '' Monacrostichus'' ** ''Zeugodacus''Virgilio M, Jordaens K, Verwimp C, White IM, De Meyer M (2015) Higher phylogeny of frugivorous flies (Diptera, Tephritidae, Dacini): localised partition conflicts and a novel generic classification. '' Mol Phylogenet Evol'' 85: 171–179. doi: 10.1016/j.ympev.2015.01.007 * Tribe Gastrozonini: ** '' Acroceratitis'' ** '' Acrotaeniostola'' ** '' Anoplomus'' ** '' Bistrispinaria'' ** '' Carpophthorella'' ** '' Ceratitoides'' ** '' Chaetellipsis'' ** ''Chelyophora'' ** ''Clinotaenia'' ** ''Cyrtostola'' ** '' Dietheria' ...
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