Selenide Iodide
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Selenide Iodide
The selenide iodides are chemical compounds that contain both selenide ions (Se2−) and iodide ions (I−) and one or metal atoms. They are in the class of mixed anion compounds or chalcogenide halides : 220px, Cadmium sulfide, a prototypical metal chalcogenide, is used as a yellow pigment. A chalcogenide is a chemical compound consisting of at least one chalcogen anion and at least one more electropositive element. Although all group 16 elemen .... Some related compounds do not actually contain a selenide ion, instead containing an iodoselenium cation. These cations include SeI3+, Se2I42+, Se6I22+, and polymeric Se6I+. List References {{Reflist Selenides Iodides ...
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Selenide
A selenide is a chemical compound containing a selenium anion with oxidation number of −2 (Se2−), much as sulfur does in a sulfide. The chemistry of the selenides and sulfides is similar. Similar to sulfide, in aqueous solution, the selenide ion, Se2−, is prevalent only in very basic conditions. In neutral conditions, hydrogen selenide ion, HSe−, is most common. In acid conditions, hydrogen selenide, H2Se, is formed. Some selenides are reactive to oxidation by air. Owing to the greater reducing power of selenide, metal selenides are more easily decomposed to the elements than are sulfides (tellurides are even more labile). Selenides of electropositive metals: such as aluminium selenide readily hydrolyse, even in moist air, evolving toxic hydrogen selenide gas. Pure selenide minerals are rare, instead selenium tends to partially substitute for sulfide in many sulfide minerals. The degree of substitution is only of commercial interest for copper sulfide ores, in which case ...
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Iodide
An iodide ion is the ion I−. Compounds with iodine in formal oxidation state −1 are called iodides. In everyday life, iodide is most commonly encountered as a component of iodized salt, which many governments mandate. Worldwide, iodine deficiency affects two billion people and is the leading preventable cause of intellectual disability. Structure and characteristics of inorganic iodides Iodide is one of the largest monatomic anions. It is assigned a radius of around 206 picometers. For comparison, the lighter halides are considerably smaller: bromide (196 pm), chloride (181 pm), and fluoride (133 pm). In part because of its size, iodide forms relatively weak bonds with most elements. Most iodide salts are soluble in water, but often less so than the related chlorides and bromides. Iodide, being large, is less hydrophilic compared to the smaller anions. One consequence of this is that sodium iodide is highly soluble in acetone, whereas sodium chloride is not. T ...
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Mixed Anion Compounds
Mixed anion compounds, heteroanionic materials or mixed anion materials are chemical compounds containing cations and more than one kind of anion. The compounds contain a single phase, rather than just a mixture. Use in materials science By having more than one anion, many more compounds can be made, and properties tuned to desirable values. In terms of optics, properties include laser damage threshold, refractive index, birefringence, absorption particularly in the ultraviolet or near infrared, non-linearity. Mechanical properties can include ability to grow a large crystal, ability to form a thin layer, strength, or brittleness. Thermal properties can include melting point, thermal stability, phase transition temperatures, Thermal expansion coefficient. For electrical properties, electric conductivity, band gap, superconducting transition temperature piezoelectricity, pyroelectricity, ferromagnetism, dielectric constant, charge-density wave transition can be adjusted. Pro ...
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Chalcogenide Halides
: 220px, Cadmium sulfide, a prototypical metal chalcogenide, is used as a yellow pigment. A chalcogenide is a chemical compound consisting of at least one chalcogen anion and at least one more electropositive element. Although all group 16 elements of the periodic table are defined as chalcogens, the term chalcogenide is more commonly reserved for sulfides, selenides, tellurides, and polonides, rather than oxides. Many metal ores exist as chalcogenides. Photoconductive chalcogenide glasses are used in xerography. Some pigments and catalysts are also based on chalcogenides. The metal dichalcogenide MoS2 is a common solid lubricant. Alkali metal and alkaline earth chalcogenides Alkali metal and alkaline earth monochalcogenides are salt-like, being colourless and often water-soluble. The sulfides tend to undergo hydrolysis to form derivatives containing bisulfide (SH−) anions. The alkali metal chalcogenides often crystallize with the anti fluorite structure and the alkaline ...
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Selenides
A selenide is a chemical compound containing a selenium anion with oxidation number of −2 (Se2−), much as sulfur does in a sulfide. The chemistry of the selenides and sulfides is similar. Similar to sulfide, in aqueous solution, the selenide ion, Se2−, is prevalent only in very basic conditions. In neutral conditions, hydrogen selenide ion, HSe−, is most common. In acid conditions, hydrogen selenide, H2Se, is formed. Some selenides are reactive to oxidation by air. Owing to the greater reducing power of selenide, metal selenides are more easily decomposed to the elements than are sulfides (tellurides are even more labile). Selenides of electropositive metals: such as aluminium selenide readily hydrolyse, even in moist air, evolving toxic hydrogen selenide gas. Pure selenide minerals are rare, instead selenium tends to partially substitute for sulfide in many sulfide minerals. The degree of substitution is only of commercial interest for copper sulfide ores, in which case ...
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