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Scotchgard
Scotchgard is a 3M brand of products, a stain and durable water repellent applied to fabric, furniture, and carpets to protect them from stains. Scotchgard products typically rely on organofluorine chemicals as the main active ingredient along with petroleum distillate solvents. Development of the formula The original formula for Scotchgard was discovered accidentally in 1952 by 3M chemists Patsy Sherman and Samuel Smith. Sales began in 1956, and in 1973 the two chemists received a patent for the formula. 3M reformulated Scotchgard and since June 2003 has replaced PFOS with perfluorobutanesulfonic acid (PFBS). PFBS has a much shorter half-life in people than PFOS (a little over one month vs. 5.4 years). 3M now states that Scotchgard utilizes a proprietary fluorinated urethane. Environmental concerns During 1999, the United States Environmental Protection Agency (EPA) began an investigation into the class of chemicals used in Scotchgard, after receiving information on the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Patsy Sherman
Patsy O’Connell Sherman (September 15, 1930– February 11, 2008) was an American chemist and co-inventor of Scotchgard, a 3M brand of products, a stain repellent and durable water repellent. Early life Sherman was born in Minneapolis, Minnesota, and graduated in 1948 from Minneapolis North High School. While in high school, an aptitude test indicated that Sherman would be most suited to the role of a housewife. She demanded to take the version of the test for male students, which suggested dentistry or science as potential career paths. In 1952, Sherman earned bachelor's degrees in chemistry and mathematics at Gustavus Adolphus College in St. Peter, Minnesota. Career At 3M In 1952, Sherman started her career at 3M. With Samuel Smith, Sherman co-invented Scotchgard, which soon become one of the most famous and widely used stain repellent and soil removal products in North America. The invention of Scotchgard was sparked by an accident. Sherman and coworkers were initi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perfluorooctane Sulfonate
Perfluorooctanesulfonic acid (PFOS) (conjugate base perfluorooctanesulfonate) is a chemical compound having an eight-carbon fluorocarbon chain and a sulfonic acid functional group and thus a perfluorosulfonic acid. It is an anthropogenic (man-made) fluorosurfactant, now regarded as a global pollutant. PFOS was the key ingredient in Scotchgard, a fabric protector made by 3M, and related stain repellents. The acronym "PFOS" refers to the parent sulfonic acid and to various salts of perfluorooctanesulfonate. These are all colorless or white, water soluble solids. Although of low acute toxicity, PFOS has attracted much attention for its pervasiveness and environmental impact. It was added to Annex B of the Stockholm Convention on Persistent Organic Pollutants in May 2009. History In 1949, 3M began producing PFOS-based compounds by electrochemical fluorination resulting in the synthetic precursor perfluorooctanesulfonyl fluoride. In 1968, organofluorine content was detected in the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Samuel Smith (chemist)
Samuel Smith (September 13, 1927 – January 1, 2005) was an American chemist who co-invented Scotchgard with Patsy Sherman while an employee at the 3M company in 1952. Biography He was born in New York City and received his B.S. from the City College of New York and his M.S. from the University of Michigan in 1949. He held 30 U.S. patents and retired from 3M in 1998. He died on January 1, 2005. Legacy Smith was an inductee in the National Inventors Hall of Fame The National Inventors Hall of Fame (NIHF) is an American not-for-profit organization, founded in 1973, which recognizes individual engineers and inventors who hold a U.S. patent of significant technology. Besides the Hall of Fame, it also opera .... References Further readingInvent Now: Smith 20th-century American chemists 1927 births 2005 deaths University of Michigan alumni 20th-century American inventors {{US-chemist-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
3M Brands
3M (originally the Minnesota Mining and Manufacturing Company) is an American multinational conglomerate operating in the fields of industry, worker safety, U.S. health care, and consumer goods. The company produces over 60,000 products under several brands, including adhesives, abrasives, laminates, passive fire protection, personal protective equipment, window films, paint protection films, dental and orthodontic products, electrical and electronic connecting and insulating materials, medical products, car-care products, electronic circuits, healthcare software and optical films. It is based in Maplewood, a suburb of Saint Paul, Minnesota. 3M made $35.4 billion in total sales in 2021, and ranked number 102 in the ''Fortune'' 500 list of the largest United States corporations by total revenue. , the company had approximately 95,000 employees, and had operations in more than 70 countries. History Five businessmen founded the Minnesota Mining and Manufacturing Company as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stain Repellent
A stain repellent is a product added to fabric in order to prevent stains. Stains Stains on fabrics are classified into three types: water-based stains and oil-based stains or a mix of both. Stain repellant fabrics Fabrics are finished with certain finishes that do not allow unwanted stains or that will wash out in simple laundry. Chemicals Mostly larger PFCAs such as perfluorooctanoic acid (PFOA) are used in stain repellancy. It is also known colloquially as C8. PFOA is a product of health concern and subject to regulatory action and voluntary industrial phase-outs. Alternative chemistry There are chemicals which are based on C8 free chemistry that may be used as an alternative to PFOA, but those are less durable. See also *Fluorosurfactant *Perfluorobutanesulfonic acid *Perfluorooctanesulfonic acid *Scotchgard Scotchgard is a 3M brand of products, a stain and durable water repellent applied to fabric, furniture, and carpets to protect them from stains. Scotchg ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perfluorooctanesulfonamide
Perfluorooctanesulfonamide (PFOSA) is a synthetic organofluorine compound. It is a fluorocarbon derivative and a perfluorinated compound, having an eight-carbon chain and a terminal sulfonamide functional group. PFOSA, a persistent organic pollutant, was an ingredient in 3M's former Scotchgard formulation from 1956 until 2003, and the compound was used to repel grease and water in food packaging along with other consumer applications. It breaks down to form perfluorooctane sulfonate (PFOS). The perfluorooctanesulfonyl fluoride-based chemistry that was used to make sulfonamides like PFOSA was phased out by 3M in the United States (US) during 2000–2002 but it has grown in China by other producers. PFOSA can be synthesized from perfluorooctane sulfonyl halides by reaction with liquid ammonia or by a two step reaction via an azide followed by reduction with Zn and HCl. PFOSA is also a metabolic by-product of ''N''-alkylated perfluorooctanesulfonamides. For example, ''N''-ethyl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perfluorobutanesulfonic Acid
Perfluorobutanesulfonic acid (PFBS) is a chemical compound having a four-carbon fluorocarbon chain and a sulfonic acid functional group. It is stable and unreactive because of the strength of carbon–fluorine bonds. It can occur in the form of a colorless liquid or a corrosive solid. Its conjugate base is perfluorobutanesulfonate (also called nonaflate) which functions as the hydrophobe in fluorosurfactants. Since June 2003, 3M has used PFBS as a replacement for the persistent, toxic, and bioaccumulative compound perfluorooctanesulfonic acid (PFOS) in its Scotchgard stain repellents. 3M markets surfactant with PFBS in two fluorosurfactants. Safety PFBS has a half-life of a little over one month in humans, much shorter than PFOS with 5.4 years. PFBS is persistent in the environment. Studies have not yet been specifically conducted to determine safety in humans. The ECHA decision adding PFBS and its salts to the REACH Regulation Candidate List of Substances of Very High Co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Durable Water Repellent
Durable water repellent, or DWR, is a coating added to fabrics at the factory to make them water-resistant (''hydrophobic''). Most factory-applied treatments are fluoropolymer based; these applications are quite thin and not always effective. Durable water repellents are commonly used in conjunction with waterproof breathable fabrics such as Gore-Tex to prevent the outer layer of fabric from becoming saturated with water. This saturation, called 'wetting out,' can reduce the garment's breathability (moisture transport through the breathable membrane) and let water through. As the DWR wears off over time, re-treatment is recommended when necessary. Many spray-on and wash-in products for treatment of non-waterproof garments and re-treatment of proofed garments losing their water-repellency are available. Older methods for factory application of DWR treatments involve applying a solution of a chemical onto the surface of the fabric by spraying or dipping. More recently the chemist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organofluorides
Organofluorine chemistry describes the chemistry of the organofluorines, organic compounds that contain the carbon–fluorine bond. Organofluorine compounds find diverse applications ranging from Lipophobicity, oil and hydrophobe, water repellents to pharmaceuticals, refrigerants, and reagents in catalysis. In addition to these applications, some organofluorine compounds are pollutants because of their contributions to ozone depletion, global warming, bioaccumulation, and toxicity. The area of organofluorine chemistry often requires special techniques associated with the handling of fluorinating agents. The carbon–fluorine bond Fluorine has several distinctive differences from all other substituents encountered in organic molecules. As a result, the physical and chemical properties of organofluorines can be distinctive in comparison to other organohalogens. # The carbon–fluorine bond is one of the strongest in organic chemistry (an average bond energy around 480 kJ/molKirsch ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorosurfactant
Per- and polyfluoroalkyl substances (PFASs) are synthetic organofluorine chemical compounds that have multiple fluorine atoms attached to an alkyl chain. An early definition, from 2011, required that they contain at least one perfluoroalkyl moiety, –CnF2n+1–. More recently (2021) the Organisation for Economic Co-operation and Development (OECD) expanded the definition, stating that "PFASs are defined as fluorinated substances that contain at least one fully fluorinated methyl or methylene carbon atom (without any H/Cl/Br/I atom attached to it), i.e. with a few noted exceptions, any chemical with at least a perfluorinated methyl group (–CF3) or a perfluorinated methylene group (–CF2–) is a PFAS." According to the OECD, at least 4,730 distinct PFASs are known with at least three perfluorinated carbon atoms. A United States Environmental Protection Agency (EPA) toxicity database, DSSTox, lists 14,735 PFASs, while PubChem lists approximately 6 million. A subgroup, the '' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorocarbon
Fluorocarbons are chemical compounds with carbon-fluorine bonds. Compounds that contain many C-F bonds often has distinctive properties, e.g., enhanced stability, volatility, and hydrophobicity. Fluorocarbons and their derivatives are commercial polymers, refrigerants, drugs, and anesthetics. Nomenclature Perfluorocarbons or PFCs, are organofluorine compounds with the formula CxFy, i.e., they contain only carbon and fluorine. The terminology is not strictly followed and many fluorine-containing organic compounds are called fluorocarbons. Compounds with the prefix perfluoro- are hydrocarbons, including those with heteroatoms, wherein all C-H bonds have been replaced by C-F bonds. Fluorocarbons includes perfluoroalkanes, fluoroalkenes, fluoroalkynes, and perfluoroaromatic compounds. Perfluoroalkanes Chemical properties Perfluoroalkanes are very stable because of the strength of the carbon–fluorine bond, one of the strongest in organic chemistry. Its strength is a resu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Minnesota
Minnesota () is a state in the upper midwestern region of the United States. It is the 12th largest U.S. state in area and the 22nd most populous, with over 5.75 million residents. Minnesota is home to western prairies, now given over to intensive agriculture; deciduous forests in the southeast, now partially cleared, farmed, and settled; and the less populated North Woods, used for mining, forestry, and recreation. Roughly a third of the state is covered in forests, and it is known as the "Land of 10,000 Lakes" for having over 14,000 bodies of fresh water of at least ten acres. More than 60% of Minnesotans live in the Minneapolis–Saint Paul metropolitan area, known as the "Twin Cities", the state's main political, economic, and cultural hub. With a population of about 3.7 million, the Twin Cities is the 16th largest metropolitan area in the U.S. Other minor metropolitan and micropolitan statistical areas in the state include Duluth, Mankato, Moorhead, Rochester, and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
