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Superselection
In quantum mechanics, superselection extends the concept of selection rules. Superselection rules are postulated rules forbidding the preparation of quantum states that exhibit coherence between eigenstates of certain observables. It was originally introduced by Wick, Wightman, and Wigner to impose additional restrictions to quantum theory beyond those of selection rules. Mathematically speaking, two quantum states \psi_1 and \psi_2 are separated by a selection rule if \langle \psi_1 , H , \psi_2 \rangle = 0 for the given Hamiltonian H , while they are separated by a superselection rule if \langle \psi_1 , A , \psi_2 \rangle = 0 for ''all ''physical observables A . Because no observable connects \langle \psi_1 , and , \psi_2 \rangle they cannot be put into a quantum superposition \alpha , \psi_1 \rangle + \beta , \psi_2 \rangle , and/or a quantum superposition cannot be distinguished from a classical mixture of the two states. It also implies that there is a cl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Selection Rules
In physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another. Selection rules have been derived for electromagnetic transitions in molecules, in atoms, in atomic nuclei, and so on. The selection rules may differ according to the technique used to observe the transition. The selection rule also plays a role in chemical reactions, where some are formally spin-forbidden reactions, that is, reactions where the spin state changes at least once from reactants to products. In the following, mainly atomic and molecular transitions are considered. Overview In quantum mechanics the basis for a spectroscopic selection rule is the value of the ''transition moment integral'' :\int \psi_1^* \, \mu \, \psi_2 \, \mathrm\tau\,, where \psi_1 and \psi_2 are the wave functions of the two states, "state 1" and "state 2", involved in the transition, and is the transition moment operator. Thi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary ( macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Homotopy Group
In mathematics, homotopy groups are used in algebraic topology to classify topological spaces. The first and simplest homotopy group is the fundamental group, denoted \pi_1(X), which records information about loops in a space. Intuitively, homotopy groups record information about the basic shape, or '' holes'', of a topological space. To define the ''n''-th homotopy group, the base-point-preserving maps from an ''n''-dimensional sphere (with base point) into a given space (with base point) are collected into equivalence classes, called homotopy classes. Two mappings are homotopic if one can be continuously deformed into the other. These homotopy classes form a group, called the ''n''-th homotopy group, \pi_n(X), of the given space ''X'' with base point. Topological spaces with differing homotopy groups are never equivalent ( homeomorphic), but topological spaces that homeomorphic have the same homotopy groups. The notion of homotopy of paths was introduced by Camille Jord ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coset
In mathematics, specifically group theory, a subgroup of a group may be used to decompose the underlying set of into disjoint, equal-size subsets called cosets. There are ''left cosets'' and ''right cosets''. Cosets (both left and right) have the same number of elements (cardinality) as does . Furthermore, itself is both a left coset and a right coset. The number of left cosets of in is equal to the number of right cosets of in . This common value is called the index of in and is usually denoted by . Cosets are a basic tool in the study of groups; for example, they play a central role in Lagrange's theorem that states that for any finite group , the number of elements of every subgroup of divides the number of elements of . Cosets of a particular type of subgroup (a normal subgroup) can be used as the elements of another group called a quotient group or factor group. Cosets also appear in other areas of mathematics such as vector spaces and error-correcting cod ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Summation Convention
In mathematics, especially the usage of linear algebra in Mathematical physics, Einstein notation (also known as the Einstein summation convention or Einstein summation notation) is a notational convention that implies summation over a set of indexed terms in a formula, thus achieving brevity. As part of mathematics it is a notational subset of Ricci calculus; however, it is often used in physics applications that do not distinguish between tangent and cotangent spaces. It was introduced to physics by Albert Einstein in 1916. Introduction Statement of convention According to this convention, when an index variable appears twice in a single term and is not otherwise defined (see Free and bound variables), it implies summation of that term over all the values of the index. So where the indices can range over the set , : y = \sum_^3 c_i x^i = c_1 x^1 + c_2 x^2 + c_3 x^3 is simplified by the convention to: : y = c_i x^i The upper indices are not exponents but are indic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Correlation Length
A correlation function is a function that gives the statistical correlation between random variables, contingent on the spatial or temporal distance between those variables. If one considers the correlation function between random variables representing the same quantity measured at two different points, then this is often referred to as an autocorrelation function, which is made up of autocorrelations. Correlation functions of different random variables are sometimes called cross-correlation functions to emphasize that different variables are being considered and because they are made up of cross-correlations. Correlation functions are a useful indicator of dependencies as a function of distance in time or space, and they can be used to assess the distance required between sample points for the values to be effectively uncorrelated. In addition, they can form the basis of rules for interpolating values at points for which there are no observations. Correlation functions used ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phase Transition
In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point. Types of phase transition At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Temperature
Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied on various reference points and thermometric substances for definition. The most common scales are the Celsius scale with the unit symbol °C (formerly called ''centigrade''), the Fahrenheit scale (°F), and the Kelvin scale (K), the latter being used predominantly for scientific purposes. The kelvin is one of the seven base units in the International System of Units (SI). Absolute zero, i.e., zero kelvin or −273.15 °C, is the lowest point in the thermodynamic temperature scale. Experimentally, it can be approached very closely but not actually reached, as recognized in the third law of thermodynamics. It would be impossible to extract energy as heat from a body at that temperature. Temperature is important in all fields of na ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ising Model
The Ising model () (or Lenz-Ising model or Ising-Lenz model), named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that represent magnetic dipole moments of atomic "spins" that can be in one of two states (+1 or −1). The spins are arranged in a graph, usually a lattice (where the local structure repeats periodically in all directions), allowing each spin to interact with its neighbors. Neighboring spins that agree have a lower energy than those that disagree; the system tends to the lowest energy but heat disturbs this tendency, thus creating the possibility of different structural phases. The model allows the identification of phase transitions as a simplified model of reality. The two-dimensional square-lattice Ising model is one of the simplest statistical models to show a phase transition. The Ising model was invented by the physicist , who gave it as a pro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Order Parameter
In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point. Types of phase transition At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have id ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hopf Algebra
Hopf is a German surname. Notable people with the surname include: * Eberhard Hopf (1902–1983), Austrian mathematician * Hans Hopf (1916–1993), German tenor * Heinz Hopf (1894–1971), German mathematician * Heinz Hopf (actor) (1934–2001), Swedish actor * Ludwig Hopf (1884–1939), German physicist * Maria Hopf (1914-2008), German botanist and archaeologist {{surname, Hopf German-language surnames ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lie Superalgebra
In mathematics, a Lie superalgebra is a generalisation of a Lie algebra to include a Z2 grading. Lie superalgebras are important in theoretical physics where they are used to describe the mathematics of supersymmetry. In most of these theories, the ''even'' elements of the superalgebra correspond to bosons and ''odd'' elements to fermions (but this is not always true; for example, the BRST supersymmetry is the other way around). Definition Formally, a Lie superalgebra is a nonassociative Z2-graded algebra, or ''superalgebra'', over a commutative ring (typically R or C) whose product ·, · called the Lie superbracket or supercommutator, satisfies the two conditions (analogs of the usual Lie algebra axioms, with grading): Super skew-symmetry: : ,y-(-1)^ ,x\ The super Jacobi identity: :(-1)^ ,_z">,_[y,_z<_a>_+_(-1)^[y,_[z,_x.html" ;"title=",_z.html" ;"title=", [y, z">, [y, z + (-1)^[y, [z, x">,_z.html" ;"title=", [y, z">, [y, z + (-1)^[y, [z, x + (-1)^[z, [x, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
