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Second Quantization
Second quantization, also referred to as occupation number representation, is a formalism used to describe and analyze quantum many-body systems. In quantum field theory, it is known as canonical quantization, in which the fields (typically as the wave functions of matter) are thought of as field operators, in a manner similar to how the physical quantities (position, momentum, etc.) are thought of as operators in first quantization. The key ideas of this method were introduced in 1927 by Paul Dirac, and were later developed, most notably, by Pascual Jordan and Vladimir Fock. In this approach, the quantum many-body states are represented in the Fock state basis, which are constructed by filling up each single-particle state with a certain number of identical particles. The second quantization formalism introduces the creation and annihilation operators to construct and handle the Fock states, providing useful tools to the study of the quantum many-body theory. Quantum many- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and Microscopic scale, (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales. Quantum systems have Bound state, bound states that are Quantization (physics), quantized to Discrete mathematics, discrete values of energy, momentum, angular momentum, and ot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Determinant
In mathematics, the determinant is a Scalar (mathematics), scalar-valued function (mathematics), function of the entries of a square matrix. The determinant of a matrix is commonly denoted , , or . Its value characterizes some properties of the matrix and the linear map represented, on a given basis (linear algebra), basis, by the matrix. In particular, the determinant is nonzero if and only if the matrix is invertible matrix, invertible and the corresponding linear map is an linear isomorphism, isomorphism. However, if the determinant is zero, the matrix is referred to as singular, meaning it does not have an inverse. The determinant is completely determined by the two following properties: the determinant of a product of matrices is the product of their determinants, and the determinant of a triangular matrix is the product of its diagonal entries. The determinant of a matrix is :\begin a & b\\c & d \end=ad-bc, and the determinant of a matrix is : \begin a & b & c \\ d & e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Jordan–Wigner Transformation
The Jordan–Wigner transformation is a transformation that maps spin operators onto fermionic creation and annihilation operators. It was proposed by Pascual Jordan and Eugene Wigner for one-dimensional lattice models, but now two-dimensional analogues of the transformation have also been created. The Jordan–Wigner transformation is often used to exactly solve 1D spin-chains such as the Ising and XY models by transforming the spin operators to fermionic operators and then diagonalizing in the fermionic basis. This transformation actually shows that the distinction between spin-1/2 particles and fermions is nonexistent. It can be applied to systems with an arbitrary dimension. Analogy between spins and fermions In what follows we will show how to map a 1D spin chain of spin-1/2 particles to fermions. Take spin-1/2 Pauli operators acting on a site j of a 1D chain, \sigma_^, \sigma_^, \sigma_^. Taking the anticommutator of \sigma_^ and \sigma_^, we find \ = I, as would be ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kronecker Delta
In mathematics, the Kronecker delta (named after Leopold Kronecker) is a function of two variables, usually just non-negative integers. The function is 1 if the variables are equal, and 0 otherwise: \delta_ = \begin 0 &\text i \neq j, \\ 1 &\text i=j. \end or with use of Iverson brackets: \delta_ = =j, For example, \delta_ = 0 because 1 \ne 2, whereas \delta_ = 1 because 3 = 3. The Kronecker delta appears naturally in many areas of mathematics, physics, engineering and computer science, as a means of compactly expressing its definition above. Generalized versions of the Kronecker delta have found applications in differential geometry and modern tensor calculus, particularly in formulations of gauge theory and topological field models. In linear algebra, the n\times n identity matrix \mathbf has entries equal to the Kronecker delta: I_ = \delta_ where i and j take the values 1,2,\cdots,n, and the inner product of vectors can be written as \mathbf\cdot\mathbf = \sum_^n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tensor Algebra
In mathematics, the tensor algebra of a vector space ''V'', denoted ''T''(''V'') or ''T''(''V''), is the algebra over a field, algebra of tensors on ''V'' (of any rank) with multiplication being the tensor product. It is the free algebra on ''V'', in the sense of being left adjoint to the forgetful functor from algebras to vector spaces: it is the "most general" algebra containing ''V'', in the sense of the corresponding universal property (see #Adjunction and universal property, below). The tensor algebra is important because many other algebras arise as quotient associative algebra, quotient algebras of ''T''(''V''). These include the exterior algebra, the symmetric algebra, Clifford algebras, the Weyl algebra and universal enveloping algebras. The tensor algebra also has two coalgebra structures; one simple one, which does not make it a bi-algebra, but does lead to the concept of a cofree coalgebra, and a more complicated one, which yields a bialgebra, and can be extended by gi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Harmonic Oscillator
The quantum harmonic oscillator is the quantum-mechanical analog of the classical harmonic oscillator. Because an arbitrary smooth potential can usually be approximated as a harmonic potential at the vicinity of a stable equilibrium point, it is one of the most important model systems in quantum mechanics. Furthermore, it is one of the few quantum-mechanical systems for which an exact, analytical solution is known. One-dimensional harmonic oscillator Hamiltonian and energy eigenstates The Hamiltonian of the particle is: \hat H = \frac + \frac k ^2 = \frac + \frac m \omega^2 ^2 \, , where is the particle's mass, is the force constant, \omega = \sqrt is the angular frequency of the oscillator, \hat is the position operator (given by in the coordinate basis), and \hat is the momentum operator (given by \hat p = -i \hbar \, \partial / \partial x in the coordinate basis). The first term in the Hamiltonian represents the kinetic energy of the particle, and the second ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vacuum State
In quantum field theory, the quantum vacuum state (also called the quantum vacuum or vacuum state) is the quantum state with the lowest possible energy. Generally, it contains no physical particles. However, the quantum vacuum is not a simple empty space, but instead contains fleeting electromagnetic waves and particles that pop into and out of the quantum field. The QED vacuum of quantum electrodynamics (or QED) was the first vacuum of quantum field theory to be developed. QED originated in the 1930s, and in the late 1940s and early 1950s, it was reformulated by Feynman, Tomonaga, and Schwinger, who jointly received the Nobel prize for this work in 1965. For a historical discussion, see for example For the Nobel prize details and the Nobel lectures by these authors, see Today, the electromagnetic interactions and the weak interactions are unified (at very high energies only) in the theory of the electroweak interaction. The Standard Model is a generalization ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hilbert Space
In mathematics, a Hilbert space is a real number, real or complex number, complex inner product space that is also a complete metric space with respect to the metric induced by the inner product. It generalizes the notion of Euclidean space. The inner product allows lengths and angles to be defined. Furthermore, Complete metric space, completeness means that there are enough limit (mathematics), limits in the space to allow the techniques of calculus to be used. A Hilbert space is a special case of a Banach space. Hilbert spaces were studied beginning in the first decade of the 20th century by David Hilbert, Erhard Schmidt, and Frigyes Riesz. They are indispensable tools in the theories of partial differential equations, mathematical formulation of quantum mechanics, quantum mechanics, Fourier analysis (which includes applications to signal processing and heat transfer), and ergodic theory (which forms the mathematical underpinning of thermodynamics). John von Neumann coined the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fock Space
The Fock space is an algebraic construction used in quantum mechanics to construct the quantum states space of a variable or unknown number of identical particles from a single particle Hilbert space . It is named after V. A. Fock who first introduced it in his 1932 paper "Konfigurationsraum und zweite Quantelung" (" Configuration space and second quantization"). M.C. Reed, B. Simon, "Methods of Modern Mathematical Physics, Volume II", Academic Press 1975. Page 328. Informally, a Fock space is the sum of a set of Hilbert spaces representing zero particle states, one particle states, two particle states, and so on. If the identical particles are bosons, the -particle states are vectors in a symmetrized tensor product of single-particle Hilbert spaces . If the identical particles are fermions, the -particle states are vectors in an antisymmetrized tensor product of single-particle Hilbert spaces (see symmetric algebra and exterior algebra respectively). A general state in Fock ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pauli Exclusion Principle
In quantum mechanics, the Pauli exclusion principle (German: Pauli-Ausschlussprinzip) states that two or more identical particles with half-integer spins (i.e. fermions) cannot simultaneously occupy the same quantum state within a system that obeys the laws of quantum mechanics. This principle was formulated by Austrian physicist Wolfgang Pauli in 1925 for electrons, and later extended to all fermions with his spin–statistics theorem of 1940. In the case of electrons in atoms, the exclusion principle can be stated as follows: in a poly-electron atom it is impossible for any two electrons to have the same two values of ''all'' four of their quantum numbers, which are: ''n'', the principal quantum number; ', the azimuthal quantum number; ''m'', the magnetic quantum number; and ''ms'', the spin quantum number. For example, if two electrons reside in the same orbital, then their values of ''n'', ', and ''m'' are equal. In that case, the two values of ''m''s (spin) pair must be ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Slater Determinant
In quantum mechanics, a Slater determinant is an expression that describes the wave function of a multi-fermionic system. It satisfies anti-symmetry requirements, and consequently the Pauli principle, by changing sign upon exchange of two fermions.Molecular Quantum Mechanics Parts I and II: An Introduction to QUANTUM CHEMISTRY (Volume 1), P. W. Atkins, Oxford University Press, 1977, . Only a small subset of all possible many-body fermionic wave functions can be written as a single Slater determinant, but those form an important and useful subset because of their simplicity. The Slater determinant arises from the consideration of a wave function for a collection of electrons, each with a wave function known as the spin-orbital \chi(\mathbf), where \mathbf denotes the position and spin of a single electron. A Slater determinant containing two electrons with the same spin orbital would correspond to a wave function that is zero everywhere. The Slater determinant is named for John ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Parity Of A Permutation
In mathematics, when ''X'' is a finite set with at least two elements, the permutations of ''X'' (i.e. the bijective functions from ''X'' to ''X'') fall into two classes of equal size: the even permutations and the odd permutations. If any total ordering of ''X'' is fixed, the parity (oddness or evenness) of a permutation \sigma of ''X'' can be defined as the parity of the number of inversions for ''σ'', i.e., of pairs of elements ''x'', ''y'' of ''X'' such that and . The sign, signature, or signum of a permutation ''σ'' is denoted sgn(''σ'') and defined as +1 if ''σ'' is even and −1 if ''σ'' is odd. The signature defines the alternating character of the symmetric group S''n''. Another notation for the sign of a permutation is given by the more general Levi-Civita symbol (''ε''''σ''), which is defined for all maps from ''X'' to ''X'', and has value zero for non-bijective maps. The sign of a permutation can be explicitly expressed as : where ''N''('' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
