Rubidium Nitrate
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Rubidium Nitrate
Rubidium nitrate is an inorganic compound with the formula Rb NO3. This alkali metal nitrate salt is white and highly soluble in water. Properties Rubidium nitrate is a white crystalline powder that is highly soluble in water and very slightly soluble in acetone. In a flame test, RbNO3 gives a mauve/light purple colour. Uses Rubidium compounds have very few applications. Like caesium nitrate, it is used in infrared radiation optics, in pyrotechnic compositions as a pyrotechnic colorant and as an oxidizer, ''e.g.'' in decoys and illumination flares although it is rarely used in fireworks to produce a red-violet colour. It is also used as a raw material for preparation of other rubidium compounds and rubidium metal, for manufacture of catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the c ...
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Hygroscopic
Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance's molecules, adsorbing substances can become physically changed, e.g., changing in volume, boiling point, viscosity or some other physical characteristic or property of the substance. For example, a finely dispersed hygroscopic powder, such as a salt, may become clumpy over time due to collection of moisture from the surrounding environment. ''Deliquescent'' materials are sufficiently hygroscopic that they absorb so much water that they become liquid and form an aqueous solution. Etymology and pronunciation The word ''hygroscopy'' () uses combining forms of '' hygro-'' and '' -scopy''. Unlike any other ''-scopy'' word, it no longer refers to a viewing or imaging mode. It did begin that way, with the word ''hygroscope'' referring in th ...
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Flame Test
A flame test is an analytical procedure used in chemistry to detect the presence of certain elements, primarily metal ions, based on each element's characteristic flame emission spectrum (which may be affected by the presence of chloride ion). The color of flames in general also depends on temperature and oxygen fed; see flame color. Process The test involves introducing a sample of the element or compound to a hot, non-luminous flame, and observing the color of the flame that results. The idea of the test is that sample atoms evaporate and since they are hot, they emit light when being in flame. The solvent of the solution evaporates first, leaving finely divided solid particles which move to the hottest region of the flame where gaseous atoms and ions are produced through the dissociation of molecules. Here electrons are excited by the heat, and the spontaneously emit photon to decay to lower energy states. Bulk sample emits light too, but its light is not good for a ...
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Nitrates
Nitrate is a polyatomic ion with the chemical formula . Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insoluble nitrate is bismuth oxynitrate. Structure The ion is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a formal charge of −1. This charge results from a combination formal charge in which each of the three oxygens carries a − charge, whereas the nitrogen carries a +1 charge, all these adding up to formal charge of the polyatomic nitrate ion. This arrangement is commonly used as an example of resonance. Like the isoelectronic carbonate ion, the nitrate ion can be represented by resonance structures: Dietary nitrate A rich source of inorganic nitrate in the human diets come from leafy green foods ...
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Rubidium Compounds
Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher than water. On Earth, natural rubidium comprises two isotopes: 72% is a stable isotope 85Rb, and 28% is slightly radioactive 87Rb, with a half-life of 48.8 billion years—more than three times as long as the estimated age of the universe. German chemists Robert Bunsen and Gustav Kirchhoff discovered rubidium in 1861 by the newly developed technique, flame spectroscopy. The name comes from the Latin word , meaning deep red, the color of its emission spectrum. Rubidium's compounds have various chemical and electronic applications. Rubidium metal is easily vaporized and has a convenient spectral absorption range, making it a frequent target for laser manipulation of atoms. Rubidium is not a known nutrient for any living organisms. However, r ...
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Scintillation Counter
A scintillation counter is an instrument for detecting and measuring ionizing radiation by using the excitation effect of incident radiation on a scintillating material, and detecting the resultant light pulses. It consists of a scintillator which generates photons in response to incident radiation, a sensitive photodetector (usually a photomultiplier tube (PMT), a charge-coupled device (CCD) camera, or a photodiode), which converts the light to an electrical signal and electronics to process this signal. Scintillation counters are widely used in radiation protection, assay of radioactive materials and physics research because they can be made inexpensively yet with good quantum efficiency, and can measure both the intensity and the energy of incident radiation. History The first electronic scintillation counter was invented in 1944 by Sir Samuel Curran whilst he was working on the Manhattan Project at the University of California at Berkeley. There was a requirement to measur ...
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Catalyst
Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst. Catalysis may be classified as either homogeneous, whose components are dispersed in the same phase (usually gaseous or liquid) as the reactant, or heterogeneous, whose components are not in the same phase. Enzymes and other biocatalysts are often considered as a third category. Catalysis is ubiquitous in chemical industry of all kinds. Estimates are that 90% of all commercially produced chemical products involve catalysts at some s ...
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Fireworks
Fireworks are a class of Explosive, low explosive Pyrotechnics, pyrotechnic devices used for aesthetic and entertainment purposes. They are most commonly used in fireworks displays (also called a fireworks show or pyrotechnics), combining a large number of devices in an outdoor setting. Such displays are the focal point of many cultural and religious Celebration (party), celebrations. Fireworks take many forms to produce four primary effects: noise, light, smoke, and floating materials (confetti most notably). They may be designed to burn with colored flames and sparks including red, orange, yellow, green, blue, purple and silver. They are generally classified by where they perform, either 'ground' or 'aerial'. Aerial fireworks may have their own Air propulsion, propulsion (skyrocket) or be shot into the air by a Mortar (weapon), mortar (aerial shell). Most fireworks consist of a paper or Card stock, pasteboard tube or casing filled with the combustion, combustible materia ...
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Flare
A flare, also sometimes called a fusée, fusee, or bengala in some Latin-speaking countries, is a type of pyrotechnic that produces a bright light or intense heat without an explosion. Flares are used for distress signaling, illumination, or defensive countermeasures in civilian and military applications. Flares may be ground pyrotechnics, projectile pyrotechnics, or parachute-suspended to provide maximum illumination time over a large area. Projectile pyrotechnics may be dropped from aircraft, fired from rocket or artillery, or deployed by flare guns or handheld percussive tubes. History The earliest recorded use of gunpowder for signaling purposes was the 'signal bomb' used by the Chinese Song Dynasty (960–1279) as the Mongol-led Yuan Dynasty (1271–1368) besieged Yangzhou in 1276. These soft-shelled bombs, timed to explode in midair, were used to send messages to a detachment of troops far in the distance. Another mention of the signal bomb appears in a text dating ...
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Decoy Flare
A flare or decoy flare is an aerial infrared countermeasure used by a plane or helicopter to counter an infrared homing ("heat-seeking") surface-to-air missile or air-to-air missile. Flares are commonly composed of a pyrotechnic composition based on magnesium or another hot-burning metal, with burning temperature equal to or hotter than engine exhaust. The aim is to make the infrared-guided missile seek out the heat signature from the flare rather than the aircraft's engines. Tactics In contrast to radar-guided missiles, IR-guided missiles are very difficult to find as they approach aircraft. They do not emit detectable radar, and they are generally fired from behind, directly toward the engines. In most cases, pilots have to rely on their wingmen to spot the missile's smoke trail and alert of a launch. Since IR-guided missiles have a shorter range than their radar-guided counterparts, good situational awareness of altitude and potential threats continues to be an effective ...
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Oxidizer
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, to a substrate. Combust ...
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Pyrotechnic Colorant
A pyrotechnic colorant is a chemical compound which causes a flame to burn with a particular color. These are used to create the colors in pyrotechnic compositions like fireworks and colored fires. The color-producing species are usually created from other chemicals during the reaction. Metal salts are commonly used; elemental metals are used rarely (e.g. copper for blue flames). The color of the flame is dependent on the metal cation; the anion of the salt has very little direct influence. The anions however influence the flame temperature, both by increasing it (e.g. nitrates, chlorates) and decreasing it (e.g. carbonates, oxalates), indirectly influencing the flame brightness and brilliancy. For temperature-decreasing additives, the limit of colorant may be about 10–20 wt.% of the composition. Some common examples are: The * indicates that the compound will burn orange where x=0,2,3,5. Radiating species Despite the wide numbers of metal ion donors, they serve to form o ...
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Pyrotechnic Composition
A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic reaction, exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction. Types Basic types of pyrotechnic compositions are: * flash powder – burns very fast, produces explosions and/or bright flashes of light * gunpowder – burns slower than flash powder, produces large amount of gases * solid propellants – produce large amount of hot gases, used as sources of kinetic energy for rockets and projectiles * pyrotechnic initiators – produce large amount of heat, flames, and/or hot sparks, used to ignite other compositions * gas generators – produce large amount of gas, either high volume at short time (for actuators and ejection charges, often using solid propellants) or controlled flow rate (e.g. chemical ...
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