Rubber Pollution
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Rubber Pollution
Rubber pollution, similar to plastic pollution, occurs in various environments, and originates from a variety of sources, ranging from the food industry processing chain to tire wear. Synthetic and natural rubber dust and fragments now occur in food, airborne as particulates in air pollution, hidden in the earth as soil pollution, and in waterways, lakes and the sea. Causes Tire wear is a major source of rubber pollution. A concern is that, unlike exhaust emissions, vehicle tire wear pollution is not regulated. Some devices are nonetheless being developed in an effort to reduce the amount of particulates coming from the tire and otherwise ending up in the atmosphere. Although not immediately visible to the naked eye, tire dust makes up a significant portion of road debris. Other sources can be artificial turf and rubber O-rings and seals. Classification Very fine rubber dust particles can depending on the classification be counted among microplastic (because rubber is just a ...
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Plastic Pollution
Plastic pollution is the accumulation of plastic objects and particles (e.g. plastic bottles, bags and microbeads) in the Earth's environment that adversely affects humans, wildlife and their habitat. Plastics that act as pollutants are categorized by size into micro-, meso-, or macro debris. Plastics are inexpensive and durable, making them very adaptable for different uses; as a result, manufacturers choose to use plastic over other materials. However, the chemical structure of most plastics renders them resistant to many natural processes of degradation and as a result they are slow to degrade. Together, these two factors allow large volumes of plastic to enter the environment as mismanaged waste and for it to persist in the ecosystem. Plastic pollution can afflict land, waterways and oceans. It is estimated that 1.1 to 8.8 million tonnes of plastic waste enters the ocean from coastal communities each year. It is estimated that there is a stock of 86 million tons of plastic ...
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O-ring
An O-ring, also known as a packing or a toric joint, is a mechanical gasket in the shape of a torus; it is a loop of elastomer with a round cross-section, designed to be seated in a groove and compressed during assembly between two or more parts, forming a seal at the interface. The O-ring may be used in static applications or in dynamic applications where there is relative motion between the parts and the O-ring. Dynamic examples include rotating pump shafts and hydraulic cylinder pistons. Static applications of O-rings may include fluid or gas sealing applications in which: (1) the O-ring is compressed resulting in zero clearance, (2) the O-ring material is vulcanized solid such that it is impermeable to the fluid or gas, and (3) the O-ring material is resistant to degradation by the fluid or gas. The wide range of potential liquids and gases that need to be sealed has necessitated the development of a wide range of materials. O-rings are one of the most common seals used i ...
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Tire Recycling
Tire recycling, or rubber recycling, is the process of recycling waste tires that are no longer suitable for use on vehicles due to wear or irreparable damage. These tires are a challenging source of waste, due to the large volume produced, the durability of the tires, and the components in the tire that are ecologically problematic. Because tires are highly durable and non-biodegradable, they can consume valuable space in landfills. If waste tires are improperly managed they may cause rubber pollution. In 1990, it was estimated that over 1 billion scrap tires were in stockpiles in the United States. As of 2015, only 67 million tires remain in stockpiles. From 1994 to 2010, the European Union increased the amount of tires recycled from 25% of annual discards to nearly 95%, with roughly half of the end-of-life tires used for energy, mostly in cement manufacturing. Pyrolysis and devulcanization could facilitate recycling. Aside from use as fuel, the main end use for tires rema ...
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Hydrofuramide
Hydrofuramide is a condensation product of three molar equivalents of furfural with two molar equivalents of ammonia. Hydrofuramide is a crystalline solid with a melting point of 118-119 °C. The molecule may be described as a diimine with three pendant furanyl rings. Hydrofuramide is a versatile specialty chemical with applications in diverse areas, including rubber additives, pharmaceutical intermediates, preservatives, and rodenticides. Synthesis Hydrofuramide was prepared in 1960 by Kapur via the reaction of furfural with aqueous ammonia in chilled ethanol solution. Reactions The reactive imine double bonds of hydrofuramide are easily reduced. Reduction with aqueous sodium borohydride yields ''N'',''N''-bisfurfuryl-2-furylmethanediamine, useful as an antihypertensive drug compound. Catalytic hydrogenation of hydrofuramide with Raney nickel in the presence of ammonia in ethanol yields mixtures of furfurylamine and difurfurylamine. By contrast, hydrogenation in aceti ...
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Carbonyl Sulfide
Carbonyl sulfide is the chemical compound with the linear formula OCS. It is a colorless flammable gas with an unpleasant odor. It is a linear molecule consisting of a carbonyl group double bonded to a sulfur atom. Carbonyl sulfide can be considered to be intermediate between carbon dioxide and carbon disulfide, both of which are valence isoelectronic with it. Occurrence Carbonyl sulfide is the most abundant sulfur compound naturally present in the atmosphere, at , because it is emitted from oceans, volcanoes and deep sea vents. As such, it is a significant compound in the global sulfur cycle. Measurements on the Antarctica ice cores and from air trapped in snow above glaciers (firn air) have provided a detailed picture of OCS concentrations from 1640 to the present day and allow an understanding of the relative importance of anthropogenic and non-anthropogenic sources of this gas to the atmosphere. Some carbonyl sulfide that is transported into the stratospheric sulfate lay ...
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Antiozonant
An antiozonant, also known as anti-ozonant, is an organic compound that prevents or retards damage caused by ozone. The most important antiozonants are those which prevent degradation of elastomers like rubber. A number of research projects study the application of another type of antiozonats to protect plants. Effect of ozone Many elastomers are rich in unsaturated double bonds, which can react with ozone present in the air in process known as ozonolysis. This reaction breaks the polymer chains, degrading the mechanical properties of the material. The most obvious effect of this is cracking of the elastomer (ozone cracking), which is exacerbated by mechanical stress. The rate of degradation is effected both by the chemical structure of the elastomer and the amount of ozone in the environment. Elastomers which are rich in double bonds, such as natural rubber, polybutadiene, styrene-butadiene rubber and nitrile rubber are the most sensitive to degradation, whereas butyl rubbe ...
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6PPD-quinone
6PPD is an organic chemical widely used as stabilising additive (or antidegradant) in rubbers, such as NR, SBR and BR; all of which are common in vehicle tires. Although it is an effective antioxidant it is primarily used because of its excellent antiozonant peformance. It is one of several antiozonants based around ''p''-phenylenediamine (PPD). Manufacturing 6PPD is prepared by reductive amination of methyl isobutyl ketone with 4-aminodiphenylamine. This produces a racemic mixture. Application 6PPD is a common rubber antiozonant, with a major application in vehicle tires. It is mobile within the rubber and is slowly forced to the surface via blooming. Here it forms a "scavenger-protective film", reacting with the ozone more quickly that the ozone can react with the rubber. This process initially forms aminoxyl radicals and was thought to stop at the quinone diimine, but is now known to continue to form quinones, amongst other products. Despite 6PPD being used in tires sinc ...
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Monomer
In chemistry, a monomer ( ; ''mono-'', "one" + '' -mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization. Classification Monomers can be classified in many ways. They can be subdivided into two broad classes, depending on the kind of the polymer that they form. Monomers that participate in condensation polymerization have a different stoichiometry than monomers that participate in addition polymerization: : Other classifications include: *natural vs synthetic monomers, e.g. glycine vs caprolactam, respectively *polar vs nonpolar monomers, e.g. vinyl acetate vs ethylene, respectively *cyclic vs linear, e.g. ethylene oxide vs ethylene glycol, respectively The polymerization of one kind of monomer gives a homopolymer. Many polymers are copolymers, meaning that they are derived from two different monomers. In the case of condensation polymerizations, the r ...
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Polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'' ...
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Microplastic
Microplastics are fragments of any type of plastic less than in length, according to the U.S. National Oceanic and Atmospheric Administration (NOAA) and the European Chemicals Agency. They cause pollution by entering natural ecosystems from a variety of sources, including cosmetics, clothing, food packaging, and industrial processes. The term ''macroplastics'' is used to differentiate microplastics from larger plastic waste, such as plastic bottles. Two classifications of microplastics are currently recognized. Primary microplastics include any plastic fragments or particles that are already 5.0 mm in size or less before entering the environment. These include microfibers from clothing, microbeads, and plastic pellets (also known as nurdles). Secondary microplastics arise from the degradation (breakdown) of larger plastic products through natural weathering processes after entering the environment. Such sources of secondary microplastics include water and soda bottles, fis ...
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Artificial Turf
Artificial turf is a surface of synthetic fibers made to look like natural grass. It is most often used in arenas for sports that were originally or are normally played on grass. However, it is now being used on residential lawns and commercial applications as well. The main reason is maintenanceartificial turf stands up to heavy use, such as in sports, and requires no irrigation or trimming. Domed, covered, and partially covered stadiums may require artificial turf because of the difficulty of getting grass enough sunlight to stay healthy. Artificial turf does have its downside, however: limited life, periodic cleaning requirements, petroleum use, toxic chemicals from infill, and heightened health and safety concerns. Artificial turf first gained substantial attention in 1966, when it was installed in the year-old Astrodome. The specific product used was "ChemGrass", developed by Monsanto and rebranded as AstroTurf; this term since then became a generic trademark for any ...
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Food Industry
The food industry is a complex, global network of diverse businesses that supplies most of the food consumed by the world's population. The food industry today has become highly diversified, with manufacturing ranging from small, traditional, family-run activities that are highly labor-intensive, to large, capital-intensive and highly mechanized industrial processes. Many food industries depend almost entirely on local agriculture, produce, or fishing. It is challenging to find an inclusive way to cover all aspects of food production and sale. The UK Food Standards Agency describes it as "the whole food industry – from farming and food production, packaging and distribution, to retail and catering." The Economic Research Service of the USDA uses the term ''food system'' to describe the same thing, stating: "The U.S. food system is a complex network of farmers and the industries that link to them. Those links include makers of farm equipment and chemicals as well as firms ...
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