Resin (enzyme)
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Resin (enzyme)
In polymer chemistry and materials science, a resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on naturally occurring resins. Plants secrete resins for their protective benefits in response to injury. The resin protects the plant from insects and pathogens. Resins confound a wide range of herbivores, insects, and pathogens, while the volatile phenolic compounds may attract benefactors such as parasitoids or predators of the herbivores that attack the plant. Composition Most plant resins are composed of terpenes. Specific components are alpha-pinene, beta-pinene, delta-3 carene, and sabinene, the monocyclic terpenes limonene and terpinolene, and smaller amounts of the tricyclic sesquiterpenes, longifolene, caryophyllene, and delta-cadinene. Some resins also contain a high proportion of resin acids. Rosins on the other hand are less ...
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Resin With Insect (aka)
In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on naturally occurring resins. Plants secrete resins for their protective benefits in response to injury. The resin protects the plant from insects and pathogens. Resins confound a wide range of herbivores, insects, and pathogens, while the volatile phenolic compounds may attract benefactors such as parasitoids or predators of the herbivores that attack the plant. Composition Most plant resins are composed of terpenes. Specific components are alpha-pinene, beta-pinene, delta-3 carene, and sabinene, the monocyclic terpenes limonene and terpinolene, and smaller amounts of the tricyclic sesquiterpenes, longifolene, caryophyllene, and delta-cadinene. Some resins also contain a high proportion of resin acids. Rosins on the other hand are less v ...
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Limonene
Limonene is a colorless liquid aliphatic hydrocarbon classified as a cyclic monoterpene, and is the major component in the oil of citrus fruit peels. The -isomer, occurring more commonly in nature as the fragrance of oranges, is a flavoring agent in food manufacturing. It is also used in chemical synthesis as a precursor to carvone and as a renewables-based solvent in cleaning products. The less common -isomer has a piny, turpentine-like odor, and is found in the edible parts of such plants as caraway, dill, and bergamot orange plants. Limonene takes its name from Italian ''limone'' ("lemon"). Limonene is a chiral molecule, and biological sources produce one enantiomer: the principal industrial source, citrus fruit, contains -limonene ((+)-limonene), which is the (''R'')-enantiomer. Racemic limonene is known as dipentene. -Limonene is obtained commercially from citrus fruits through two primary methods: centrifugal separation or steam distillation. Chemical reactions Limon ...
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Protium (plant)
''Protium'' is a genus of more than 140 species of flowering plants in the family Burseraceae. It is native to the Neotropics (where around 175 species have been found), Madagascar, Papua New Guinea, Indonesia and southern Asia from Pakistan east to Vietnam. The genus had been included in ''Bursera'', but is distinct, being most closely related to '' Crepidospermum'' and ''Tetragastris''. The species are usually small or medium-sized trees, but some can be large, up to tall. In their native range, some species are grown for timber, used as firewood, as medicinal plants, for their fruit, their resin (Copal) or in other cultural contexts. Selected species * '' Protium almecega'' March. * '' Protium apiculatum'' Sw. * '' Protium aracouchini'' * '' Protium asperum'' * '' Protium attenuatum'' * '' Protium connarifolium'' * ''Protium copal'' * '' Protium correae'' * '' Protium decandrum'' * '' Protium elegans'' * '' Protium gigantium'' * '' Protium guianense'' * '' Protium hebetatum' ...
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Copal
Copal is tree resin, particularly the aromatic resins from the copal tree ''Protium copal'' (Burseraceae) used by the cultures of pre-Columbian Mesoamerica as ceremonially burned incense and for other purposes. More generally, copal includes resinous substances in an intermediate stage of polymerization and hardening between "gummier" resins and amber. Copal that is partly mineralized is known as copaline. It is available in different forms; the hard, amber-like yellow copal is a less expensive version, while the milky white copal is more expensive. Etymology The word "copal" is derived from the Nahuatl language word , meaning "incense". History and uses Subfossil copal is well known from New Zealand (kauri gum from ''Agathis australis'' (Araucariaceae)), Japan, the Dominican Republic, Colombia, and Madagascar. It often has inclusions and is sometimes sold as "young amber". When it is treated or enhanced in an autoclave (as is sometimes done to industrialized Baltic amber) ...
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Balsam
Balsam is the resinous exudate (or sap) which forms on certain kinds of trees and shrubs. Balsam (from Latin balsamum "gum of the balsam tree", ultimately from Semitic, Aramaic ''busma'', Arabic ''balsam'' and Hebrew ''basam'', "spice", "perfume") owes its name to the biblical Balm of Gilead. Chemistry Balsam is a solution of plant-specific resins in plant-specific solvents (essential oils). Such resins can include resin acids, esters, or alcohols. The exudate is a mobile to highly viscous liquid and often contains crystallized resin particles. Over time and as a result of other influences the exudate loses its liquidizing components or gets chemically converted into a solid material (i.e. by autoxidation). Some authors require balsams to contain benzoic or cinnamic acid or their esters. Plant resins are sometimes classified according to other plant constituents in the mixture, for example as: * pure resins (guaiac, hashish), * gum-resins (containing gums/polysaccharides) ...
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Balm Of Gilead
Balm of Gilead was a rare perfume used medicinally, that was mentioned in the Hebrew Bible, and named for the region of Gilead, where it was produced. The expression stems from William Tyndale's language in the King James Bible of 1611, and has come to signify a universal cure in figurative speech. The tree or shrub producing the balm is commonly identified as ''Commiphora gileadensis''. However, some botanical scholars have concluded that the actual source was a terebinth tree in the genus ''Pistacia''.Groom (1981) History Hebrew Bible In the Bible, balsam is designated by various names: (''bosem''), (''besem''), (''ẓori''), (''nataf''), which all differ from the terms used in rabbinic literature. After having cast Joseph into a pit, his brothers noticed a caravan on its way from Gilead to Egypt, "with their camels bearing spicery, and balm, and myrrh" (Gen. ). When Jacob dispatched his embassy into Egypt, his present to the unknown ruler included "a little balm" (Gen. ) ...
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Amber
Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In Maxine N. Lurie and Marc Mappen (eds.) ''Encyclopedia of New Jersey'', Rutgers University Press, . Amber is used in jewelry and has been used as a healing agent in folk medicine. There are five classes of amber, defined on the basis of their chemical constituents. Because it originates as a soft, sticky tree resin, amber sometimes contains animal and plant material as inclusions. Amber occurring in coal seams is also called resinite, and the term ''ambrite'' is applied to that found specifically within New Zealand coal seams. Etymology The English word ''amber'' derives from Arabic (ultimately from Middle Persian ''ambar'') via Middle Latin ''ambar'' and Middle French ''ambre''. The word was adopted in Middle English in the 14th century ...
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Rosin
Rosin (), also called colophony or Greek pitch ( la, links=no, pix graeca), is a solid form of resin obtained from pines and some other plants, mostly conifers, produced by heating fresh liquid resin to vaporize the volatile liquid terpene components. It is semi-transparent and varies in color from yellow to black. At room temperature rosin is brittle, but it melts at stove-top temperature. It chiefly consists of various resin acids, especially abietic acid. The term ''colophony'' comes from , Latin for "resin from Colophon" ( grc, Κολοφωνία ῥητίνη, Kolophōnia rhētinē), an ancient Ionic city. Properties Rosin is brittle and friable, with a faint piny odor. It is typically a glassy solid, though some rosins will form crystals, especially when brought into solution. The practical melting point varies with different specimens, some being semi-fluid at the temperature of boiling water, others melting at 100 °C to 120 °C. It is very flammable, burni ...
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Resin Acid
Resin acid refers to mixtures of several related carboxylic acids, primarily abietic acid, found in tree resins. Nearly all resin acids have the same basic skeleton: three fused rings having the empirical formula C19H29COOH. Resin acids are tacky, yellowish gums that are water-insoluble. They are used to produce soaps for diverse applications, but their use is being displaced increasingly by synthetic acids such as 2-ethylhexanoic acid or petroleum-derived naphthenic acids. Botanical analysis Resin acids are protectants and wood preservatives that are produced by parenchymatous epithelial cells that surround the resin ducts in trees from temperate coniferous forests. The resin acids are formed when two-carbon and three-carbon molecules couple with isoprene building units to form monoterpenes (volatile), sesquiterpenes (volatile), and diterpenes (nonvolatile) structures. Pines contain numerous vertical and radial resin ducts scattered throughout the entire wood. The accumulation ...
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Cadinene
Cadinenes are a group of isomeric hydrocarbons that occur in a wide variety of essential oil-producing plants. The name is derived from that of the Cade juniper (''Juniperus oxycedrus'' L.), the wood of which yields an oil from which cadinene isomers were first isolated. Chemically, the cadinenes are bicyclic sesquiterpenes. The term ''cadinene'' has sometimes also been used in a broad sense to refer to any sesquiterpene with the so-called cadalane (4-isopropyl-1,6-dimethyldecahydronaphthalene) carbon skeleton. Because of the large number of known double-bond and stereochemical isomers, this class of compounds has been subdivided into four subclasses based on the relative stereochemistry at the isopropyl group and the two bridgehead carbon atoms. The name ''cadinene'' is now properly used only for the first subclass below, which includes the compounds originally isolated from cade oil. Only one enantiomer In chemistry, an enantiomer ( /ɪˈnænti.əmər, ɛ-, -oʊ-/ ...
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Caryophyllene
Caryophyllene (), more formally (−)-β-caryophyllene, (BCP), is a natural bicyclic sesquiterpene that is a constituent of many essential oils, especially clove oil, the oil from the stems and flowers of '' Syzygium aromaticum'' (cloves), the essential oil of ''Cannabis sativa'', rosemary, and hops. It is usually found as a mixture with isocaryophyllene (the ''cis'' double bond isomer) and α-humulene (obsolete name: α-caryophyllene), a ring-opened isomer. Caryophyllene is notable for having a cyclobutane ring, as well as a ''trans''-double bond in a 9-membered ring, both rarities in nature. β-Caryophyllene acts as a full agonist of the Cannabinoid receptor type 2 (CB2 receptor) in rats. β-Caryophyllene has a binding affinity of Ki = 155nM at the CB2 receptors in mice. β-Caryophyllene has been shown to have anti-inflammatory action linked to its CB2 receptor activity in a study comparing the pain killing effects in mice with and without CB2 receptors with the group of mice w ...
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