Rare Earth Mineral
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Rare Earth Mineral
A rare-earth mineral contains one or more rare-earth elements as major metal constituents. Rare-earth minerals are usually found in association with alkaline to peralkaline igneous complexes, in pegmatites associated with alkaline magmas and in or associated with carbonatite intrusives. Perovskite mineral phases are common hosts to rare-earth elements within the alkaline complexes. Mantle-derived carbonate melts are also carriers of the rare earths. Hydrothermal deposits associated with alkaline magmatism contain a variety of rare-earth minerals. The following includes the relatively common hydrothermal rare-earth minerals and minerals that often contain significant rare-earth substitution: *Aeschynite-( Y or Ce) *allanite *apatite *bastnäsite *britholite * brockite *cerite * Dollaseite-(Ce) *fluocerite *fluorite * gadolinite *monazite *parisite-( Ce or La) *stillwellite *synchysite *titanite *wakefieldite *xenotime *zircon Zircon () is a mineral belonging to the grou ...
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Britholite
Britholite-(Ce) is a rare radioactive mineral with the chemical formula (Ce,Ca)(SiO)OH. It comes in a variety of different colors. Its type locality is Naujakasik (Naajakasik), Tunulliarfik Fjord, Ilímaussaq complex, Narsaq, Kujalleq, Greenland. Discovery The mineral was first discovered by Gustaf Flink in 1897 inside a nepheline-syenite at Naujakasik, Ilímaussaq complex, Greenland. It was named after the Greek word βρῖθος (''brithos'') which means "weight" referring to its high specific gravity, it was later named birtholite-(Ce) due to the high amounts of cerium Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 ... in its composition. References External links"Britholite-(Ce) Mineral Data" Minerals Hexagonal minerals Minerals in space group 176 Radioactive ...
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Wakefieldite
Wakefieldite () is an uncommon rare-earth element vanadate mineral. There are four main types described of wakefieldite- wakefieldite-(La), wakefieldite-(Ce), wakefieldite-(Nd), and wakefieldite-(Y), depending upon the dominant rare-earth metal ion present. Wakefieldite has a Mohs hardness ranging from 4 to 5. Wakefieldite forms crystals of tetragonal structure. In terms of crystal structure, it is the vanadate analog of the rare-earth phosphate mineral xenotime. Unlike xenotime, it is more favorable for wakefieldite to contain the lighter rare-earth elements over the heavier ones. Due to the lanthanide contraction, the heavier rare earths have smaller ionic radii than the lighter ones. When the phosphate anion is replaced by the larger vanadate anion, the tetragonal crystal system preferentially accommodates the larger light rare-earth elements. Wakefieldite was first described for an occurrence in the Evans Lou mine, St. Pierre de Wakefield, Quebec, Canada Canada ...
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Titanite
Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly replaced by thorium. Nomenclature The International Mineralogical Association Commission on New Minerals and Mineral Names (CNMMN) adopted the name titanite and "discredited" the name sphene as of 1982, although commonly papers and books initially identify the mineral using both names. Sphene was the most commonly used name until the IMA decision, although both were well known. Some authorities think it is less confusing as the word is used to describe any chemical or crystal with oxidized titanium such as the rare earth titanate pyrochlores series and many of the minerals with the perovskite structure. The name sphene continues to be publishable in peer-reviewed scientific literature, e.g ...
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Synchysite
Synchysite is a group of carbonate minerals. The three isostructural chemical end members are synchysite-(Ce), synchysite-(Nd) and synchysite-(Y). Huanghoite-(Ce) belongs to the group, but has a different symmetry and calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ... is replaced by barium. References {{Reflist Carbonate minerals Monoclinic minerals Minerals in space group 15 ...
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Stillwellite
Stillwellite-(Ce) is a rare-earth boro-silicate mineral with chemical formula . Location It occurs as a metasomatic replacement of metamorphosed limestones in the Mary Kathleen mine, Australia and in alkalic pegmatites associated with syenite in an alkaline massif in Tajikistan. It occurs in association with allanite, garnet, uraninite in the Australian deposit; with calcite, monazite, bastnasite, thorite, uranothorite and thorianite in the Desmont mine, Wilberforce, Ontario, Canada; and with pyrochlore, tienshanite, sogdianite, thorite, caesium kupletskite, reedmergnerite, steacyite, pectolite and quartz in the Tajikistan deposit. It has also been reported from Mont Saint-Hilaire, Quebec, Canada and from Mineville, Essex County, New York. Other occurrences include the Inagli massif, Yakutia, Russia, around Langesundsfjord, Norway, in the Ilimaussaq intrusive complex, southern Greenland and the Vico volcano, Lazio, Italy. Discovery It was first described in 1955 ...
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Parisite-(La)
Parisite-(La) is mineral discovered by Daniel Atencio of the University of São Paulo and colleagues in the Mula claim, Bahia, Brazil. Parisite-(La) is the lanthanum analog of parisite-(Ce), which has the same structure, but with cerium substituted for lanthanum. Parisite-(La) is chemically similar to synchysite-(La). The type material for parisite-(La) resides in the mineralogical collections of the Museu de Ciência e Técnica, Escola de Minas, Universidade Federal de Ouro Preto, Minas Gerais, Brazil, and at the University of Arizona Mineral Museum, Tucson, Arizona. Localities Brazil Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...: Mula claim, Tapera, Novo Horizonte, Bahia References {{carbonate-mineral-stub Carbonate minerals Monoclinic minerals ...
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Parisite-(Ce)
Parisite is a rare mineral consisting of cerium, lanthanum and calcium fluoro-carbonate, . Parisite is mostly parisite-(Ce), but when neodymium is present in the structure the mineral becomes parisite-(Nd). It is found only as crystals, which belong to the trigonal or monoclinic pseudo-hexagonal system and usually have the form of acute double pyramids terminated by the basal planes; the faces of the hexagonal pyramids are striated horizontally, and parallel to the basal plane there is a perfect cleavage. The crystals are hair-brown in color and are translucent. The hardness is 4.5 and the specific gravity is 4.36. Light which has traversed a crystal of parisite exhibits a characteristic absorption spectrum. At first, the only known occurrence of this mineral was in the famous emerald mine at Muzo in Colombia, South America, where it was found by J.J. Paris, who rediscovered and worked the mine in the early part of the 19th century; here it is associated with emerald in a bitu ...
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Monazite
Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the cerium-dominant member of the group. It occurs usually in small isolated crystals. It has a hardness of 5.0 to 5.5 on the Mohs scale of mineral hardness and is relatively dense, about 4.6 to 5.7 g/cm3. There are five different most common species of monazite, depending on the relative amounts of the rare earth elements in the mineral: * monazite-(Ce), ( Ce, La, Nd, Th) PO4 (the most common member), * monazite-(La), (La,Ce,Nd)PO4, * monazite-(Nd), (Nd,La,Ce)PO4, * monazite-(Sm), ( Sm, Gd,Ce,Th)PO4, * monazite-(Pr), ( Pr,Ce,Nd,Th)PO4. The elements in parentheses are listed in the order of their relative proportion within the mineral: lanthanum is the most common rare-earth element in monazite-(La), and so forth. Silica (SiO2) is present in trace a ...
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Gadolinite
Gadolinite, sometimes known as ytterbite, is a silicate mineral consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with the formula . It is called gadolinite-(Ce) or gadolinite-(Y), depending on the prominent composing element (Y if yttrium predominates, and Ce if cerium). It may contain 35.5% yttria sub-group rare earths, 2.2% ceria earths, as much as to 11.6% BeO, and traces of thorium. It is found in Sweden, Norway, and the US (Texas and Colorado). Characteristics Gadolinite is fairly rare and typically occurs as well-formed crystals. It is nearly black in color and has a vitreous luster. The hardness is between 6.5 and 7 on the Mohs scale, and the specific gravity is between 4.0 and 4.7. It fractures in a conchoidal pattern and streaks grayish-green. It was also thought to exhibit pyrognomic properties, as it can emit visible light when heated to relatively low temperatures, but the scientific consensus is that this is the p ...
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Fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scale of mineral hardness, based on scratch hardness comparison, defines value 4 as fluorite. Pure fluorite is colourless and transparent, both in visible and ultraviolet light, but impurities usually make it a colorful mineral and the stone has ornamental and lapidary uses. Industrially, fluorite is used as a flux for smelting, and in the production of certain glasses and enamels. The purest grades of fluorite are a source of fluoride for hydrofluoric acid manufacture, which is the intermediate source of most fluorine-containing fine chemicals. Optically clear transparent fluorite lenses have low dispersion, so lenses made from it exhibit less chromatic aberration, making them valuable in microscopes and telescopes. Fluorite optics are also ...
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Fluocerite
Fluocerite, also known as tysonite, is a mineral consisting of cerium and lanthanum fluorides, with the chemical formula . The end members are classified as two different mineral types depending on the cation, fluocerite-(Ce) and fluocerite-(La), corresponding respectively to lanthanum trifluoride and cerium trifluoride. Both crystallize in the trigonal system. Fluocerite-(Ce) was first described (without the Ce) in 1845 from hydrothermal veins in granite in Sweden. Fluocerite-(La) was first described in 1969 from the type locality in central Kazakhstan. The name tysonite was given in 1880 to the same type of mineral found in Colorado. Tysonite-type structure is used for rare-earth fluorides with the P3c1 space group In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it uncha ... structure ...
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