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Plutonium-241
Plutonium-241 (241Pu or Pu-241) is an isotope of plutonium formed when plutonium-240 captures a neutron. Like some other plutonium isotopes (especially 239Pu), 241Pu is fissile, with a neutron absorption cross section about one-third greater than that of 239Pu, and a similar probability of fissioning on neutron absorption, around 73%. In the non-fission case, neutron capture produces plutonium-242. In general, isotopes with an odd number of neutrons are both more likely to absorb a neutron, and more likely to undergo fission on neutron absorption, than isotopes with an even number of neutrons. Decay to americium 241Pu has a half-life of 14 years, corresponding to a decay of about 5% of 241Pu nuclei over a one-year period. The longer spent nuclear fuel waits before reprocessing, the more 241Pu decays to americium-241, which is nonfissile (although fissionable by fast neutrons) and an alpha emitter with a halflife of 432 years; 241Am is a major contributor to the radioact ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium
Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous. Plutonium was first synthetically produced and isolated in late 1940 and early 1941, by a deuteron bombardment of uranium-238 in the cyclotron at the University of California, Berkeley. First, neptunium-238 ( half-life 2.1 days) was synthesized, which subsequently beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isotopes Of Plutonium
Plutonium (94Pu) is an artificial element, except for trace quantities resulting from neutron capture by uranium, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was synthesized long before being found in nature, the first isotope synthesized being 238Pu in 1940. Twenty plutonium radioisotopes have been characterized. The most stable are plutonium-244 with a half-life of 80.8 million years, plutonium-242 with a half-life of 373,300 years, and plutonium-239 with a half-life of 24,110 years. All of the remaining radioactive isotopes have half-lives that are less than 7,000 years. This element also has eight meta states; all have half-lives of less than one second. The isotopes of plutonium range in atomic weight from 228.0387 u (228Pu) to 247.074 u (247Pu). The primary decay modes before the most stable isotope, 244Pu, are spontaneous fission and alpha emission; the primary mode after is beta emission. The p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium-240
Plutonium-240 ( or Pu-240) is an isotope of plutonium formed when plutonium-239 captures a neutron. The detection of its spontaneous fission led to its discovery in 1944 at Los Alamos and had important consequences for the Manhattan Project. 240Pu undergoes spontaneous fission as a secondary decay mode at a small but significant rate. The presence of 240Pu limits plutonium's use in a nuclear bomb, because the neutron flux from spontaneous fission initiates the chain reaction prematurely, causing an early release of energy that physically disperses the core before full implosion is reached. It decays by alpha emission to uranium-236. Nuclear properties About 62% to 73% of the time when 239Pu captures a neutron, it undergoes fission; the remainder of the time, it forms 240Pu. The longer a nuclear fuel element remains in a nuclear reactor, the greater the relative percentage of 240Pu in the fuel becomes. The isotope 240Pu has about the same thermal neutron capture cross sect ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium-242
Plutonium-242 (242Pu or Pu-242) is one of the isotopes of plutonium, the second longest-lived, with a half-life of 375,000 years. The half-life of 242Pu is about 15 times that of 239Pu; so it is one-fifteenth as radioactive, and not one of the larger contributors to nuclear waste radioactivity. 242Pu's gamma ray emissions are also weaker than those of the other isotopes. It is not fissile (but it is fissionable by fast neutrons) and its neutron capture cross section is also low. In the nuclear fuel cycle Plutonium-242 is produced by successive neutron capture on 239Pu, 240Pu, and 241Pu. The odd-mass isotopes 239Pu and 241Pu have about a 3/4 chance of undergoing fission on capture of a thermal neutron and about a 1/4 chance of retaining the neutron and becoming the following isotope. The proportion of 242Pu is low at low burnup but increases nonlinearly. Plutonium-242 has a particularly low cross section for thermal neutron capture; and it takes three neutron absorptions to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spent Nuclear Fuel
Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and depending on its point along the nuclear fuel cycle, it may have considerably different isotopic constituents. The term "fuel" is slightly confusing, as it implies a combustion of some type, which does not occur in a nuclear power plant. Nevertheless, this term is generally accepted. Nature of spent fuel Nanomaterial properties In the oxide fuel, intense temperature gradients exist that cause fission products to migrate. The zirconium tends to move to the centre of the fuel pellet where the temperature is highest, while the lower-boiling fission products move to the edge of the pellet. The pellet is likely to contain many small bubble-like pores that form during use; the fission product xenon migrates to these voids. Some of this xen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Americium-241
Americium-241 (, Am-241) is an isotope of americium. Like all isotopes of americium, it is radioactive, with a half-life of . is the most common isotope of americium as well as the most prevalent isotope of americium in nuclear waste. It is commonly found in ionization type smoke detectors and is a potential fuel for long-lifetime radioisotope thermoelectric generators (RTGs). Its common parent nuclides are β− from , EC from , and α from . is fissile and the critical mass of a bare sphere is and a sphere diameter of . Americium-241 has a specific activity of . It is commonly found in the form of americium-241 dioxide (). This isotope also has one meta state, , with an excitation energy of and a half-life of . The presence of americium-241 in plutonium is determined by the original concentration of plutonium-241 and the sample age. Because of the low penetration of alpha radiation, americium-241 only poses a health risk when ingested or inhaled. Older samples of pluton ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Waste
Radioactive waste is a type of hazardous waste that contains radioactive material. Radioactive waste is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, rare-earth mining, and nuclear weapons reprocessing. The storage and disposal of radioactive waste is regulated by government agencies in order to protect human health and the environment. Radioactive waste is broadly classified into low-level waste (LLW), such as paper, rags, tools, clothing, which contain small amounts of mostly short-lived radioactivity, intermediate-level waste (ILW), which contains higher amounts of radioactivity and requires some shielding, and high-level waste (HLW), which is highly radioactive and hot due to decay heat, so requires cooling and shielding. In nuclear reprocessing plants about 96% of spent nuclear fuel is recycled back into uranium-based and mixed-oxide (MOX) fuels. The residual 4% is minor actinides and fission products the latter of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Valence (chemistry)
In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Description The combining capacity, or affinity of an atom of a given element is determined by the number of hydrogen atoms that it combines with. In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; and in hydrogen chloride, chlorine has a valence of 1. Chlorine, as it has a valence of one, can be substituted for hydrogen. Phosphorus has a valence of 5 in phosphorus pentachloride, . Valence diagrams of a compound represent the connectivity of the elements, with lines drawn between two elements, sometimes called bonds, representing a saturated valency for each element. The two tables below show some examples of different compounds, their valence diagrams, and the valences for each element of the compound. Modern definition ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electronegativity
Electronegativity, symbolized as , is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond. An atom's electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity, the more an atom or a substituent group attracts electrons. Electronegativity serves as a simple way to quantitatively estimate the bond energy, and the sign and magnitude of a bond's chemical polarity, which characterizes a bond along the continuous scale from covalent to ionic bonding. The loosely defined term electropositivity is the opposite of electronegativity: it characterizes an element's tendency to donate valence electrons. On the most basic level, electronegativity is determined by factors like the nuclear charge (the more protons an atom has, the more "pull" it will have on electrons) and the number and locat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Neptunium
Neptunium is a chemical element with the symbol Np and atomic number 93. A radioactive actinide metal, neptunium is the first transuranic element. Its position in the periodic table just after uranium, named after the planet Uranus, led to it being named after Neptune, the next planet beyond Uranus. A neptunium atom has 93 protons and 93 electrons, of which seven are valence electrons. Neptunium metal is silvery and tarnishes when exposed to air. The element occurs in three allotropic forms and it normally exhibits five oxidation states, ranging from +3 to +7. It is radioactive, poisonous, pyrophoric, and capable of accumulating in bones, which makes the handling of neptunium dangerous. Although many false claims of its discovery were made over the years, the element was first synthesized by Edwin McMillan and Philip H. Abelson at the Berkeley Radiation Laboratory in 1940. Since then, most neptunium has been and still is produced by neutron irradiation of uranium in nuclea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Synthetic Radioisotope
A synthetic radioisotope is a radionuclide that is not found in nature: no natural process or mechanism exists which produces it, or it is so unstable that it decays away in a very short period of time. Examples include technetium-95 and promethium-146. Many of these are found in, and harvested from, spent nuclear fuel assemblies. Some must be manufactured in particle accelerators. Production Some synthetic radioisotopes are extracted from spent nuclear reactor fuel rods, which contain various fission products. For example, it is estimated that up to 1994, about 49,000 terabecquerels (78 metric ton) of technetium was produced in nuclear reactors, which is by far the dominant source of terrestrial technetium. Some synthetic isotopes are produced in significant quantities by fission but are not yet being reclaimed. Other isotopes are manufactured by neutron irradiation of parent isotopes in a nuclear reactor (for example, Tc-97 can be made by neutron irradiation of Ru-96) or by b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium
Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weakly radioactive because all isotopes of uranium are unstable; the half-lives of its naturally occurring isotopes range between 159,200 years and 4.5 billion years. The most common isotopes in natural uranium are uranium-238 (which has 146 neutrons and accounts for over 99% of uranium on Earth) and uranium-235 (which has 143 neutrons). Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead, and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite. In nature, uranium is found as uranium-238 (99. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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