|
Particle In A Ring
In quantum mechanics, the case of a particle in a one-dimensional ring is similar to the particle in a box. The Schrödinger equation for a free particle which is restricted to a ring (technically, whose configuration space is the circle S^1) is : -\frac\nabla^2 \psi = E\psi Wave function Using polar coordinates on the 1-dimensional ring of radius R, the wave function depends only on the angular coordinate, and so Problems and Solutions to accompany Physical Chemistry: a Molecular Approach : \nabla^2 = \frac \frac Requiring that the wave function be periodic in \ \theta with a period 2 \pi (from the demand that the wave functions be single-valued functions on the circle), and that they be normalized leads to the conditions : \int_^ \left, \psi ( \theta ) \^2 \, d\theta = 1\ , and : \ \psi (\theta) = \ \psi ( \theta + 2\pi) Under these conditions, the solution to the Schrödinger equation is given by : \psi_(\theta) = \frac\, e^ Energy eigenvalues The energy e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantization (physics)
In physics, quantization (in British English quantisation) is the systematic transition procedure from a classical understanding of physical phenomena to a newer understanding known as quantum mechanics. It is a procedure for constructing quantum mechanics from classical mechanics. A generalization involving infinite degrees of freedom is field quantization, as in the "quantization of the electromagnetic field", referring to photons as field " quanta" (for instance as light quanta). This procedure is basic to theories of atomic physics, chemistry, particle physics, nuclear physics, condensed matter physics, and quantum optics. Historical overview In 1901, when Max Planck was developing the distribution function of statistical mechanics to solve ultraviolet catastrophe problem, he realized that the properties of blackbody radiation can be explained by the assumption that the amount of energy must be in countable fundamental units, i.e. amount of energy is not continuous b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benzene
Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, benzene is classed as a hydrocarbon. Benzene is a natural constituent of petroleum and is one of the elementary petrochemicals. Due to the cyclic continuous pi bonds between the carbon atoms, benzene is classed as an aromatic hydrocarbon. Benzene is a colorless and highly flammable liquid with a sweet smell, and is partially responsible for the aroma of gasoline. It is used primarily as a precursor to the manufacture of chemicals with more complex structure, such as ethylbenzene and cumene, of which billions of kilograms are produced annually. Although benzene is a major industrial chemical, it finds limited use in consumer items because of its toxicity. History Discovery The word "''benzene''" derives from "''gum benzoin''" (benzoin res ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aromatic
In chemistry, aromaticity is a chemical property of cyclic ( ring-shaped), ''typically'' planar (flat) molecular structures with pi bonds in resonance (those containing delocalized electrons) that gives increased stability compared to saturated compounds having single bonds, and other geometric or connective non-cyclic arrangements with the same set of atoms. Aromatic rings are very stable and do not break apart easily. Organic compounds that are not aromatic are classified as aliphatic compounds—they might be cyclic, but only aromatic rings have enhanced stability. The term ''aromaticity'' with this meaning is historically related to the concept of having an aroma, but is a distinct property from that meaning. Since the most common aromatic compounds are derivatives of benzene (an aromatic hydrocarbon common in petroleum and its distillates), the word ''aromatic'' occasionally refers informally to benzene derivatives, and so it was first defined. Nevertheless, many ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Chemistry
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J.; Greeves, N. and Warren, S. (2012) ''Organic Chemistry''. Oxford University Press. pp. 1–15. . Study of structure determines their structural formula. Study of properties includes physical and chemical properties, and evaluation of chemical reactivity to understand their behavior. The study of organic reactions includes the chemical synthesis of natural products, drugs, and polymers, and study of individual organic molecules in the laboratory and via theoretical ( in silico) study. The range of chemicals studied in organic chemistry includes hydrocarbons (compounds containing only carbon and hydrogen) as well as compounds based on carbon, but also containing other elements, especially oxygen, nitrogen, sulfur, phosphorus (included in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fourier Series
A Fourier series () is a summation of harmonically related sinusoidal functions, also known as components or harmonics. The result of the summation is a periodic function whose functional form is determined by the choices of cycle length (or ''period''), the number of components, and their amplitudes and phase parameters. With appropriate choices, one cycle (or ''period'') of the summation can be made to approximate an arbitrary function in that interval (or the entire function if it too is periodic). The number of components is theoretically infinite, in which case the other parameters can be chosen to cause the series to converge to almost any ''well behaved'' periodic function (see Pathological and Dirichlet–Jordan test). The components of a particular function are determined by ''analysis'' techniques described in this article. Sometimes the components are known first, and the unknown function is ''synthesized'' by a Fourier series. Such is the case of a discrete-ti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fourier Theorem
A Fourier series () is a summation of harmonically related sinusoidal functions, also known as components or harmonics. The result of the summation is a periodic function whose functional form is determined by the choices of cycle length (or ''period''), the number of components, and their amplitudes and phase parameters. With appropriate choices, one cycle (or ''period'') of the summation can be made to approximate an arbitrary function in that interval (or the entire function if it too is periodic). The number of components is theoretically infinite, in which case the other parameters can be chosen to cause the series to converge to almost any ''well behaved'' periodic function (see Pathological and Dirichlet–Jordan test). The components of a particular function are determined by ''analysis'' techniques described in this article. Sometimes the components are known first, and the unknown function is ''synthesized'' by a Fourier series. Such is the case of a discrete-ti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Superposition
Quantum superposition is a fundamental principle of quantum mechanics. It states that, much like waves in classical physics, any two (or more) quantum states can be added together ("superposed") and the result will be another valid quantum state; and conversely, that every quantum state can be represented as a sum of two or more other distinct states. Mathematically, it refers to a property of solutions to the Schrödinger equation; since the Schrödinger equation is linear, any linear combination of solutions will also be a solution(s) . An example of a physically observable manifestation of the wave nature of quantum systems is the interference peaks from an electron beam in a double-slit experiment. The pattern is very similar to the one obtained by diffraction of classical waves. Another example is a quantum logical qubit state, as used in quantum information processing, which is a quantum superposition of the "basis states" , 0 \rangle and , 1 \rangle . Here , 0 \r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eigenfunction
In mathematics, an eigenfunction of a linear operator ''D'' defined on some function space is any non-zero function f in that space that, when acted upon by ''D'', is only multiplied by some scaling factor called an eigenvalue. As an equation, this condition can be written as Df = \lambda f for some scalar eigenvalue \lambda. The solutions to this equation may also be subject to boundary conditions that limit the allowable eigenvalues and eigenfunctions. An eigenfunction is a type of eigenvector. Eigenfunctions In general, an eigenvector of a linear operator ''D'' defined on some vector space is a nonzero vector in the domain of ''D'' that, when ''D'' acts upon it, is simply scaled by some scalar value called an eigenvalue. In the special case where ''D'' is defined on a function space, the eigenvectors are referred to as eigenfunctions. That is, a function ''f'' is an eigenfunction of ''D'' if it satisfies the equation where λ is a scalar. The solutions to Equation may also ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Azimuth
An azimuth (; from ar, اَلسُّمُوت, as-sumūt, the directions) is an angular measurement in a spherical coordinate system. More specifically, it is the horizontal angle from a cardinal direction, most commonly north. Mathematically, the relative position vector from an observer (origin) to a point of interest is projected perpendicularly onto a reference plane (the horizontal plane); the angle between the projected vector and a reference vector on the reference plane is called the azimuth. When used as a celestial coordinate, the azimuth is the horizontal direction of a star or other astronomical object in the sky. The star is the point of interest, the reference plane is the local area (e.g. a circular area with a 5 km radius at sea level) around an observer on Earth's surface, and the reference vector points to true north. The azimuth is the angle between the north vector and the star's vector on the horizontal plane. Azimuth is usually measured in d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Nucleus
The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment. After the discovery of the neutron in 1932, models for a nucleus composed of protons and neutrons were quickly developed by Dmitri Ivanenko and Werner Heisenberg. An atom is composed of a positively charged nucleus, with a cloud of negatively charged electrons surrounding it, bound together by electrostatic force. Almost all of the mass of an atom is located in the nucleus, with a very small contribution from the electron cloud. Protons and neutrons are bound together to form a nucleus by the nuclear force. The diameter of the nucleus is in the range of () for hydrogen (the diameter of a single proton) to about for uranium. These dimensions are much smaller than the diameter of the atom itself (nucleus + electron cloud), by a factor of about 26,634 (uranium atomic radiu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no known components or substructure. The electron's mass is approximately 1/1836 that of the proton. Quantum mechanical properties of the electron include an intrinsic angular momentum ( spin) of a half-integer value, expressed in units of the reduced Planck constant, . Being fermions, no two electrons can occupy the same quantum state, in accordance with the Pauli exclusion principle. Like all elementary particles, electrons exhibit properties of both particles and waves: They can collide with other particles and can be diffracted like light. The wave properties of electrons are easier to observe with experiments than those of other particles like neutrons and protons because electrons have a lower mass and hence a longer de Broglie wavele ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
2.png "Click for more on -> Benzene")
.png "Click for more on -> Aromatic")
