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Proton Conductor
A proton conductor is an electrolyte, typically a solid electrolyte, in which H+ are the primary charge carriers. Composition Acid solutions exhibit proton-conductivity, while pure proton conductors are usually dry solids. Typical materials are polymers or ceramic. Typically, the pores in practical materials are small such that protons dominate direct current and transport of cations or bulk solvent is prevented. Water ice is a common example of a pure proton conductor, albeit a relatively poor one. A special form of water ice, superionic water, has been shown to conduct much more efficiently than normal water ice. Solid-phase proton conduction was first suggested by Alfred Rene Jean Paul Ubbelohde and S. E. Rogers. in 1950, although electrolyte proton currents have been recognized since 1806. Proton conduction has also been observed in the new type of proton conductors for fuel cells – protic organic ionic plastic crystals (POIPCs), such as 1,2,4-triazolium perfluorobutan ...
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Superionic Ice Conducting
Superionic water, also called superionic ice or ice XVIII is a phase of water that exists at extremely high temperatures and pressures. In superionic water, water molecules break apart and the oxygen ions crystallize into an evenly spaced lattice while the hydrogen ions float around freely within the oxygen lattice.Weird water lurking inside giant planets
New Scientist,01 September 2010, Magazine issue 2776.
The freely mobile hydrogen ions make superionic water almost as as typical metals, making it a
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Energy & Environmental Science
''Energy & Environmental Science'' is a monthly peer-reviewed scientific journal publishing original (primary) research and review articles. The journal covers work of an interdisciplinary nature in the biochemical and biophysical sciences and chemical and mechanical engineering disciplines. It covers energy area. ''Energy & Environmental Science'' is published by the Royal Society of Chemistry and the editor-in-chief is Joseph Hupp (Northwestern University, USA). According to the ''Journal Citation Reports'', the journal has a 2017 impact factor of 30.067, ranking it 4th out of 163 journals in the category "Chemistry, Multidisciplinary", first out of 88 journals in the category "Energy & Fuels", first out of 135 journals in the category "Engineering, Chemical", and first among 225 journals in the category "Environmental Sciences". Article types ''Energy & Environmental Science'' publishes the following types of articles: Research Papers (original scientific work); Review Artic ...
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Zirconate
A zirconate is an oxyanion containing zirconium. Examples include Na2ZrO3, Ca2ZrO3 which can be prepared by fusing zirconium dioxide Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabi ... with e.g. Na2O and CaO respectively. References Oxometallates {{chemistry-stub ...
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Science Advances
''Science Advances'' is a peer-reviewed multidisciplinary open-access scientific journal established in early 2015 and published by the American Association for the Advancement of Science. The journal's scope includes all areas of science, including life sciences, physical sciences, social sciences Social science is one of the branches of science, devoted to the study of societies and the relationships among individuals within those societies. The term was formerly used to refer to the field of sociology, the original "science of so ..., computer sciences, and environmental sciences. History The journal was announced in February 2014, and the first articles were published in early 2015. In 2019, ''Science Advances'' surpassed Science (journal), ''Science magazine'' in the number of monthly submissions, becoming the largest member in the Science family of journals. It is the only member of that family where all papers are gold open access. Editorial structure Editori ...
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The Washington Post
''The Washington Post'' (also known as the ''Post'' and, informally, ''WaPo'') is an American daily newspaper published in Washington, D.C. It is the most widely circulated newspaper within the Washington metropolitan area and has a large national audience. Daily broadsheet editions are printed for D.C., Maryland, and Virginia. The ''Post'' was founded in 1877. In its early years, it went through several owners and struggled both financially and editorially. Financier Eugene Meyer purchased it out of bankruptcy in 1933 and revived its health and reputation, work continued by his successors Katharine and Phil Graham (Meyer's daughter and son-in-law), who bought out several rival publications. The ''Post'' 1971 printing of the Pentagon Papers helped spur opposition to the Vietnam War. Subsequently, in the best-known episode in the newspaper's history, reporters Bob Woodward and Carl Bernstein led the American press's investigation into what became known as the Watergate scandal ...
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Ampullae Of Lorenzini
Ampullae of Lorenzini (singular ''Ampulla'') are electroreceptors, sense organs able to detect electric fields. They form a network of mucus-filled pores in the skin of cartilaginous fish (sharks, rays, and chimaeras) and of basal actinopterygians (bony fishes) such as reedfish, sturgeon, and lungfish. They are associated with and evolved from the mechanosensory lateral line organs of early vertebrates. Most bony fishes and terrestrial vertebrates have lost their ampullae of Lorenzini. History Ampullae were initially described by Marcello Malpighi and later given an exact description by the Italian physician and ichthyologist Stefano Lorenzini in 1679, though their function was unknown. Electrophysiological experiments in the 20th century suggested a sensibility to temperature, mechanical pressure, and possibly salinity. In 1960 the ampullae were identified as specialized receptor organs for sensing electric fields. One of the first descriptions of calcium-activated potassium ...
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Nafion
Nafion is a brand name for a sulfonated tetrafluoroethylene based fluoropolymer-copolymer discovered in the late 1960s by Dr. Walther Grot of DuPont. Nafion is a brand of the Chemours company. It is the first of a class of synthetic polymers with ionic properties that are called ionomers. Nafion's unique ionic properties are a result of incorporating perfluorovinyl ether groups terminated with sulfonate groups onto a tetrafluoroethylene (PTFE) backbone. Nafion has received a considerable amount of attention as a proton conductor for proton exchange membrane (PEM) fuel cells because of its excellent chemical and mechanical stability in the harsh conditions of this application. The chemical basis of Nafion's ion-conductive properties remain a focus of extensive research. Ion conductivity of Nafion increases with the level of hydration. Exposure of Nafion to a humidified environment or liquid water increases the amount of water molecules associated with each sulfonic acid group. The ...
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Proton Exchange Membrane Fuel Cell
A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ratio). Protons and neutrons, each with masses of approximately one atomic mass unit, are jointly referred to as "nucleons" (particles present in atomic nuclei). One or more protons are present in the Atomic nucleus, nucleus of every atom. They provide the attractive electrostatic central force which binds the atomic electrons. The number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number (represented by the symbol ''Z''). Since each chemical element, element has a unique number of protons, each element has its own unique atomic number, which determines the number of atomic electrons and consequently the chemical characteristics of the element. The word ''proton'' is Greek language, G ...
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Proton Exchange Membrane
A proton-exchange membrane, or polymer-electrolyte membrane (PEM), is a semipermeable membrane generally made from ionomers and designed to conduct protons while acting as an electronic insulator and reactant barrier, e.g. to oxygen and hydrogen gas. This is their essential function when incorporated into a membrane electrode assembly (MEA) of a proton-exchange membrane fuel cell or of a proton-exchange membrane electrolyser: separation of reactants and transport of protons while blocking a direct electronic pathway through the membrane. PEMs can be made from either pure polymer membranes or from composite membranes, where other materials are embedded in a polymer matrix. One of the most common and commercially available PEM materials is the fluoropolymer (PFSA) Nafion, a DuPont product. While Nafion is an ionomer with a perfluorinated backbone like Teflon, there are many other structural motifs used to make ionomers for proton-exchange membranes. Many use polyaromatic polymers, ...
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Journal Of Materials Chemistry A
The ''Journal of Materials Chemistry A'' is a weekly peer-reviewed scientific journal that covers the synthesis, properties, and applications of novel materials related to energy and sustainability. It is one of three journals created after the ''Journal of Materials Chemistry'' was split at the end of 2012. Its first issue was published in January 2013. The journal is published by the Royal Society of Chemistry and has two sister journals, '' Journal of Materials Chemistry B'' and ''Journal of Materials Chemistry C'', which cover different materials science topics. The editor-in-chief for the ''Journal of Materials Chemistry'' family of journals is currently Nazario Martin. The deputy editor-in-chief for ''Journal of Materials Chemistry A'' is Anders Hagfeldt, while the executive editor is Michaela Mühlberg. Abstracting and indexing The journal is abstracted and indexed in the Science Citation Index Expanded, Current Contents/Physical, Chemical & Earth Sciences, and Current Cont ...
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Imidazolium
Imidazole (ImH) is an organic compound with the formula C3N2H4. It is a white or colourless solid that is soluble in water, producing a mildly alkaline solution. In chemistry, it is an aromatic heterocycle, classified as a diazole, and has non-adjacent nitrogen atoms in meta-substitution. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. This ring system is present in important biological building blocks, such as histidine and the related hormone histamine. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam. When fused to a pyrimidine ring, it forms a purine, which is the most widely occurring nitrogen-containing heterocycle in nature. The name "imidazole" was coined in 1887 by the German chemist Arthur Rudolf Hantzsch (1857–1935). Structure and properties Imidazole is a planar 5-membered ri ...
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Plastic Crystal
A plastic crystal is a crystal composed of weakly interacting molecules that possess some orientational or conformational degree of freedom. The name plastic crystal refers to the mechanical softness of such phases: they resemble waxes and are easily deformed. If the internal degree of freedom is molecular rotation, the name rotor phase or rotatory phase is also used. Typical examples are the modifications Methane I and Ethane I. In addition to the conventional molecular plastic crystals, there are also emerging ionic plastic crystals, particularly organic ionic plastic crystals (OIPCs) and protic organic ionic plastic crystals (POIPCs). POIPCs are solid protic organic salts formed by proton transfer from a Brønsted acid to a Brønsted base and in essence are protic ionic liquids in the molten state, have found to be promising solid-state proton conductors for high temperature proton-exchange membrane fuel cells. Examples include 1,2,4- triazolium perfluorobutanesulfonate and imid ...
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