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Peroxyacetyl Nitrate
Peroxyacetyl nitrate is a peroxyacyl nitrate. It is a secondary pollutant present in photochemical smog. It is thermally unstable and decomposes into peroxyethanoyl radicals and nitrogen dioxide gas. It is a lachrymatory substance, meaning that it irritates the lungs and eyes. Peroxyacetyl nitrate, or PAN, is an oxidant that is more stable than ozone. Hence, it is more capable of long-range transport than ozone. It serves as a carrier for oxides of nitrogen (NOx) into rural regions and causes ozone formation in the global troposphere. Atmospheric chemistry PAN is produced in the atmosphere via photochemical oxidation of hydrocarbons to peroxyacetic acid radicals in the presense of nitrogen dioxide (NO2). Since there are no direct emissions, it is a secondary pollutant. Next to ozone and hydrogen peroxide (H2O2), it is an important component of photochemical smog. Further peroxyacyl nitrates in the atmosphere are peroxypropionyl nitrate (PPN), peroxybutyryl nitrate (PBN), an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peroxyacyl Nitrates
In organic chemistry, peroxyacyl nitrates (also known as Acyl peroxy nitrates, APN or PANs) are powerful respiratory and eye irritants present in photochemical smog. They are nitrates produced in the thermal equilibrium between organic peroxy radicals by the gas-phase oxidation of a variety of volatile organic compounds (VOCs), or by aldehydes and other oxygenated VOCs oxidizing in the presence of . For example, peroxyacetyl nitrate, : :Hydrocarbons + O2 + NO2 + light -> CH3COOONO2 The general equation is: :C_\mathitH_\mathitO3 + NO2 -> C_\mathitH_\mathitO3NO2 They are good markers for the source of VOCs as either biogenic or anthropogenic, which is useful in the study of global and local effects of pollutants. PANs are both toxic and irritating, as they dissolve more readily in water than ozone. They are lachrymators, causing eye irritation at concentrations of only a few parts per billion. At higher concentrations they cause extensive damage to vegetation. Both PANs and t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Greenhouse Gas
A greenhouse gas (GHG or GhG) is a gas that Absorption (electromagnetic radiation), absorbs and Emission (electromagnetic radiation), emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse gases in Atmosphere of Earth, Earth's atmosphere are water vapor (), carbon dioxide (), methane (), nitrous oxide (), and ozone (). Without greenhouse gases, the average temperature of Earth#Surface, Earth's surface would be about , rather than the present average of . The atmospheres of atmosphere of Venus, Venus, atmosphere of Mars, Mars and atmosphere of Titan, Titan also contain greenhouse gases. Human activities since the beginning of the Industrial Revolution (around 1750) have increased the Carbon dioxide in Earth's atmosphere, atmospheric concentration of carbon dioxide by over 50%, from 280 parts per million, ppm in 1750 to 421 ppm in 2022. The last time the atmospheric concentration of carbon dioxide was this high was over 3&nbs ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrate Esters
In organic chemistry, a nitrate ester is an organic functional group with the formula , where R stands for any organic residue. They are the esters of nitric acid and alcohols. A well-known example is nitroglycerin, which is not a ''nitro'' compound, despite its name. : Synthesis and reactions Nitrate esters are typically prepared by condensation of nitric acid and the alcohol: For example, the simplest nitrate ester, methyl nitrate, is formed by reaction of methanol and nitric acid in the presence of sulfuric acid: :CH3OH + HNO3 -> CH3ONO2 + H2O This condensation is sometimes called "nitroxylation". Explosive properties The thermal decomposition of nitrate esters mainly yields the gases molecular nitrogen (N2) and carbon dioxide. The considerable chemical energy of the detonation is due to the high strength of the bond in molecular nitrogen. This stoichiometry is illustrated by the equation for the detonation of nitroglycerin. : Illustrative of the highly sensitive n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Peroxides
In organic chemistry, organic peroxides are organic compounds containing the peroxide functional group (). If the R′ is hydrogen, the compounds are called hydroperoxides, which are discussed in that article. The O−O bond of peroxides easily breaks, producing free radicals of the form (the dot represents an unpaired electron). Thus, organic peroxides are useful as initiators for some types of polymerisation, such as the epoxy resins used in glass-reinforced plastics. MEKP and benzoyl peroxide are commonly used for this purpose. However, the same property also means that organic peroxides can explosively combust. Organic peroxides, like their inorganic counterparts, are often powerful bleaching agents. Types of organic peroxides Tert-Butyl hydroperoxide Structural Formula V2.svg, ''tert''-Butyl hydroperoxide, a hydroperoxide (formula: ROOH) that is used to epoxide alkenes. Dicumyl peroxide.svg, Dicumyl peroxide, a dialkyl peroxide (formula: ROOR) that is used to initiate po ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mutagen
In genetics, a mutagen is a physical or chemical agent that permanently changes nucleic acid, genetic material, usually DNA, in an organism and thus increases the frequency of mutations above the natural background level. As many mutations can cause cancer in animals, such mutagens can therefore be carcinogens, although not all necessarily are. All mutagens have characteristic mutational signatures with some chemicals becoming mutagenic through cellular processes. The process of DNA becoming modified is called mutagenesis. Not all mutations are caused by mutagens: so-called "spontaneous mutations" occur due to spontaneous hydrolysis, DNA error, errors in DNA replication, repair and Genetic recombination, recombination. Discovery The first mutagens to be identified were carcinogens, substances that were shown to be linked to cancer. Tumors were described more than 2,000 years before the discovery of chromosomes and DNA; in 500 B.C., the Greece, Greek physician Hippocrates named tu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methyl Nitrate
Methyl nitrate is the methyl ester of nitric acid and has the chemical formula CH3NO3. It is a colourless explosive volatile liquid. Synthesis It can be produced by the condensation of nitric acid and methanol: :CH3OH + HNO3 → CH3NO3 + H2O A newer method uses methyl iodide and silver nitrate: CH3I + AgNO3 → CH3NO3 + AgI Methyl nitrate can be produced on a laboratory or industrial scale either through the distillation of a mixture of methanol and nitric acid, or by the nitration of methanol by a mixture of sulfuric and nitric acids. The first procedure is not preferred due to the great explosion danger presented by the methyl nitrate vapour. The second procedure is essentially identical to that of making nitroglycerin. However, the process is usually run at a slightly higher temperature and the mixture is stirred mechanically on an industrial scale instead of with compressed air. Explosive properties Methyl nitrate is a sensitive explosive. When ignited it burns extremel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Environmental Science & Technology
''Environmental Science & Technology'' is a biweekly peer-reviewed scientific journal published since 1967 by the American Chemical Society. It covers research in environmental science and environmental technology, including environmental policy. ''Environmental Science & Technology'' has a sister journal, ''Environmental Science & Technology Letters'', which publishes short communications. The editor-in-chief of ''Environmental Science & Technology'' is Prof. Julie Zimmerman (Yale University). Previous editors have been: David Sedlak (University of California, Berkeley, 2014 - 2020), James J. Morgan (California Institute of Technology; founding editor, 1967-1975), Russell F. Christman (University of North Carolina, 1975-1987), William H. Glaze (University of North Carolina, 1987-2003) and Jerald L. Schnoor (University of Iowa, 2002-2014). Abstracting and indexing According to the ''Journal Citation Reports'', the journal has a 2021 impact factor of 11.357. The journal is abstra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mercury Lamp
A mercury-vapor lamp is a gas-discharge lamp that uses an electric arc through vaporized mercury to produce light. The arc discharge is generally confined to a small fused quartz arc tube mounted within a larger soda lime or borosilicate glass bulb. The outer bulb may be clear or coated with a phosphor; in either case, the outer bulb provides thermal insulation, protection from the ultraviolet radiation the light produces, and a convenient mounting for the fused quartz arc tube. Mercury vapor lamps are more energy efficient than incandescent lamps with luminous efficacies of 35 to 55 lumens/watt. Their other advantages are a long bulb lifetime in the range of 24,000 hours and a high intensity, clear white light output. For these reasons, they are used for large area overhead lighting, such as in factories, warehouses, and sports arenas as well as for streetlights. Clear mercury lamps produce a greenish light due to mercury's combination of spectral lines. This is not fl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acetone
Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour. Acetone is miscible with water and serves as an important organic solvent in its own right, in industry, home, and laboratory. About 6.7 million tonnes were produced worldwide in 2010, mainly for use as a solvent and production of methyl methacrylate (and from that PMMA) as well as bisphenol A.Acetone World Petrochemicals report, January 2010Stylianos Sifniades, Alan B. Levy, "Acetone" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. It is a common building block in |
Tridecane
Tridecane or ''n''-tridecane is an alkane with the chemical formula CH3(CH2)11CH3. Tridecane is a combustible colourless liquid. In industry, they have no specific value aside from being components of various fuels and solvents. In the research laboratory, tridecane is also used as a distillation chaser. Natural occurrence Nymphs of the southern green shield bug produce tridecane as a dispersion/aggregation pheromone, which possibly serves as a defense against predator Predation is a biological interaction where one organism, the predator, kills and eats another organism, its prey. It is one of a family of common feeding behaviours that includes parasitism and micropredation (which usually do not kill th ...s. It is also the main component of the defensive fluid produced by the stink bug '' Cosmopepla bimaculata''. See also * Higher alkanes * List of isomers of tridecane References External links Material Safety Data Sheet for TridecanePhytochemical and Ethnobo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atmospheric Environment
An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosphere is the outer region of a star, which includes the layers above the opacity (optics), opaque photosphere; stars of low temperature might have outer atmospheres containing compound molecules. The atmosphere of Earth is composed of nitrogen (78%), oxygen (21%), argon (0.9%), Carbon dioxide in Earth's atmosphere, carbon dioxide (0.04%) and trace gases. Most organisms use oxygen for respiration (physiology), respiration; lightning and bacteria perform nitrogen fixation to produce ammonia that is used to make nucleotides and amino acids; plants, algae, and cyanobacteria use carbon dioxide for photosynthesis. The layered composition of the atmosphere minimises the harmful effects of sunlight, ultraviolet radiation, the solar win ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of Geophysical Research
The ''Journal of Geophysical Research'' is a peer-reviewed scientific journal. It is the flagship journal of the American Geophysical Union. It contains original research on the physical, chemical, and biological processes that contribute to the understanding of the Earth, Sun, and Solar System. It has seven sections: A (Space Physics), B (Solid Earth), C (Oceans), D (Atmospheres), E (Planets), F (Earth Surface), and G (Biogeosciences). All current and back issues are available online for subscribers. History The journal was originally founded under the name ''Terrestrial Magnetism'' by the American Geophysical Union's president Louis Agricola Bauer in 1896. It was renamed to ''Terrestrial Magnetism and Atmospheric Electricity'' in 1899 and in 1948 it acquired its current name. In 1980, three specialized sections were established: ''A: Space Physics'', ''B: Solid Earth'', and ''C: Oceans''. Subsequently, further sections have been added: ''D: Atmospheres'' in 1984, ''E: Planets'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
