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Oxygen Balance
Oxygen balance (OB, OB%, or Ω) is an expression that is used to indicate the degree to which an explosive can be oxidized. If an explosive molecule contains just enough oxygen to fully oxidize the other atoms in the explosive. For example, fully oxidized carbon forms carbon dioxide, hydrogen forms water, sulfur forms sulfur dioxide, and metals form metal oxides. A molecule is said to have a positive oxygen balance if it contains more oxygen than is needed and a negative oxygen balance if it contains less oxygen than is needed. An explosive with a negative oxygen balance will lead to incomplete combustion, which commonly produces carbon monoxide, which is a toxic gas. Explosives with negative or positive oxygen balance are commonly mixed with other energetic materials that are either oxygen positive or negative, respectively, to increase the explosive's power. For example, TNT is a oxygen negative explosive and is commonly mixed with oxygen positive energetic materials or fuels ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or BLEVE * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate are said to be "low explosives". Explosives may al ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Nitrate
Ammonium nitrate is a chemical compound with the chemical formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer.Karl-Heinz Zapp "Ammonium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'' 2012, Wiley-VCH, Weinheim. Global production was estimated at 21.6 million tonnes in 2017. Its other major use is as a component of explosive mixtures used in mining, quarrying, and civil construction. It is the major constituent of ANFO, a popular industrial explosive which accounts for 80% of explosives used in North America; similar formulations have been used in improvised explosive devices. Many countries are phasing out its use in consumer applications due to concerns over its potential for misuse. [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Brisance
In explosives engineering, brisance (; , ) is the shattering capability of a high explosive, determined mainly by its detonation pressure. Practical uses Brisance is of practical importance for determining the effectiveness of an explosion in fragmenting shells, bomb casings, grenades, structures, and the like. The sand crush teand Trauzl lead block test are commonly used to determine the relative brisance in comparison to TNT (which is considered a standard reference for many purposes). The value of brisance depends on the application. At one extreme, if an explosive is to be used for propulsion, e.g. by driving a piston or a bullet, brisance is likely to be undesirable, because the objective will be to ''move'' the load, not to shatter it or the engine or firearm, nor to produce a loud report. Such propulsive charges are designed to burn controllably, such as carburetted fuel/air mixes in vehicle piston engines, or nitrocellulose fibres or grains of controlled textures in fir ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trinitrotriazine
Trinitrotriazine, or 2,4,6-trinitro-1,3,5-triazine, is a theoretical explosive compound. Synthesis of this compound has been elusive despite its simple structure, as conventional nitration of triazine becomes increasingly more difficult as more nitro groups are added. A successful route would more likely proceed by trimerisation of nitryl cyanide. The precursor, nitryl cyanide, was first synthesized by Rahm et al. in 2014. Trinitrotriazine has a neutral oxygen balance, potentially making it a very powerful explosive, though calculations predict it would be fairly unstable and inferior to the related compound 3,6-dinitro-1,2,4,5-tetrazine.Jinshan Li. An Ab Initio Theoretical Study of 2,4,6-Trinitro-1,3,5-Triazine, 3,6-Dinitro-1,2,4,5-Tetrazine, and 2,5,8-Trinitro-Tri-s-Triazine, more commonly known as RDX. ''Propellants, Explosives, Pyrotechnics.'' December 2008; 33(6):443-447. See also * RDX RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ethylene Glycol Dinitrate
Ethylene glycol dinitrate, abbreviated EGDN and NGC, also known as Nitroglycol, is a colorless, oily, explosive liquid obtained by nitration, nitrating ethylene glycol. It is similar to nitroglycerine in both manufacture and properties, though it is more volatile and less viscosity, viscous. Unlike nitroglycerine, the chemical has a perfect oxygen balance, meaning that its ideal exothermic decomposition would completely convert it to low energy carbon dioxide, water, and nitrogen gas, with no excess unreacted substances, without needing to react with anything else. History and production Pure EGDN was first produced by the Belgian chemist Louis Henry (1834–1913) in 1870 by dropping a small amount of ethylene glycol into a mixture of nitric acid, nitric and sulfuric acids cooled to 0 °C. The previous year, Friedrich August Kekulé von Stradonitz, August Kekulé had produced EGDN by the nitration of ethylene, but this was actually contaminated with beta-nitroethyl nitrate. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitroglycerine
Nitroglycerin (NG), (alternative spelling of nitroglycerine) also known as trinitroglycerin (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is an organic nitrate compound rather than a nitro compound, but the traditional name is retained. Invented in 1847 by Ascanio Sobrero, nitroglycerin has been used ever since as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. Since the 1880s, it has been used by militaries as an active ingredient and gelatinizer for nitrocellulose in some solid propellants such as cordite and ballistite. It is a major component in double-based smokeless propellants used by reloaders. Combined with nitrocellulo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lithium Perchlorate
Lithium perchlorate is the inorganic compound with the formula LiClO4. This white or colourless crystalline salt is noteworthy for its high solubility in many solvents. It exists both in anhydrous form and as a water of crystallization, trihydrate. Applications Inorganic chemistry Lithium perchlorate is used as a source of oxygen in some chemical oxygen generators. It decomposes at about 400 °C, yielding lithium chloride and oxygen: : LiClO4 → LiCl + 2 O2 Over 60% of the mass of the lithium perchlorate is released as oxygen. It has both the highest oxygen to weight and oxygen to volume ratio of all practical perchlorate salts. Organic chemistry LiClO4 is highly soluble in organic solvents, even diethyl ether. Such solutions are employed in Diels–Alder reaction, Diels–Alder reactions, where it is proposed that the Lewis acidic Li+ binds to Lewis basic sites on the dienophile, thereby accelerating the reaction. Lithium perchlorate is also used as a co-catalyst in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetranitromethane
Tetranitromethane or TNM is an organic oxidizer with chemical formula . Its chemical structure consists of four nitro groups attached to one carbon atom. In 1857 it was first synthesised by the reaction of sodium cyanoacetamide with nitric acid. Uses It has been investigated for use as an oxidizer in bipropellant rockets; however, its high melting point makes it unsuitable. Highly purified tetranitromethane cannot be made to explode, but its sensitivity is increased dramatically by oxidizable contaminants, such as anti-freezing additives. This makes it effectively unusable as a propellant. In the laboratory it is used as a reagent for the detection of double bonds in organic compounds and as a nitrating reagent. It has also found use as an additive to diesel fuel to increase the cetane number. Preparation TNM is a pale yellow liquid that can be prepared in the laboratory by the nitration of acetic anhydride with anhydrous nitric acid (Chattaway's method). This method was attemp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Nitrate
Potassium nitrate is a chemical compound with the chemical formula . This alkali metal nitrate salt is also known as Indian saltpetre (large deposits of which were historically mined in India). It is an ionic salt of potassium ions K+ and nitrate ions NO3−, and is therefore an alkali metal nitrate. It occurs in nature as a mineral, niter (or ''nitre'' in the UK). It is a source of nitrogen, and nitrogen was named after niter. Potassium nitrate is one of several nitrogen-containing compounds collectively referred to as saltpeter (or ''saltpetre'' in the UK). Major uses of potassium nitrate are in fertilizers, tree stump removal, rocket propellants and fireworks. It is one of the major constituents of gunpowder (black powder). In processed meats, potassium nitrate reacts with hemoglobin and myoglobin generating a red color. Etymology Potassium nitrate, because of its early and global use and production, has many names. Hebrew and Egyptian words for it had the consonants n-t-r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Chlorate
Sodium chlorate is an inorganic compound with the chemical formula Na ClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leaves sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper. Synthesis Industrially, sodium chlorate is produced by the electrolysis of concentrated sodium chloride solutions. All other processes are obsolete. The sodium chlorate process is not to be confused with the chloralkali process, which is an industrial process for the electrolytic production of sodium hydroxide and chlorine gas. The overall reaction can be simplified to the equation: First, chloride is oxidised to form intermediate hypochlorite, ClO−, which undergoes further oxidisation to chlorate along two competing reaction paths: (1) Anodic chlorate formation at the boundary layer between the electrolyte and t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Chlorate
Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. It is a strong oxidizing agent and its most important application is in safety matches. In other applications it is mostly obsolete and has been replaced by safer alternatives in recent decades. It has been used * in fireworks, propellants and explosives, * to prepare oxygen, both in the lab and in chemical oxygen generators, * as a disinfectant, for example in medical mouthwashes, * in agriculture as an herbicide. Production On the industrial scale, potassium chlorate is produced by the salt metathesis reaction of sodium chlorate and potassium chloride: : NaClO3 + KCl → NaCl + KClO3 The reaction is driven by the low solubility of potassium chlorate in water. The equilibrium of the reaction is shifted to the right hand side by the continuo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Perchlorate
Ammonium perchlorate ("AP") is an inorganic compound with the formula NH4 ClO4. It is a colorless or white solid that is soluble in water. It is a powerful oxidizer. Combined with a fuel, it can be used as a rocket propellant called ammonium perchlorate composite propellant. Its instability has involved it in a number of accidents, such as the PEPCON disaster. Production Ammonium perchlorate (AP) is produced by reaction between ammonia and perchloric acid. This process is the main outlet for the industrial production of perchloric acid. The salt also can be produced by salt metathesis reaction of ammonium salts with sodium perchlorate. This process exploits the relatively low solubility of NH4ClO4, which is about 10% of that for sodium perchlorate.Helmut Vogt, Jan Balej, John E. Bennett, Peter Wintzer, Saeed Akbar Sheikh, Patrizio Gallone "Chlorine Oxides and Chlorine Oxygen Acids" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH. AP crystallises as colorle ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
