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Octyldodecanol
Octyldodecanol is a branched-chain primary alcohol used as the isomer 2-octyl-1-dodecanol in cosmetics such as lipstick, or as an anti-blooming agent in facepowder. It is a medium spreading emollient, with equilibrium spreading pressure of 17.0 dyne/cm. Octyldodecanol is in the class of Guerbet alcohols, because it has the branch at the β position. Compared to arachidyl alcohol, the linear alcohol of the same molecular weight, it has a lower melting point, yet retains low volatility. Production 2-Octyldodecanol is produced by the Guerbet condensation of decyl alcohol. Reactions When octyldodecanol is melted with an alkali it yields octyldodecanoic acid by a dehydrogenation reaction. References {{Reflist Fatty alcohols Primary alcohols Cosmetics chemicals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Branched-chain Alcohol
In polymer chemistry, branching is the regular or irregular attachment of side chains to a polymer's backbone chain. It occurs by the replacement of a substituent (e.g. a hydrogen atom) on a monomer subunit by another covalently-bonded chain of that polymer; or, in the case of a graft copolymer, by a chain of another type. Branched polymers have more compact and symmetrical molecular conformations, and exhibit intra-heterogeneous dynamical behavior with respect to the unbranched polymers. In crosslinking rubber by vulcanization, short sulfur branches link polyisoprene chains (or a synthetic variant) into a multiple-branched thermosetting elastomer. Rubber can also be so completely vulcanized that it becomes a rigid solid, so hard it can be used as the bit in a smoking pipe. Polycarbonate chains can be crosslinked to form the hardest, most impact-resistant thermosetting plastic, used in safety glasses. Branching may result from the formation of carbon-carbon ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Primary Alcohol
A primary alcohol is an alcohol in which the hydroxy group is bonded to a primary carbon atom. It can also be defined as a molecule containing a “–CH2OH” group. In contrast, a secondary alcohol has a formula “–CHROH” and a tertiary alcohol has a formula “–CR2OH”, where “R” indicates a carbon-containing group. Examples of primary alcohols include ethanol and 1-butanol. Methanol is also generally regarded as a primary alcohol, including the 1911 edition of the Encyclopædia Britannica,. See also * Alcohol (especially Nomenclature section for discussion on Secondary and Tertiary alcohols.) * Oxidation of primary alcohols to carboxylic acids The oxidation of primary alcohols to carboxylic acids is an important oxidation reaction in organic chemistry. When a primary alcohol is converted to a carboxylic acid, the terminal carbon atom increases its oxidation state by four. Oxidants able ... References {{organic-chem-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Emollient
A moisturizer, or emollient, is a cosmetic preparation used for protecting, moisturizing, and lubricating the skin. These functions are normally performed by sebum produced by healthy skin. The word "emollient" is derived from the Latin verb ''mollire'', to soften. Mechanism of action In the human body, water constantly evaporates from the deeper layers of the skin through an effect known as transepidermal water loss (TEWL). By regulating its water content, human skin naturally maintains a dry, easily shed surface as a barrier against pathogens, dirt, or damage, while protecting itself from drying out and becoming brittle and rigid. The ability to retain moisture depends on the lipid bilayer between the corneocytes. Moisturizers modify the rate of water loss, with active ingredients of moisturizers falling into one of two categories: occlusives and humectants. Occlusives form a coating on the surface of the skin, keeping moisture from escaping. The more occlusive the formula ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Guerbet Alcohol
The Guerbet reaction, named after Marcel Guerbet (1861–1938), is an organic reaction that converts a primary alcohol into its β-alkylated dimer alcohol with loss of one equivalent of water. The process is of interest because it converts simple inexpensive feedstocks into more valuable products. Its main disadvantage is that the reaction produces mixtures. Scope and applications The original 1899 publication concerned the conversion of ''n''-butanol to 2-ethylhexanol. 2-ethylhexanol is however more easily prepared by alternative methods (from butyraldehyde). Instead, the Guerbet reaction is mainly applied to fatty alcohols to afford oily products, which are called Guerbet alcohols. They are of commercial interest to as components of cosmetics, plasticizers, and related applications. The reaction is conducted in the temperature range 180-360 °C, often in a sealed reactor. The reaction requires alkali metal hydroxides or alkoxides. Catalysts such as Raney Nickel are req ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arachidyl Alcohol
Arachidyl alcohol, also 1-icosanol, is a waxy substance used as an emollient in cosmetics. It is a straight-chain fatty alcohol with 20 carbon atoms, typically obtained via the hydrogenation of arachidic acid or arachidonic acid, both of which are present in peanut oil. Its name is derived from that of the peanut The peanut (''Arachis hypogaea''), also known as the groundnut, goober (US), pindar (US) or monkey nut (UK), is a legume crop grown mainly for its edible Seed, seeds. It is widely grown in the tropics and subtropics, important to both small ... plant (Latin: ''arachis''). References {{Alcohols Fatty alcohols Primary alcohols Alkanols ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Linear Alcohol
Linearity is the property of a mathematical relationship ('' function'') that can be graphically represented as a straight line. Linearity is closely related to '' proportionality''. Examples in physics include rectilinear motion, the linear relationship of voltage and current in an electrical conductor (Ohm's law), and the relationship of mass and weight. By contrast, more complicated relationships are '' nonlinear''. Generalized for functions in more than one dimension, linearity means the property of a function of being compatible with addition Addition (usually signified by the Plus and minus signs#Plus sign, plus symbol ) is one of the four basic Operation (mathematics), operations of arithmetic, the other three being subtraction, multiplication and Division (mathematics), division. ... and scaling, also known as the superposition principle. The word linear comes from Latin ''linearis'', "pertaining to or resembling a line". In mathematics In mathematics, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
