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Nitropentaamminecobalt(III) Chloride
Nitropentaamminecobalt(III) chloride is an inorganic compound with the molecular formula o(NH3)5(NO2)l2. It is an orange solid that is soluble in water. Although it has no applications, the compound has been of academic interest as a source of the transition metal nitrite complex o(NH3)5(NO2)sup>2+. Linkage isomers The coordination complexes o(NH3)5(NO2)sup>2+ and o(NH3)5(ONO)sup>2+ provided an early example of linkage isomerism. This nitritopentaamminecobalt(III) isomer converts to the more stable nitro form at room temperature. The two isomers can be distinguished by UV-Vis spectroscopy. Absorbance maxima for the nitro isomer occur at 457.5, 325, and 239 nm. The nitrito has maxima at 486, 330, and 220 nm. Their IR spectra also differ. The nitrito isomer absorbs at 1460 and 1065 cm−1. The nitro isomer absorbs at 1430 and 825 cm−1. The O-linkage isomer scrambles rapidly between the two oxygen sites, i.e. Co-O*NO/Co-ONO*. Preparation and reactio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Chemistry (journal)
''Inorganic Chemistry'' is a biweekly peer-reviewed scientific journal published by the American Chemical Society since 1962. It covers research in all areas of inorganic chemistry. The current editor-in-chief is William B. Tolman (Washington University). Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2021 impact factor of 5.436. See also * ''Organometallics ''Organometallics'' is a biweekly journal published by the American Chemical Society. Its area of focus is organometallic and organometalloid chemistry. This peer-reviewed journal has an impact factor of 3.837 as reported by the 2021 Journal Cit ...'' References External links * American Chemical Society academic journals Biweekly journals Publications established in 1962 English-language journals Inorganic chemistry journals {{chem-journal-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Transition Metal Nitrite Complex
In organometallic chemistry, transition metal complexes of nitrite describes families of coordination complexes containing one or more nitrite () ligands. Although the synthetic derivatives are only of scholarly interest, metal-nitrite complexes occur in several enzymes that participate in the nitrogen cycle. Structure and bonding Bonding modes Three linkage isomers are common for nitrite ligands, O-bonded, N-bonded, and bidentate O,O-bonded. The former two isomers have been characterized for the pentamminecobalt(III) system, i.e. and , referred to as N-nitrito and O-nitrito, respectively. These two forms are sometimes called nitro and nitrito. An example of chelating nitrite is – "bipy" is the bidentate ligand 2,2′-bipyridyl. This bonding mode is sometimes described as κ2O,O-. Focusing on electron-counting in monometallic complexes, O-bonded, N-bonded are viewed as 1-electron pseudohalides ("X-ligand"). The bidentate O,O-bonded is an "L-X ligand", akin to bidentate car ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coordination Complex
A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as ''ligands'' or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that belong to the Periodic Table's d-block), are coordination complexes. Nomenclature and terminology Coordination complexes are so pervasive that their structures and reactions are described in many ways, sometimes confusingly. The atom within a ligand that is bonded to the central metal atom or ion is called the donor atom. In a typical complex, a metal ion is bonded to several donor atoms, which can be the same or different. A polydentate (multiple bonded) ligand is a molecule or ion that bonds to the central atom through several of the ligand's atoms; ligands with 2, 3, 4 or even 6 bonds to the central atom are common. These compl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Linkage Isomerism
In chemistry, linkage isomerism or ambidentate isomerism is a form of isomerism in which certain coordination compounds have the same composition but differ in their metal atom's connectivity to a ligand. Typical ligands that give rise to linkage isomers are: *thiocyanate, – isothiocyanate, *selenocyanate, – isoselenocyanate, *nitrite, *sulfite, Examples of linkage isomers are violet-colored and orange-colored . The isomerization of the S-bonded isomer to the N-bonded isomer occurs intramolecularly. The complex ''cis''- dichlorotetrakis(dimethylsulfoxide)ruthenium(II) () exhibits linkage isomerism of dimethyl sulfoxide ligands due to S- vs. O-bonding. ''Trans''-dichlorotetrakis(dimethylsulfoxide)ruthenium(II) does not exhibit linkage isomers. History Linkage isomerism was first noted for nitropentaamminecobalt(III) chloride, . This cationic cobalt complex Complex commonly refers to: * Complexity, the behaviour of a system whose components interact in multiple ways ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of Chemical Education
The ''Journal of Chemical Education'' is a monthly peer-reviewed academic journal available in both print and electronic versions. It is published by the Division of Chemical Education of the American Chemical Society and was established in 1924 by Neil Gordon. The journal covers research on chemical education Chemistry education (or chemical education) is the study of teaching and learning chemistry. It is one subset of STEM education or discipline-based education research (DBER). Topics in chemistry education include understanding how students learn ..., and its target audience includes instructors of chemistry from middle school through graduate school and some scientists in commerce, industry, and government. References External links * Chemical education journals American Chemical Society academic journals Monthly journals Publications established in 1924 English-language journals {{chemistry-journal-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of The American Chemical Society
The ''Journal of the American Chemical Society'' is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society. The journal has absorbed two other publications in its history, the ''Journal of Analytical and Applied Chemistry'' (July 1893) and the ''American Chemical Journal'' (January 1914). It covers all fields of chemistry. Since 2021, the editor-in-chief is Erick M. Carreira (ETH Zurich). In 2014, the journal moved to a hybrid open access publishing model. Abstracting and indexing The journal is abstracted and indexed in Chemical Abstracts Service, Scopus, EBSCO databases, ProQuest databases, Index Medicus/MEDLINE/PubMed, and the Science Citation Index Expanded. According to the ''Journal Citation Reports'', the journal has a 2021 impact factor of 16.383. Editors-in-chief The following people are or have been editor-in-chief: * 1879–1880 – Hermann Endemann * 1880–1881 – Gideon E. Moore * 1881–1882 – Hermann Endemann ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chloropentamminecobalt Chloride
Chloropentamminecobalt chloride is the dichloride salt of the coordination complex o(NH3)5Clsup>2+. It is a red-violet, diamagnetic, water-soluble salt. The compound has been of academic and historical interest. Synthesis and reactions The salt is prepared with a two-step process starting with oxidizing a solution of cobalt chloride and ammonia. :2 CoCl2·6H2O + 10 NH3 + 2 HCl + H2O2 → 2 o(NH3)5(OH2)l3 + 12 H2O This intermediate is then heated to induce coordination of one of the outer sphere chloride ligands: : o(NH3)5(OH2)l3 → o(NH3)5Cll2 + H2O The dication o(NH3)5Clsup>2+ has idealized C4v symmetry. In an aqueous solution, chloropentaamminecobalt(III) chloride reforms aquopentammine complex. With concentrated sulfuric acid, chloropentaamminecobalt(III) chloride forms the hydrogen sulfate complex o(NH3)5OSO3Hsup>2+. History Cobalt complexes have been of long-standing interest in inorganic chemistry because they are numerous, easily prepar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bioinorganic Chemistry
Bioinorganic chemistry is a field that examines the role of metals in biology. Bioinorganic chemistry includes the study of both natural phenomena such as the behavior of metalloproteins as well as artificially introduced metals, including those that are non-essential, in medicine and toxicology. Many biological processes such as respiration depend upon molecules that fall within the realm of inorganic chemistry. The discipline also includes the study of inorganic models or mimics that imitate the behaviour of metalloproteins. As a mix of biochemistry and inorganic chemistry, bioinorganic chemistry is important in elucidating the implications of electron-transfer proteins, substrate bindings and activation, atom and group transfer chemistry as well as metal properties in biological chemistry. The successful development of truly interdisciplinary work is necessary to advance bioinorganic chemistry. Composition of living organisms About 99% of mammals' mass are the elements carb ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobalt Complexes
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal. Cobalt-based blue pigments (cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was for a long time thought to be due to the known metal bismuth. Miners had long used the name ''kobold ore'' (German for ''goblin ore'') for some of the blue-pigment-producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the ''kobold''. Today, some cobalt is produced specifically from one of a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobalt(III) Compounds
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal. Cobalt-based blue pigments (cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was for a long time thought to be due to the known metal bismuth. Miners had long used the name ''kobold ore'' (German for ''goblin ore'') for some of the blue-pigment-producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the ''kobold''. Today, some cobalt is produced specifically from one of a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammine Complexes
In coordination chemistry, metal ammine complexes are metal complexes containing at least one ammonia () ligand. "Ammine" is spelled this way due to historical reasons; in contrast, alkyl or aryl bearing ligands are spelt with a single "m". Almost all metal ions bind ammonia as a ligand, but the most prevalent examples of ammine complexes are for Cr(III), Co(III), Ni(II), Cu(II) as well as several platinum group metals.A. von Zelewsky "Stereochemistry of Coordination Compounds" John Wiley: Chichester, 1995. . History Ammine complexes played a major role in the development of coordination chemistry, specifically determination of the stereochemistry and structure. They are easily prepared, and the metal-nitrogen ratio can be determined by elemental analysis. Through studies mainly on the ammine complexes, Alfred Werner developed his Nobel Prize-winning concept of the structure of coordination compounds (see Figure). One of the first ammine complexes to be described was Magnus' green ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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