Molten Salt Heat Storage
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Molten Salt Heat Storage
Thermal energy storage (TES) is achieved with widely different technologies. Depending on the specific technology, it allows excess thermal energy to be stored and used hours, days, months later, at scales ranging from the individual process, building, multiuser-building, district, town, or region. Usage examples are the balancing of energy demand between daytime and nighttime, storing summer heat for winter heating, or winter cold for summer air conditioning (Seasonal thermal energy storage). Storage media include water or ice-slush tanks, masses of native earth or bedrock accessed with heat exchangers by means of boreholes, deep aquifers contained between impermeable strata; shallow, lined pits filled with gravel and water and insulated at the top, as well as eutectic solutions and phase-change materials. Other sources of thermal energy for storage include heat or cold produced with heat pumps from off-peak, lower cost electric power, a practice called peak shaving; heat fro ...
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Solar Power Tower
A solar power tower, also known as 'central tower' power plant or 'heliostat' power plant, is a type of solar furnace using a tower to receive focused sunlight. It uses an array of flat, movable mirrors (called heliostats) to focus the sun's rays upon a collector tower (the target). Concentrating Solar Power (CSP) systems are seen as one viable solution for renewable, pollution-free energy. Early designs used these focused rays to heat water, and used the resulting steam to power a turbine. Newer designs using liquid sodium have been demonstrated, and systems using molten salts (40% potassium nitrate, 60% sodium nitrate) as the working fluids are now in operation. These working fluids have high heat capacity, which can be used to store the energy before using it to boil water to drive turbines. These designs also allow power to be generated when the sun is not shining. Cost In 2021, the US National Renewable Energy Laboratory (NREL) estimated cost of electricity from concent ...
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Gemasolar Thermosolar Plant
Gemasolar is a concentrated solar power plant with a molten salt heat storage system. It is located within the city limits of Fuentes de Andalucía in the province of Seville, Spain. Design and specifications The plant is of the solar power tower type CSP and uses concepts pioneered in the Solar One and Solar Two demonstration projects, using molten salt as its heat transfer fluid and energy storage medium. Originally called Solar Tres, it was renamed Gemasolar. The project, which has received a subsidy of five million euros from the European Commission and a loan of 80 million euros from the European Investment Bank, makes use of the Solar Two technology tested in Barstow, California, but is approximately three times the size. It makes use of several advances in technology after Solar Two was designed and built. Gemasolar is the first commercial solar plant with central tower receiver and molten salt heat storage technology. It consists of a solar heliostat aperture area wi ...
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Solana Generating Station
The Solana Generating Station is a solar power plant near Gila Bend, Arizona, about southwest of Phoenix, completed in 2013. When commissioned it was the largest parabolic trough plant in the world and the first U.S. solar plant with molten salt thermal energy storage. Built by the Spanish company Abengoa Solar, it has a total capacity of 280 megawatts (MW) gross, from two 140 MW gross (125 MW net) steam turbine generators, which is enough to power 70,000 homes while avoiding around 475,000 tons of CO2 every year. Its name is the Spanish term for "sunny spot". Technology The plant employs a proprietary concentrating solar power (CSP) trough technology developed by Abengoa, and covers an area of . Construction was expected to create about 1,500 construction jobs with the plant employing 85 full-time workers. Solar thermal plants use substantially more water for cooling than other solar generating technologies. Nevertheless, the Sierra Club supported the Solan ...
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Concentrated Solar Power
Concentrated solar power (CSP, also known as concentrating solar power, concentrated solar thermal) systems generate solar power by using mirrors or lenses to concentrate a large area of sunlight into a receiver. Electricity is generated when the concentrated light is converted to heat (solar thermal energy), which drives a heat engine (usually a steam turbine) connected to an electrical power generator or powers a thermochemical reaction. CSP had a global total installed capacity of 6,800 Megawatt, MW in 2021, up from 354 MW in 2005. Solar power in Spain, Spain accounted for almost one third of the world's capacity, at 2,300 MW, despite no new capacity entering commercial operation in the country since 2013. The United States follows with 1,740 MW. Interest is also notable in North Africa and the Middle East, as well as China and India. The global market was initially dominated by parabolic-trough plants, which accounted for 90% of CSP plants at one point ...
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Phase Change Material
A phase change material (PCM) is a substance which releases/absorbs sufficient energy at phase transition to provide useful heat or cooling. Generally the transition will be from one of the first two fundamental states of matter - solid and liquid - to the other. The phase transition may also be between non-classical states of matter, such as the conformity of crystals, where the material goes from conforming to one crystalline structure to conforming to another, which may be a higher or lower energy state. The energy released/absorbed by phase transition from solid to liquid, or vice versa, the heat of fusion is generally much higher than the sensible heat. Ice, for example, requires 333.55 J/g to melt, but then water will rise one degree further with the addition of just 4.18 J/g. Water/ice is therefore a very useful phase change material and has been used to store winter cold to cool buildings in summer since at least the time of the Achaemenid Empire. By melting and soli ...
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Superheated Steam
Superheated steam is steam at a temperature higher than its vaporization point at the absolute pressure where the temperature is measured. Superheated steam can therefore cool (lose internal energy) by some amount, resulting in a lowering of its temperature without changing state (i.e., condensing) from a gas, to a mixture of saturated vapor and liquid. If unsaturated steam (a mixture which contains both water vapor and liquid water droplets) is heated at constant pressure, its temperature will also remain constant as the vapor quality (think dryness, or percent saturated vapor) increases towards 100%, and becomes dry (i.e., no saturated liquid) saturated steam. Continued heat input will then "super" heat the dry saturated steam. This will occur if saturated steam contacts a surface with a higher temperature. Superheated steam and liquid water cannot coexist under thermodynamic equilibrium, as any additional heat simply evaporates more water and the steam will become saturated ...
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Steam Generator (boiler)
A steam generator is a form of low water-content boiler, similar to a flash steam boiler. The usual construction is as a spiral coil of water-tube, arranged as a single, or monotube, coil. Circulation is once-through and pumped under pressure, as a forced-circulation boiler. The narrow-tube construction, without any large-diameter drums or tanks, means that they are safe from the effects of explosion,This safety from explosion is due to two causes. Firstly, small diameter tubes are inherently stronger than large tubes of the same construction, as was first appreciated by William Fairbairn in the mid-19th century. Secondly, the low water-content means that there is relatively little volume of water per area of heating surface (i.e. boiler power). As the destructive energy of a boiler explosion is largely due to the sudden release of this energy, and proportional to water volume, a low water-content boiler has a more favourable ratio of useful power (from its area) to risk (from ...
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Thermal Insulation
Thermal insulation is the reduction of heat transfer (i.e., the transfer of thermal energy between objects of differing temperature) between objects in thermal contact or in range of radiative influence. Thermal insulation can be achieved with specially engineered methods or processes, as well as with suitable object shapes and materials. Heat flow is an inevitable consequence of contact between objects of different temperature. Thermal insulation provides a region of insulation in which thermal conduction is reduced, creating a thermal break or thermal barrier, or thermal radiation is reflected rather than absorbed by the lower-temperature body. The insulating capability of a material is measured as the inverse of thermal conductivity (k). Low thermal conductivity is equivalent to high insulating capability ( resistance value). In thermal engineering, other important properties of insulating materials are product density (ρ) and specific heat capacity (c). Definition T ...
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Calcium Nitrate
Calcium nitrate, also called ''Norgessalpeter'' (Norwegian salpeter), is an inorganic compound with the formula Ca(NO3)2(H2O)x. The anhydrous compound, which is rarely encountered, absorbs moisture from the air to give the tetrahydrate. Both anhydrous and hydrated forms are colourless salts. Calcium nitrate is mainly used as a component in fertilizers, but it has other applications. Nitrocalcite is the name for a mineral which is a hydrated calcium nitrate that forms as an efflorescence where manure contacts concrete or limestone in a dry environment as in stables or caverns. A variety of related salts are known including calcium ammonium nitrate decahydrate and calcium potassium nitrate decahydrate. Production and reactivity Norgessalpeter was synthesized at Notodden, Norway in 1905 by the Birkeland–Eyde process. Most of the world's calcium nitrate is now made in Porsgrunn. It is produced by treating limestone with nitric acid, followed by neutralization with ammonia: :CaCO3 + ...
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Potassium Nitrate
Potassium nitrate is a chemical compound with the chemical formula . This alkali metal nitrate salt is also known as Indian saltpetre (large deposits of which were historically mined in India). It is an ionic salt of potassium ions K+ and nitrate ions NO3−, and is therefore an alkali metal nitrate. It occurs in nature as a mineral, niter (or ''nitre'' in the UK). It is a source of nitrogen, and nitrogen was named after niter. Potassium nitrate is one of several nitrogen-containing compounds collectively referred to as saltpeter (or ''saltpetre'' in the UK). Major uses of potassium nitrate are in fertilizers, tree stump removal, rocket propellants and fireworks. It is one of the major constituents of gunpowder (black powder). In processed meats, potassium nitrate reacts with hemoglobin and myoglobin generating a red color. Etymology Potassium nitrate, because of its early and global use and production, has many names. Hebrew and Egyptian words for it had the consonants n-t-r ...
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Sodium Nitrate
Sodium nitrate is the chemical compound with the formula . This alkali metal nitrate salt is also known as Chile saltpeter (large deposits of which were historically mined in Chile) to distinguish it from ordinary saltpeter, potassium nitrate. The mineral form is also known as nitratine, nitratite or soda niter. Sodium nitrate is a white deliquescent solid very soluble in water. It is a readily available source of the nitrate anion (NO3−), which is useful in several reactions carried out on industrial scales for the production of fertilizers, pyrotechnics, smoke bombs and other explosives, glass and pottery enamels, food preservatives (esp. meats), and solid rocket propellant. It has been mined extensively for these purposes. History The first shipment of saltpeter to Europe arrived in England from Peru in 1820 or 1825, right after that country's independence from Spain, but did not find any buyers and was dumped at sea in order to avoid customs toll.Friedrich Georg Wieck, ' ...
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