Mawsonite
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Mawsonite
Mawsonite is a brownish orange sulfosalt mineral, containing copper, iron, tin, and sulfur: Cu6Fe2SnS8. Discovery and occurrence It was first described in 1965 for occurrences in the Royal George mine, Swinton, Tingha, Hardinge County, New South Wales; and the North Lyell mine, Mount Lyell Mine, Queenstown, Tasmania. page 66 of It was named after Australian geologist and Antarctic explorer, Sir Douglas Mawson (1882–1958). It occurs within hydrothermal copper deposits in altered volcanic rocks. It also occurs in skarn deposits and as disseminations in altered granites. It occurs in association with bornite, pyrite, chalcopyrite, chalcocite, digenite, idaite, stannite, stannoidite, pyrrhotite, pentlandite, tennantite, enargite, luzonite– famatinite, kiddcreekite, mohite, native bismuth Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter g ...
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Sulfosalt Minerals
Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury (element), mercury, zinc, vanadium *B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely germanium, or metals like tin and rarely vanadium *X is sulfur or rarely selenium and/or tellurium. The Strunz classification includes the sulfosalts in a ''sulfides and sulfosalts'' superclass. A group which have similar appearing formulas are the Sulfarsenide mineral, sulfarsenides (for example cobaltite (Co,Fe)AsS). In sulfarsenides the arsenic substitutes for sulfide anions whereas in the sulfosalts the arsenic substitutes for a metal cation.Klein, Cornelis and Cornelius S. Hurlbut (1985). ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York . About 200 sulfosalt minerals are known. Examples include: File:Proustite (long prismatic crystal) - Chanarcillo, Copiapo Province, Atacama Region, Chile.jpg, As ...
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Volcanic Rocks
Volcanic rock (often shortened to volcanics in scientific contexts) is a Rock (geology), rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of Volcano, volcanic origin. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into Subvolcanic rock, hypabyssal and metamorphic rocks and constitute an important element of some sediments and sedimentary rocks. For these reasons, in geology, volcanics and shallow hypabyssal rocks are not always treated as distinct. In the context of Precambrian shield (geology), shield geology, the term "volcanic" is often applied to what are strictly metavolcanic rocks. Volcanic rocks and sediment that form from magma erupted into the air are called "volcaniclastics," and these are technically sedimentary rocks. Volcanic rocks are among the most common rock types on Earth's surface, particularly in the oceans. On land, they are very common at plate bound ...
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Enargite
Enargite is a copper arsenic sulfosalt mineral with formula Cu3AsS4. It takes its name from the Greek word , "distinct". Enargite is a steel gray, blackish gray, to violet black mineral with metallic luster. It forms slender orthorhombic prisms as well as massive aggregates. It has a hardness of 3 and a specific gravity of 4.45. Enargite is dimorph of the tetragonal luzonite. Occurrence It is a medium to low temperature hydrothermal mineral occurring with quartz, pyrite, sphalerite, galena, bornite, tetrahedrite–tennantite, chalcocite, covellite and baryte. It occurs in the mineral deposits at Butte, Montana, San Juan Mountains, Colorado and at both Bingham Canyon and Tintic, Utah. It is also found in the copper mines of Canada, Mexico, Argentina, Chile, Peru, and the Philippines. Enargite was originally described as a new species from the copper mines of the San Francisco vein, Junin Department, Peru , image_flag = Flag of Peru.svg , image_coat ...
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Tennantite
Tennantite is a copper arsenic sulfosalt mineral with an ideal formula . Due to variable substitution of the copper by iron and zinc the formula is . It is gray-black, steel-gray, iron-gray or black in color. A closely related mineral, tetrahedrite ) has antimony substituting for arsenic and the two form a solid solution series. The two have very similar properties and is often difficult to distinguish between tennantite and tetrahedrite. Iron, zinc, and silver substitute up to about 15% for the copper site. The mineral was first described for an occurrence in Cornwall, England in 1819, where it occurs as small crystals of cubic or dodecahedral form, and was named after the English chemist Smithson Tennant (1761–1815). It is found in hydrothermal veins and contact metamorphic deposits in association with other Cu–Pb–Zn–Ag sulfides and sulfosalts, pyrite, calcite, dolomite, siderite, barite, fluorite and quartz. The arsenic component of tennantite causes the metal smelte ...
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Pentlandite
Pentlandite is an iron–nickel sulfide with the chemical formula . Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of weight. Pentlandite forms isometric crystals, but it is normally found in massive granular aggregates. It is brittle with a hardness of 3.5–4 and specific gravity of 4.6–5.0 and is non-magnetic. It has a yellowish bronze color. Pentlandite is the most important source of mined nickel. Name and discovery It is named after the Irish scientist Joseph Barclay Pentland (1797–1873), who first noted the mineral. Paragenesis Pentlandite is the most common terrestrial nickel sulfide. It typically forms during cooling of a sulfide melt. These sulfide melts, in turn, are typically formed during the evolution of a silicate melt. Because Ni is a chalcophile-like element, it has preference for (i.e. it "partitions into") sulfide phases. In sul ...
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Pyrrhotite
Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.2). It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content increases, and troilite is non-magnetic.Vaughan, D. J.; Craig, J. R. "Mineral Chemistry of Metal Sulfides" Cambridge University Press, Cambridge: 1978. . Structure Pyrrhotite exists as a number of polytypes of hexagonal or monoclinic crystal symmetry; several polytypes often occur within the same specimen. Their structure is based on the NiAs unit cell. As such, Fe occupies an octahedral site and the sulfide centers occupy trigonal prismatic sites. Materials with the NiAs structure often are non-stoichiometric because they lack up to 1/8th fraction of the metal ions, creating vacancies. One of such structures is pyrrhotite-4C (Fe7S8). Here "4" indicates that iron vacancies ...
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Stannoidite
Stannoidite is a sulfide mineral composed of five chemical elements: copper, iron, zinc, tin and sulfur. Its name originates from Latin ''stannum'' (tin) and Greek ''eides'' (or Latin ''oïda'' meaning "like"). The mineral is found in hydrothermal Cu-Sn deposits. Stannoidite was first described in 1969 for an occurrence in the Konjo mine, Okayama prefecture, Honshu Island, Japan. See also * Stannite * Kesterite Kësterite is a sulfide mineral with a chemical formula of . In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterite is the Zn-rich variety whereas the Zn-poor form is called ferrokesterite or stannite. Owing to thei ... References Sulfide minerals Orthorhombic minerals Minerals in space group 23 {{sulfide-mineral-stub ...
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Stannite
Stannite is a mineral, a sulfide of copper, iron, and tin, in the category of thiostannates. Background The chemical formula Cu2 Fe Sn S4. Zinc commonly occurs with the iron and trace germanium may be present. Stannite is used as an ore of tin, consisting of approximately 28% tin, 13% iron, 30% copper, 30% sulfur by mass. It is found in tin-bearing, hydrothermal vein deposits occurring with chalcopyrite, sphalerite, tetrahedrite, arsenopyrite, pyrite, cassiterite, and wolframite. It is also known as ''bell metal ore'' as tin is an important constituent of bell-metal. It is thought the exploitation of tin deposits in Cornwall led to an expansion in bell founding. The name comes from the Latin for tin: ''stannum''. It was first described in 1797 for an occurrence in Wheal Rock, St. Agnes, Cornwall, England. See also * Kesterite Kësterite is a sulfide mineral with a chemical formula of . In its lattice structure, zinc and iron atoms share the same lattice sites. Kesterit ...
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Digenite
Digenite is a copper sulfide mineral with formula: Cu9S5. Digenite is a black to dark blue opaque mineral that crystallizes with a trigonal - hexagonal scalenohedral structure. In habit it is usually massive, but does often show pseudo-cubic forms. It has poor to indistinct cleavage and a brittle fracture. It has a Mohs hardness of 2.5 to 3 and a specific gravity of 5.6. It is found in copper sulfide deposits of both primary and supergene occurrences. It is typically associated with and often intergrown with chalcocite, covellite, djurleite, bornite, chalcopyrite and pyrite. The type locality is Sangerhausen, Thuringia, Germany, in copper slate deposits. Occurrence Digenite occurs in the transitional zone of supergene oxidation of primary sulfide ore deposits, at the interface between the upper and lower saprolite ore zones. It is rarely an important mineral for copper ores, as it is more usually replaced by chalcocite further up in the weathering profile, and is a minor ...
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Chalcocite
Chalcocite (), copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system. The term ''chalcocite'' comes from the alteration of the obsolete name ''chalcosine'', from the Greek ''khalkos'', meaning "copper". It is also known as redruthite, vitreous copper, or copper-glance. Occurrence Chalcocite is sometimes found as a primary vein mineral in hydrothermal veins. However, most chalcocite occurs in the supergene enriched environment below the oxidation zone of copper deposits as a result of the leaching of copper from the oxidized minerals. It is also often found in sedimentary rocks. It has been mined for centuries and is one of the most profitable copper ores. The reasons for this is its high copper content (66.7% atomic ratio and nearly 80% by weight) and the ease at which copper can be separated from sulfur. ...
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Chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black. On exposure to air, chalcopyrite tarnishes to a variety of oxides, hydroxides, and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). Is rarely found in association with native copper. Chalcopyrite is a conductor of electricity. Etymology The name chalcopyrite comes from the Greek words , which means copper, and ', which means striking fire. It was sometimes historically referred to as "yellow copper". Identification Chalcopyrite is often confused with pyrite and gold since all three of these minerals have a yell ...
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