Manganite
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Manganite
Manganite is a mineral composed of manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic). Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped together in bundles. The color is dark steel-grey to iron-black, and the luster brilliant and submetallic. The streak is dark reddish brown. The hardness is 4, and the specific gravity is 4.3. There is a perfect cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. Twinned crystals are not infrequent. The mineral contains 89.7% manganese sesquioxide; it dissolves in hydrochloric acid with evolution of chlorine. Occurrence Manganite occurs with other manganese oxides in deposits formed by circulating meteoric water in the weathering environment in clay deposits and laterites. It forms by low temperature hydrothermal action in veins in association with calcite, barite, and siderite. Often associated wi ...
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Oxide Mineral
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite *** Bromellite ***Tenorite ***Litharge * **Cuprite **Ice * **Hematite group ***Corundum ***Hematite ***Ilmenite * **Rutile group ***Rutile ***Pyrolusite ***Cassiterite **Baddeleyite **Uraninite **Thorianite * **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite ***Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite ** Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify ...
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Manganese Sesquioxide
Manganese(III) oxide is a chemical compound with the formula Mn2O3. It occurs in nature as the mineral bixbyite (recently changed to bixbyite-(Mn)IMA 21-H: Redefinition of bixbyite and definition of bixbyite-(Fe) and bixbyite-(Mn). CNMNC Newsletter, 64, 2021; Mineralogical Magazine, 85, 2021).) and is used in the production of ferrites and thermistors. Preparation and chemistry Heating MnO2 in air at below 800 °C produces α-Mn2O3 (higher temperatures produce Mn3O4). γ-Mn2O3 can be produced by oxidation followed by dehydration of manganese(II) hydroxide. Many preparations of nano-crystalline Mn2O3 have been reported, for example syntheses involving oxidation of MnII salts or reduction of MnO2. Manganese(III) oxide is formed by the redox reaction in an alkaline cell: : 2 MnO2 + Zn → Mn2O3 + ZnO Manganese(III) oxide Mn2O3 must not be confused with MnOOH manganese(III) oxyhydroxide. Contrary to Mn2O3, MnOOH is a compound that decomposes at about 300 °C to form MnO2. ...
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Chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Electronegativity#Pauling electronegativity, Pauling scale, behind only oxygen and fluorine. Chlorine played an important role in the experiments conducted by medieval Alchemy, alchemists, which commonly involved the heating of chloride Salt (chemistry), salts like ammonium chloride (sal ammoniac) and sodium chloride (common salt), producing various chemical substances containing chlorine such as hydrogen chloride, mercury(II) chloride (corrosive sublimate), and hydrochloric acid (in the form of ). However ...
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Goethite
Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient times for its use as a pigment (brown ochre). Evidence has been found of its use in paint pigment samples taken from the caves of Lascaux in France. It was first described in 1806 based on samples found in the Hollertszug Mine in Herdorf, Germany. The mineral was named after the German polymath and poet Johann Wolfgang von Goethe (1749–1832). Composition Goethite is an iron oxyhydroxide containing ferric iron. It is the main component of rust and bog iron ore. Goethite's hardness ranges from 5.0 to 5.5 on the Mohs Scale, and its specific gravity varies from 3.3 to 4.3. The mineral forms prismatic needle-like crystals ("needle ironstone") but is more typically massive. Feroxyhyte and lepidocrocite are both polymorphs of the iron oxy ...
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Hausmannite
Hausmannite is a complex oxide of manganese containing both di- and tri-valent manganese. The formula can be represented as Mn2+Mn3+2O4. It belongs to the spinel group and forms tetragonal crystals. Hausmannite is a brown to black metallic mineral with Mohs hardness of 5.5 and a specific gravity of 4.8. The type locality is Oehrenstock (Öhrenstock), Ilmenau, Thuringian Forest, Thuringia, Germany, where it was first described in 1813. Locations include Batesville, Arkansas, US; Ilfeld, Germany; Langban, Sweden; and the Ural Mountains, Russia. High quality samples have been found in South Africa and Namibia where it is associated with other manganese oxides, pyrolusite and psilomelane and the iron-manganese mineral bixbyite. Wilhelm Haidinger (1827) named it in honour of Johann Friedrich Ludwig Hausmann (1782–1859), Professor of Mineralogy, University of Göttingen, Germany. Image gallery File:Hausmannite-131901.jpg, Hausmannite from Wessels Mine, Kalahari manganese fields ...
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Braunite
Braunite is a silicate mineral containing both di- and tri- valent manganese with the chemical formula: Mn2+Mn3+6 SiO4 Common impurities include iron, calcium, boron, barium, titanium, aluminium, and magnesium. Braunite forms grey/black tetragonal crystals and has a Mohs hardness of 6 - 6.5. It was named after the Wilhelm von Braun (1790–1872) of Gotha, Thuringia, Germany. A calcium iron bearing variant, named braunite II (formula: Ca(Mn3+,Fe3+)14SiO24), was discovered and described in 1967 from Kalahari, Cape Province, South Africa South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring countri .... References External linksWebmineralAthena mineral
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Pyrolusite
Pyrolusite is a mineral consisting essentially of manganese dioxide ( Mn O2) and is important as an ore of manganese.. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for ''fire'' and to ''wash'', in reference to its use as a way to remove tints from glass. Occurrence Pyrolusite and romanechite are among the most common manganese minerals. Pyrolusite occurs associated with manganite, hollandite, hausmannite, braunite, chalcophanite, goethite, and hematite under oxidizing conditions in hydrothermal deposits. It also occurs in bogs and often results from alteration of manganite. Use The metal is obtained by reduction of the oxide with sodium, magnesium, aluminium, or by electrolysis. Pyrolusite is extensively used for the manufacture of spi ...
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Siderite
Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and manganese commonly substitute for the iron resulting in the siderite-smithsonite, siderite- magnesite and siderite-rhodochrosite solid solution series. Siderite has Mohs hardness of 3.75-4.25, a specific gravity of 3.96, a white streak and a vitreous lustre or pearly luster. Siderite is antiferromagnetic below its Néel temperature of 37 K which can assist in its identification. It crystallizes in the trigonal crystal system, and are rhombohedral in shape, typically with curved and striated faces. It also occurs in masses. Color ranges from yellow to dark brown or black, the latter being due to the presence of manganese. Siderite is commonly found in hydrothermal veins, and is associated with barite, fluorite, galena, and others. It i ...
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Barite
Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), anglesite (lead sulfate), and anhydrite (calcium sulfate). Baryte and celestine form a solid solution (Ba,Sr)SO4. Names and history The radiating form, sometimes referred to as ''Bologna Stone'', attained some notoriety among alchemists for specimens found in the 17th century near Bologna by Vincenzo Casciarolo. These became phosphorescent upon being calcined. Carl Scheele determined that baryte contained a new element in 1774, but could not isolate barium, only barium oxide. Johan Gottlieb Gahn also isolated barium oxide two years later in similar studies. Barium was first isolated by electrolysis of molten barium salts in 1808 by Sir Humphry Davy in England. The American Petroleum Institute specification API 13/ISO 13500, which gover ...
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Calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on Scratch hardness, scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite. Aragonite will change to calcite over timescales of days or less at temperatures exceeding 300 °C, and vaterite is even less stable. Etymology Calcite is derived from the German ''Calcit'', a term from the 19th century that came from the Latin word for Lime (material), lime, ''calx'' (genitive calcis) with the suffix "-ite" used to name minerals. It is thus etymologically related to chalk. When applied by archaeology, archaeologists and stone trade pr ...
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Vein (geology)
In geology, a vein is a distinct sheetlike body of crystallized minerals within a rock. Veins form when mineral constituents carried by an aqueous solution within the rock mass are deposited through precipitation. The hydraulic flow involved is usually due to hydrothermal circulation. Veins are classically thought of as being the ones in the body not the rock veins and arteries planar fractures in rocks, with the crystal growth occurring normal to the walls of the cavity, and the crystal protruding into open space. This certainly is the method for the formation of some veins. However, it is rare in geology for significant open space to remain open in large volumes of rock, especially several kilometers below the surface. Thus, there are two main mechanisms considered likely for the formation of veins: ''open-space filling'' and ''crack-seal growth''. Open space filling Open space filling is the hallmark of epithermal vein systems, such as a stockwork, in greisens or in cert ...
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Hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with the assistance of. Roderick McKenzie.'' Oxford: Clarendon Press. and θέρμη, ''heat'' ). Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earth's crust. In general, this occurs near volcanic activity, but can occur in the shallow to mid crust along deeply penetrating fault irregularities or in the deep crust related to the intrusion of granite, or as the result of orogeny or metamorphism. Seafloor hydrothermal circulation Hydrothermal circulation in the oceans is the passage of the water through mid-oceanic ridge systems. The term includes both the circulation of the well-known, high-temperature vent waters near the ridge crests, and the much-lower-temperature, diffuse flow of water through sedim ...
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