|
Metallic Bonding
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be described as the sharing of ''free'' electrons among a structure of positively charged ions ( cations). Metallic bonding accounts for many physical properties of metals, such as strength, ductility, thermal and electrical resistivity and conductivity, opacity, and luster. Metallic bonding is not the only type of chemical bonding a metal can exhibit, even as a pure substance. For example, elemental gallium consists of covalently-bound pairs of atoms in both liquid and solid-state—these pairs form a crystal structure with metallic bonding between them. Another example of a metal–metal covalent bond is the mercurous ion (). History As chemistry developed into a science, it became clear that metals formed the majority of the periodic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metallic Bonding Example
Metallic may be a reference to: *Metal *Metalloid, metal-like substance *Metallic bonding, type of chemical bonding *Metallicity, in astronomy the proportion of elements other than helium and hydrogen in an object *Metallic color, a color that gives the appearance of metal *Metallic dragon, a classification of dragon found in the role playing game Dungeons & Dragons *Metallic paint, paint that provides the appearance of metal *Heavy metal music, a genre of rock music See also *Metallica (other) {{disambiguation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Periodic Table
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of chemistry. It is a graphic formulation of the periodic law, which states that the properties of the chemical elements exhibit an approximate periodic dependence on their atomic numbers. The table is divided into four roughly rectangular areas called blocks. The rows of the table are called periods, and the columns are called groups. Elements from the same group of the periodic table show similar chemical characteristics. Trends run through the periodic table, with nonmetallic character (keeping their own electrons) increasing from left to right across a period, and from down to up across a group, and metallic character (surrendering electrons to other atoms) increasing in the opposite direction. The underlying reason for these trends is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
William Hume-Rothery
William Hume-Rothery OBE FRS (15 May 1899 – 27 September 1968) was an English metallurgist and materials scientist who studied the constitution of alloys. Early life and education Hume-Rothery was born the son of lawyer Joseph Hume-Rothery in Worcester Park, Surrey. His grandfather, William Rothery, was a clergyman. His campaigning grandmother, Mary Hume-Rothery, was the daughter of Joseph Hume, a Scottish doctor and Radical Member of parliament. William spent his youth in Cheltenham and was educated at Cheltenham College. In 1917 he was made totally deaf by a virus infection. Nevertheless, he entered Magdalen College, Oxford, and obtained a first class Honours degree in chemistry. He also attended the Royal School of Mines and was awarded a PhD. Career During World War II, he supervised numerous government contracts for work on aluminium and magnesium alloys. After the war he returned to Oxford "''to carry on research in intermetallic compounds and problems on the borde ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Law Of Multiple Proportions
In chemistry, the law of multiple proportions states that if two elements form more than one compound, then the ratios of the masses of the second element which combine with a fixed mass of the first element will always be ratios of small whole numbers. This law is also known as: ''Dalton's Law'', named after John Dalton, the chemist who first expressed it. For example, Dalton knew that the element carbon forms two oxides by combining with oxygen in different proportions. A fixed mass of carbon, say 100 grams, may react with 133 grams of oxygen to produce one oxide, or with 266 grams of oxygen to produce the other. The ratio of the masses of oxygen that can react with 100 grams of carbon is 266:133 = 2:1, a ratio of small whole numbers. Dalton interpreted this result in his atomic theory by proposing (correctly in this case) that the two oxides have one and two oxygen atoms respectively for each carbon atom. In modern notation the first is CO (carbon monoxide) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phase Diagram
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium. Overview Common components of a phase diagram are ''lines of equilibrium'' or ''phase boundaries'', which refer to lines that mark conditions under which multiple phases can coexist at equilibrium. Phase transitions occur along lines of equilibrium. Metastable phases are not shown in phase diagrams as, despite their common occurrence, they are not equilibrium phases. Triple points are points on phase diagrams where lines of equilibrium intersect. Triple points mark conditions at which three different phases can coexist. For example, the water phase diagram has a triple point corresponding to the single temperature and pressure at which solid, liquid, and gaseous water can coexist in a stabl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Analysis
Thermal analysis is a branch of materials science where the properties of materials are studied as they change with temperature. Several methods are commonly used – these are distinguished from one another by the property which is measured: * Dielectric thermal analysis: dielectric permittivity and loss factor * Differential thermal analysis: temperature difference versus temperature or time * Differential scanning calorimetry: heat flow changes versus temperature or time * Dilatometer, Dilatometry: volume changes with temperature change * Dynamic mechanical analysis: measures storage modulus (stiffness) and loss modulus (damping) versus temperature, time and frequency * Evolved gas analysis: analysis of gases evolved during heating of a material, usually decomposition products * Isothermal titration calorimetry * Isothermal microcalorimetry * Laser flash analysis: thermal diffusivity and thermal conductivity * Thermogravimetric analysis: mass change versus temperature or time ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Diffraction
X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles and intensities of these diffracted beams, a crystallographer can produce a three-dimensional picture of the density of electrons within the crystal. From this electron density, the mean positions of the atoms in the crystal can be determined, as well as their chemical bonds, their crystallographic disorder, and various other information. Since many materials can form crystals—such as salts, metals, minerals, semiconductors, as well as various inorganic, organic, and biological molecules—X-ray crystallography has been fundamental in the development of many scientific fields. In its first decades of use, this method determined the size of atoms, the lengths and types of chemical bonds, and the atomic-scale differences among various mat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Brillouin Zone
In mathematics and solid state physics, the first Brillouin zone is a uniquely defined primitive cell in reciprocal space. In the same way the Bravais lattice is divided up into Wigner–Seitz cells in the real lattice, the reciprocal lattice is broken up into Brillouin zones. The boundaries of this cell are given by planes related to points on the reciprocal lattice. The importance of the Brillouin zone stems from the description of waves in a periodic medium given by Bloch's theorem, in which it is found that the solutions can be completely characterized by their behavior in a single Brillouin zone. The first Brillouin zone is the locus of points in reciprocal space that are closer to the origin of the reciprocal lattice than they are to any other reciprocal lattice points (see the derivation of the Wigner–Seitz cell). Another definition is as the set of points in ''k''-space that can be reached from the origin without crossing any Bragg plane. Equivalently, this is the Vor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fermi Surface
In condensed matter physics, the Fermi surface is the surface in reciprocal space which separates occupied from unoccupied electron states at zero temperature. The shape of the Fermi surface is derived from the periodicity and symmetry of the crystalline lattice and from the occupation of electronic energy bands. The existence of a Fermi surface is a direct consequence of the Pauli exclusion principle, which allows a maximum of one electron per quantum state. The study of the Fermi surfaces of materials is called fermiology. Theory Consider a spin-less ideal Fermi gas of N particles. According to Fermi–Dirac statistics, the mean occupation number of a state with energy \epsilon_i is given by :\langle n_i\rangle =\frac, where, *\left\langle n_i\right\rangle is the mean occupation number of the i^ state *\epsilon_i is the kinetic energy of the i^ state *\mu is the chemical potential (at zero temperature, this is the maximum kinetic energy the particle can have, i.e. Fermi ene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wave Vector
In physics, a wave vector (or wavevector) is a vector used in describing a wave, with a typical unit being cycle per metre. It has a magnitude and direction. Its magnitude is the wavenumber of the wave (inversely proportional to the wavelength), and its direction is perpendicular to the wavefront. In isotropic media, this is also the direction of wave propagation. A closely related vector is the angular wave vector (or angular wavevector), with a typical unit being radian per metre. The wave vector and angular wave vector are related by a fixed constant of proportionality, 2π radians per cycle. It is common in several fields of physics to refer to the angular wave vector simply as the ''wave vector'', in contrast to, for example, crystallography. It is also common to use the symbol ''k'' for whichever is in use. In the context of special relativity, ''wave vector'' can refer to a four-vector, in which the (angular) wave vector and (angular) frequency are combined. Def ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnitude (vector)
In mathematics, a norm is a function from a real or complex vector space to the non-negative real numbers that behaves in certain ways like the distance from the origin: it commutes with scaling, obeys a form of the triangle inequality, and is zero only at the origin. In particular, the Euclidean distance of a vector from the origin is a norm, called the Euclidean norm, or 2-norm, which may also be defined as the square root of the inner product of a vector with itself. A seminorm satisfies the first two properties of a norm, but may be zero for vectors other than the origin. A vector space with a specified norm is called a normed vector space. In a similar manner, a vector space with a seminorm is called a ''seminormed vector space''. The term pseudonorm has been used for several related meanings. It may be a synonym of "seminorm". A pseudonorm may satisfy the same axioms as a norm, with the equality replaced by an inequality "\,\leq\," in the homogeneity axiom. It can also re ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nearly Free Electron Model
In solid-state physics, the nearly free electron model (or NFE model) or quasi-free electron model is a quantum mechanical model of physical properties of electrons that can move almost freely through the crystal lattice of a solid. The model is closely related to the more conceptual empty lattice approximation. The model enables understanding and calculation of the electronic band structures, especially of metals. This model is an immediate improvement of the free electron model, in which the metal was considered as a non-interacting electron gas and the ions were neglected completely. Mathematical formulation The nearly free electron model is a modification of the free-electron gas model which includes a ''weak'' periodic perturbation meant to model the interaction between the conduction electrons and the ions in a crystalline solid. This model, like the free-electron model, does not take into account electron–electron interactions; that is, the independent electron ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
