Light-emitting Materials
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Light-emitting Materials
Luminescence is spontaneous emission of light by a substance not resulting from heat; or "cold light". It is thus a form of cold-body radiation. It can be caused by chemical reactions, electrical energy, subatomic motions or stress on a crystal. This distinguishes luminescence from incandescence, which is light emitted by a substance as a result of heating. Historically, radioactivity was thought of as a form of "radio-luminescence", although it is today considered to be separate since it involves more than electromagnetic radiation. The dials, hands, scales, and signs of aviation and navigational instruments and markings are often coated with luminescent materials in a process known as "luminising". Types The following are types of luminescence: * Chemiluminescence, the emission of light as a result of a chemical reaction **Bioluminescence, a result of biochemical reactions in a living organism **Electrochemiluminescence, a result of an electrochemical reaction **Lyolumine ...
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Luminol
Luminol (C8H7N3O2) is a chemical that exhibits chemiluminescence, with a blue glow, when mixed with an appropriate oxidizing agent. Luminol is a white-to-pale-yellow crystalline solid that is soluble in most polar organic solvents, but insoluble in water. Forensic investigators use luminol to detect trace amounts of blood at crime scenes, as it reacts with the iron in hemoglobin. Biologists use it in cellular assays to detect copper, iron, cyanides, as well as specific proteins via western blotting. When luminol is sprayed evenly across an area, trace amounts of an activating oxidant make the luminol emit a blue glow that can be seen in a darkened room. The glow only lasts about 30 seconds, but can be documented photographically. The glow is stronger in areas receiving more spray; the intensity of the glow does not indicate the amount of blood or other activator present. Synthesis Luminol is synthesized in a two-step process, beginning with 3-nitrophthalic acid. First, hydra ...
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Blackbody
A black body or blackbody is an idealized physical body that absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence. The name "black body" is given because it absorbs all colors of light. A black body also emits black-body radiation. In contrast, a white body is one with a "rough surface that reflects all incident rays completely and uniformly in all directions." A black body in thermal equilibrium (that is, at a constant temperature) emits electromagnetic black-body radiation. The radiation is emitted according to Planck's law, meaning that it has a spectrum that is determined by the temperature alone (see figure at right), not by the body's shape or composition. An ideal black body in thermal equilibrium has two main properties: #It is an ideal emitter: at every frequency, it emits as much or more thermal radiative energy as any other body at the same temperature. #It is a diffuse emitter: measured per unit area perpendicular to the ...
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Exponential Decay
A quantity is subject to exponential decay if it decreases at a rate proportional to its current value. Symbolically, this process can be expressed by the following differential equation, where is the quantity and (lambda) is a positive rate called the exponential decay constant, disintegration constant, rate constant, or transformation constant: :\frac = -\lambda N. The solution to this equation (see derivation below) is: :N(t) = N_0 e^, where is the quantity at time , is the initial quantity, that is, the quantity at time . Measuring rates of decay Mean lifetime If the decaying quantity, ''N''(''t''), is the number of discrete elements in a certain set, it is possible to compute the average length of time that an element remains in the set. This is called the mean lifetime (or simply the lifetime), where the exponential time constant, \tau, relates to the decay rate constant, λ, in the following way: :\tau = \frac. The mean lifetime can be looked at as a ...
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Relaxation (physics)
In the physical sciences, relaxation usually means the return of a perturbed system into equilibrium. Each relaxation process can be categorized by a relaxation time τ. The simplest theoretical description of relaxation as function of time ''t'' is an exponential law (exponential decay A quantity is subject to exponential decay if it decreases at a rate proportional to its current value. Symbolically, this process can be expressed by the following differential equation, where is the quantity and (lambda) is a positive rate ...). In simple linear systems Mechanics: Damped unforced oscillator Let the homogeneous differential equation: :m\frac+\gamma\frac+ky=0 model damped harmonic oscillator, damped unforced oscillations of a weight on a spring. The displacement will then be of the form y(t) = A e^ \cos(\mu t - \delta). The constant T (=2m/\gamma) is called the relaxation time of the system and the constant μ is the quasi-frequency. Electronics: RC circuit In an RC ...
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Singlet State
In quantum mechanics, a singlet state usually refers to a system in which all electrons are paired. The term 'singlet' originally meant a linked set of particles whose net angular momentum is zero, that is, whose overall spin quantum number s=0. As a result, there is only one spectral line of a singlet state. In contrast, a doublet state contains one unpaired electron and shows splitting of spectral lines into a doublet; and a triplet state has two unpaired electrons and shows threefold splitting of spectral lines. History Singlets and the related spin concepts of doublets and triplets occur frequently in atomic physics and nuclear physics, where one often needs to determine the total spin of a collection of particles. Since the only observed fundamental particle with zero spin is the extremely inaccessible Higgs boson, singlets in everyday physics are necessarily composed of sets of particles whose individual spins are non-zero, e.g. or 1. The origin of the term "singlet" is ...
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Fluorescence
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, than the absorbed radiation. A perceptible example of fluorescence occurs when the absorbed radiation is in the ultraviolet region of the electromagnetic spectrum (invisible to the human eye), while the emitted light is in the visible region; this gives the fluorescent substance a distinct color that can only be seen when the substance has been exposed to UV light. Fluorescent materials cease to glow nearly immediately when the radiation source stops, unlike phosphorescent materials, which continue to emit light for some time after. Fluorescence has many practical applications, including mineralogy, gemology, medicine, chemical sensors (fluorescence spectroscopy), fluorescent labelling, dyes, biological detectors, cosmic-ray detection, vacu ...
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Photoluminescence
Photoluminescence (abbreviated as PL) is light emission from any form of matter after the absorption of photons (electromagnetic radiation). It is one of many forms of luminescence (light emission) and is initiated by photoexcitation (i.e. photons that excite electrons to a higher energy level in an atom), hence the prefix ''photo-''. Following excitation, various relaxation processes typically occur in which other photons are re-radiated. Time periods between absorption and emission may vary: ranging from short femtosecond-regime for emission involving free-carrier plasma in inorganic semiconductorsHayes, G.R.; Deveaud, B. (2002). "Is Luminescence from Quantum Wells Due to Excitons?". ''Physica Status Solidi A'' 190 (3): 637–640doi:10.1002/1521-396X(200204)190:33.0.CO;2-7/ref> up to milliseconds for phosphoresence processes in molecular systems; and under special circumstances delay of emission may even span to minutes or hours. Observation of photoluminescence at a certain ene ...
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Sonoluminescence
Sonoluminescence is the emission of light from imploding bubbles in a liquid when excited by sound. History The sonoluminescence effect was first discovered at the University of Cologne in 1934 as a result of work on sonar. Hermann Frenzel and H. Schultes put an ultrasound transducer in a tank of photographic developer fluid. They hoped to speed up the development process. Instead, they noticed tiny dots on the film after developing and realized that the bubbles in the fluid were emitting light with the ultrasound turned on. It was too difficult to analyze the effect in early experiments because of the complex environment of a large number of short-lived bubbles. This phenomenon is now referred to as multi-bubble sonoluminescence (MBSL). In 1960, Peter Jarman from Imperial College of London proposed the most reliable theory of sonoluminescence phenomenon. He concluded that sonoluminescence is basically thermal in origin and that it might possibly arise from microshocks with th ...
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Piezoluminescence
Piezoluminescence is a form of luminescence created by pressure upon certain solids. This phenomenon is characterized by recombination processes involving electrons, holes and impurity ion centres. Some piezoelectric crystals give off a certain amount of piezoluminescence when under pressure. Irradiated salts, such as NaCl, KCl, KBr and polycrystalline chips of LiF (TLD-100), have been found to exhibit piezoluminescent properties. It has also been discovered that ferroelectric polymers exhibit piezoluminescence upon the application of stress. In the folk-literature surrounding psychedelic production, DMT, 5-MeO-DMT, and LSD have been reported to exhibit piezoluminescence. As specifically noted in the book '' Acid Dreams'', it is stated that Augustus Owsley Stanley III, one of the most prolific producers of LSD in the 1960s, observed piezoluminescence in the compound's purest form, which observation is confirmed by Alexander Shulgin: "A totally pure salt, when dry and when shaken ...
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Triboluminescence
Triboluminescence is a phenomenon in which light is generated when a material is mechanically pulled apart, ripped, scratched, crushed, or rubbed (see tribology). The phenomenon is not fully understood, but appears to be caused by the separation and reunification of static electrical charges. The term comes from the Greek τρίβειν ("to rub"; see tribology) and the Latin ''lumen'' (light). Triboluminescence can be observed when breaking sugar crystals and peeling adhesive tapes. ''Triboluminescence'' is often used as a synonym for ''fractoluminescence'' (a term sometimes used when referring only to light emitted from fractured crystals). Triboluminescence differs from piezoluminescence in that a piezoluminescent material emits light when it is deformed, as opposed to broken. These are examples of mechanoluminescence, which is luminescence resulting from any mechanical action on a solid. History Uncompahgre Ute indigenous people The Uncompahgre Ute indigenous people ...
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Mechanoluminescence
Mechanoluminescence is light emission resulting from any mechanical action on a solid. It can be produced through ultrasound, or through other means. * Fractoluminescence is caused by stress that results in the formation of fractures. * Piezoluminescence is caused by pressure that results only in elastic deformation. * Triboluminescence is nominally caused by rubbing, but actually because of resulting fractoluminescence, so is often used as a synonym. * Sonoluminescence is the emission of short bursts of light from imploding bubbles in a liquid when excited by sound. * Electrochemiluminescence is the emission induced by an electrochemical stimulus. See also *List of light sources This is a list of sources of light, the visible part of the electromagnetic spectrum. Light sources produce photons from another energy source, such as heat, chemical reactions, or conversion of mass or a different frequency of electromagnetic ener ... References {{reflist External links Ultrasound ...
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Cathodoluminescence
Cathodoluminescence is an optical and electromagnetic phenomenon in which electrons impacting on a luminescent material such as a phosphor, cause the emission of photons which may have wavelengths in the visible spectrum. A familiar example is the generation of light by an electron beam scanning the phosphor-coated inner surface of the screen of a television that uses a cathode ray tube. Cathodoluminescence is the inverse of the photoelectric effect, in which electron emission is induced by irradiation with photons. Origin Luminescence in a semiconductor results when an electron in the conduction band recombines with a hole in the valence band. The difference energy (band gap) of this transition can be emitted in form of a photon. The energy (color) of the photon, and the probability that a photon and not a phonon will be emitted, depends on the material, its purity, and the presence of defects. First, the electron has to be excited from the valence band into the conduction ba ...
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